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What is the smallest Bragg angle for \(x\) rays of wavelength \(52 \mathrm{pm}\) to reflect from reflecting planes spaced \(0.30 \mathrm{~nm}\) apart in a calcite crystal?

Short Answer

Expert verified
The smallest Bragg angle is approximately \(4.97^\circ\).

Step by step solution

01

Identify Known Values

We know that the wavelength of the x-rays, \( \lambda \), is \( 52 \text{ pm} \) or \( 52 \times 10^{-12} \text{ m} \). The spacing between the crystal planes, \( d \), is \( 0.30 \text{ nm} \) or \( 0.30 \times 10^{-9} \text{ m} \).
02

Understand Bragg's Law

Bragg's Law is given by the equation: \( n\lambda = 2d\sin\theta \), where \( n \) is the order of reflection, \( \lambda \) is the wavelength, \( d \) is the distance between reflecting planes, and \( \theta \) is the Bragg angle.
03

Solving For Smallest Bragg Angle

For the smallest angle, we consider the first order reflection (\( n = 1 \)). Applying Bragg's Law for \( n = 1 \), we have \( \lambda = 2d\sin\theta \). Plug in the known values: \( 52 \times 10^{-12} = 2(0.30 \times 10^{-9})\sin\theta \).
04

Rearrange to Find \( \theta \)

Rearrange the equation to solve for \( \sin\theta \): \( \sin\theta = \frac{52 \times 10^{-12}}{2(0.30 \times 10^{-9})} \). Calculate to get \( \sin\theta = 0.08667 \).
05

Compute the Bragg Angle

Find \( \theta \) by taking the inverse sine (arcsin) of 0.08667: \( \theta = \arcsin(0.08667) \approx 4.97^\circ \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

X-ray diffraction
X-ray diffraction is a critical concept in the study of crystal structures. This technique involves the scattering of X-rays by the atoms in a crystal, resulting in a diffraction pattern that can reveal important information about the crystal's internal lattice structure.
X-rays are a form of electromagnetic radiation with very short wavelengths, which makes them ideal for probing the tiny distances between atoms in crystals.
When X-rays encounter a crystal, they interact with the electrons in the atoms, causing the waves to scatter. If these scattered waves interfere constructively, they produce a pattern of intensity peaks. These peaks help scientists determine the arrangement of atoms in the crystal, as well as the distances between them.
The concept of X-ray diffraction is central to various fields including physics, chemistry, and biology, as it allows for the in-depth analysis of materials and biomolecules.
wavelength
Wavelength is a crucial parameter when discussing X-ray diffraction. Specifically, the wavelength is the distance between successive peaks of a wave.
In the context of X-ray diffraction, the wavelength of the X-ray must be much smaller than the dimensions of the crystal lattice. This allows the X-rays to diffract effectively and generate useful diffraction patterns.
X-rays used in diffraction studies typically have very short wavelengths, on the order of picometers (pm) or nanometers (nm). For instance, in the original exercise, the wavelength of the X-ray is given as 52 pm.
It is important because the wavelength determines the resolution of the diffraction pattern. A smaller wavelength can provide more detailed information about the crystal structure. Hence, selecting the appropriate wavelength is key to obtaining accurate diffraction results.
crystal lattice spacing
Crystal lattice spacing refers to the regular distances between the planes of atoms in a crystal. This spacing is denoted as \( d \) in Bragg's Law.
The geometry of a crystal determines these spacings, which vary among different materials. Crystal lattice spacing is pivotal because it directly influences how X-rays are diffracted as they pass through the crystal.
In Bragg's Law, \( n\lambda = 2d\sin\theta \), \( d \) represents this spacing and directly affects the calculation of the Bragg angle. This distance must be measured accurately to ensure precise diffraction analysis.
Understanding crystal lattice spacing helps in identifying the type of crystal and its properties. For example, specific spacing can suggest the strength, thermal properties, and interaction potential of the crystal.
calcite crystal
Calcite is a common form of calcium carbonate with a unique crystal structure. It is often used in studies of X-ray diffraction because its crystal lattice is well-defined and easily accessible.
In calcite crystals, the spacing between the reflecting planes is relatively large compared to other materials, making it easier to study using X-rays with longer wavelengths. This trait allows scientists to explore various angles of reflection without requiring extremely short wavelengths.
The orientation and structure of calcite make it suitable for demonstrating concepts like Bragg's Law. Using calcite crystals, researchers and students can observe how subtle changes in conditions alter the diffraction of X-rays.
Employing calcite in educational exercises aids in visualizing diffraction concepts, given that its predictable structure leads to consistent and reliable results in diffraction experiments.

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Most popular questions from this chapter

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