/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 13 Uranium- \(238\left({ }_{92}^{23... [FREE SOLUTION] | 91Ó°ÊÓ

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Uranium- \(238\left({ }_{92}^{238} \mathrm{U}\right)\) is radioactive and decays into a succession of different elements. The following particles are emitted before the nucleus reaches a stable form: \(\alpha, \beta, \beta, \alpha, \alpha, \alpha, \alpha, \alpha, \beta, \beta, \alpha, \beta, \beta\), and \(\alpha\) ( \(\beta\) stands for "beta particle," \(e^{-}\) ). What is the final stable nucleus? The original nucleus emitted 8 alpha particles and 6 beta particles. When an alpha particle is emitted. \(Z\) decreases by 2, since the alpha particle carries away a charge of \(+2 e .\) A beta particle carries away a charge of \(-1 e\), and so as a result the charge on the nucleus must increase to \((Z+1) e\). We then have, for the final nucleus, $$ \begin{array}{l} \text { Final } Z=92+6-(2)(8)=82 \\ \text { Final } A=238-(6)(0)-(8)(4)=206 \end{array} $$ The final stable nucleus is \({ }_{82}^{206} \mathrm{~Pb}\).

Short Answer

Expert verified
The final stable nucleus is \({ }_{82}^{206} \mathrm{~Pb}\) (Lead).

Step by step solution

01

Initial Understanding

We begin with Uranium-238, denoted as \(_{92}^{238} \text{U}\), which undergoes a series of radioactive decays. Understanding the names and charges of emitted particles is crucial. An alpha particle consists of 2 protons and 2 neutrons and reduces atomic number \(Z\) by 2 and mass number \(A\) by 4. A beta particle increases \(Z\) by 1 without changing \(A\).
02

Calculate Final Atomic Number

To find the final atomic number, we account for each type of emission. Starting at \(Z = 92\), we lose \(2 \times 8 = 16\) from 8 alpha emissions, and we gain \(1 \times 6 = 6\) from 6 beta emissions. The calculation is performed as: \(92 - 16 + 6 = 82\).
03

Calculate Final Mass Number

Start with \(A = 238\). Each alpha emission decreases the mass number by 4. With 8 alpha particles emitted, we have a decrease of \(8 \times 4 = 32\). Beta emissions don't affect mass number so we keep the counts the same. Calculate \(238 - 32 = 206\).
04

Identify the Final Stable Nucleus

Using the calculated \(Z = 82\) and \(A = 206\), we identify the corresponding element. The periodic table indicates that \(Z = 82\) is the element Lead (Pb). Thus, the final stable nucleus is \(_{82}^{206} \text{Pb}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Alpha Particles
In the world of radioactive decay, alpha particles play a significant role. An alpha particle is essentially the nucleus of a helium atom. It has 2 protons and 2 neutrons, which account for its mass and charge. When an alpha particle is emitted from a nucleus, it results in a decrease of the atomic number, denoted as \( Z \), by 2. This is because the nucleus is losing two protons.
Moreover, the mass number, represented by \( A \), decreases by 4 because the alpha particle also contains two neutrons. This means that for every alpha particle emitted, the original element transforms into another element further down the periodic table.
Alpha Decay Effects:
  • Reduction in Atomic Number: \( Z - 2 \)
  • Reduction in Mass Number: \( A - 4 \)
Through the process of alpha decay, heavy elements like Uranium-238 change into lighter elements, until a stable nucleus is reached.
Beta Particles
Beta particles are essentially high-energy, high-speed electrons or positrons emitted during the decay of radioactive nuclei. In beta decay, a neutron in unstable nuclei is transformed into a proton and an electron. The electron, known as a beta particle, is then emitted from the nucleus.
This process increases the atomic number, \( Z \), by 1 while the mass number \( A \) remains unchanged. Because beta particles carry away a negative charge of \(-1e\), the nucleus compensates by adding a proton.
Beta Decay Effects:
  • Increase in Atomic Number: \( Z + 1 \)
  • Mass Number Unchanged: \( A = \text{constant} \)
Thus, through beta decay, a nucleus can increase its atomic number, effectively moving to a higher element on the periodic table, while maintaining its overall mass.
Atomic Number
The atomic number, symbolized by \( Z \), is pivotal in understanding an element's identity. It represents the number of protons found within the nucleus of an atom. Since each element on the periodic table is defined by its unique atomic number, changes in \( Z \) result in element transformation.
During radioactive decay:
  • Alpha Decay: The atomic number decreases by 2, as a helium nucleus is lost.
  • Beta Decay: The atomic number increases by 1, owing to the conversion of a neutron into a proton.
Understanding these changes is crucial in radioactive decay sequences, as they guide the transition from one element to another.
Mass Number
The mass number, denoted by \( A \), is a fundamental property of an atom that consists of the total number of protons and neutrons within the nucleus. Unlike atomic number, the mass number is not singularly defining but provides insight into the isotope of an element.
In radioactive decay:
  • Alpha Decay: The mass number decreases by 4 due to the emission of a helium nucleus, which contains 2 protons and 2 neutrons.
  • Beta Decay: The mass number remains unchanged since this process involves the transformation within the nucleus without proton-neutron alteration.
The mass number helps in calculating and identifying isotopes and their transformations during decay processes, such as in the decay chain of Uranium-238 to Lead-206.

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Most popular questions from this chapter

Complete the following nuclear equations: (a) \({ }^{14} \mathrm{~N}+{ }_{2}^{4} \mathrm{He} \rightarrow{ }_{8}^{17} \mathrm{O}+\) ? (d) \({ }_{15}^{30} \mathrm{P} \rightarrow{ }_{14}^{30} \mathrm{Si}+\) ? (b) \({ }_{4}^{9} \mathrm{Be}+{ }_{2}^{3} \mathrm{He} \rightarrow{ }_{6}^{12} \mathrm{C}+?\) (e) \({ }_{1}^{3} \mathrm{H} \rightarrow{ }_{2}^{3} \mathrm{He}+?\) (c) \({ }_{4}^{9} \operatorname{Be}(p, \alpha)\) ? (f) \({ }_{20}^{43} \mathrm{Ca}(\alpha, ?) \frac{46}{21} \mathrm{Sc}\) (a) The sum of the subscripts on the left is \(7+2=9 .\) The subscript of the first product on the right is 8 . Hence, the second product on the right must have a subscript (net charge) of \(1 .\) Also, the sum of the superscripts on the left is \(14+4=18 .\) The superscript of the first product is \(17 .\) Hence, the second product on the right must have a superscript (mass number) of 1 . The particle with nuclear charge 1 and mass number 1 is the proton, \({ }_{1}^{1} \underline{H}\). (b) The nuclear charge of the second product particle (its subscript) is \((4+2)-6=0 .\) The mass number of the particle (its superscript) is \((9+4)-12=1 .\) Hence, the particle must be the neutron, \(\downarrow{n}\). (c) The reactants \({ }_{4}^{9} \mathrm{Be}\) and \({ }_{1}^{1} \mathrm{H}\) have a combined nuclear charge of 5 and a mass number of \(10 .\) In addition to the alpha particle, a product will be formed of charge \(5-2=3\) and mass number \(10-4=6\). This is \(\frac{6}{3} \mathrm{Li}\). (d) The nuclear charge of the second product particle is \(15-14=+1\). Its mass number is \(30-30=0\). Hence, the particle must be a positron, \({ }_{+1} e\). (e) The nuclear charge of the second product particle is \(1-2=-1 .\) Its mass number is \(3-3=0 .\) Hence. the particle must be a beta particle (an electron), \(_{-1}^{0} e\). ( \(f\) ) The reactants, \(_{20}^{43} \mathrm{Ca}\) and \({ }_{2}^{4} \mathrm{He}\), have a combined nuclear charge of 22 and mass number of \(47 .\) The ejected product will have charge \(22-21=1\), and mass number \(47-46=1 .\) This is a proton and should be represented in the parentheses by \(p\). In some of these reactions a neutrino and/or a photon are emitted. We ignore them for this discussion since the charge for both are zero. Moreover the mass of the photon is zero and the mass of each of the several neutrinos, although not zero, is negligibly small.

Technetium-99 \(\left({ }_{43}^{99} \mathrm{Tc}\right)\) has an excited state that decays by emission of a gamma ray. The half-life of the excited state is \(360 \mathrm{~min}\). What is the activity, in curies, of \(1.00 \mathrm{mg}\) of this excited isotope? Because we have the half-life \(\left(t_{1 / 2}\right)\) we can determine the decay constant since \(\lambda t_{1 / 2}=0.693 .\) The activity of a sample is \(\lambda N\). In this case, $$ \lambda=\frac{0.693}{t_{1 / 2}}=\frac{0.693}{21600 \mathrm{~s}}=3.21 \times 10^{-5} \mathrm{~s}^{-1} $$ We also know that \(99.0 \mathrm{~kg}\) of Tc contains \(6.02 \times 10^{26}\) atoms. A mass \(m\) will therefore contain \([m /(99.0 \mathrm{~kg})]\left(6.02 \times 10^{26}\right)\) atoms. In our case, \(m=1.00 \times 10^{-6} \mathrm{~kg}\), and so $$ \begin{aligned} \text { Activity } &=\lambda N=\left(3.21 \times 10^{-5} \mathrm{~s}^{-1}\right)\left(\frac{1.00 \times 10^{-6} \mathrm{~kg}}{99.0 \mathrm{~kg}}\right)\left(6.02 \times 10^{26}\right) \\ &=1.95 \times 10^{14} \mathrm{~s}^{-1}=1.95 \times 10^{14} \mathrm{~Bq} \end{aligned} $$

By how much does the mass of a heavy nucleus change when it emits a 4.8-MeV gamma ray?

Complete the notations for the following processes. (a) \({ }^{24} \mathrm{Mg}(d, \alpha) ?\) (e) \(130 \mathrm{Te}(d, 2 n) ?\) (b) \({ }^{26} \mathrm{Mg}(d, p) ?\) (f) \({ }^{55} \mathrm{Mn}(n, \gamma)\) ? (c) \({ }^{40} \operatorname{Ar}(\alpha, p) ?\) \((g){ }^{59} \mathrm{Co}(n, \alpha) ?\) (d) \({ }^{12} \mathrm{C}(d, n) ?\)

How much energy must a bombarding proton possess to cause the reaction \({ }^{7} \operatorname{Li}(p, n)^{7} \mathrm{Be}\) ? Give your answer to three significant figures. The reaction is as follows: $$ { }_{3}^{7} \mathrm{Li}+{ }_{1}^{1} \mathrm{H} \rightarrow{ }_{4}^{7} \mathrm{Be}+{ }_{0}^{1} n $$ where the symbols represent the nuclei of the atoms indicated. Because the masses listed in Table \(45-2\) include the masses of the atomic electrons, the appropriate number of electron masses \(\left(m_{e}\right)\) must be subtracted from the values given. Subtracting the total reactant mass from the total product mass gives the increase in mass as \(0.00176 \mathrm{u}\). (Notice that the electron masses cancel out. This happens frequently, but not always.) To create this mass in the reaction, energy must have been supplied to the reactants. The energy corresponding to \(0.00176 \mathrm{u}\) is \((931 \times 0.00176) \mathrm{MeV}=1.65 \mathrm{MeV}\). This energy is supplied as \(\mathrm{KE}\) of the bombarding proton. The incident proton must have more than this energy because the system must possess some KE even after the reaction, so that momentum is conserved. With momentum conservation taken into account, the minimum KE that the incident particle must have can be found with the formula $$ \left(1+\frac{m}{M}\right)(1.65) \mathrm{MeV} $$ where \(M\) is the mass of the target particle, and \(m\) that of the incident particle. Therefore, the incident particle must have an energy of at least $$ \left(1+\frac{1}{7}\right)(1.65) \mathrm{MeV}=1.89 \mathrm{MeV} $$

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