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One mole of an ideal gas initially at a temperature of \(T_{i}=0^{\circ}\) C undergoes an expansion at a constant pressure of \(1.00 \mathrm{~atm}\) to four times its original volume. (a) Calculate the new temperature \(T_{f}\) of the gas. (b) Calculate the work done on the gas during the expansion.

Short Answer

Expert verified
The new temperature of the gas after expansion is \(T_f = 1092~K\) and the work done on the gas during the expansion is \(W = 3.039x10^5 * V_1~J\), where \(V_1\) is the initial volume in \(m^3\).

Step by step solution

01

Calculate the final temperature of the gas

We know that the volume of the gas expands to four times its original volume at constant pressure. For an ideal gas subjected to isobaric process (constant pressure), we can use the formula \(V_1 / T_1 = V_2 / T_2\), where \(V1\) and \(T1\) are initial volume and temperature respectively and \(V2\) and \(T2\) are final volume and temperature respectively. From the equation we can express the final temperature as \(T_2 = T_1 * (V_2 / V_1)\), since \(V2\) is four times \(V1\), then the equation becomes \(T_2 = T_1 * 4\). However, we need to convert the initial temperature from Celsius to Kelvin by adding 273 to it, which gives us \(T_1 = 273~K\). Therefore, \(T_2 = 273~K * 4 = 1092~K\).
02

Calculate the work done on the gas during the expansion

The work done in an isobaric process can be calculated using the equation \(W = P * ∆V\), where \(P\) is the constant pressure and \(∆V\) is the change in volume. Since the volume expands to four times its original volume, we know that \(∆V = V_2 - V_1 = 3 * V_1\). But we don't know the values of \(V_1\) and \(V_2\). However, we don't need to know their actual values because the problem only requires the work done on the gas during the process which is proportional to the change in volume, ∆V, irrespective of the actual values of \(V_1\) and \(V_2\). Therefore, the work is \(W = P * ∆V = 1.00~atm * 3 * V_1\). We can express 'atm' in terms of 'Joules' where \(1~atm = 1.013x10^5~Pascals\) and \(1~Pascal = 1~J/m^3\), so \(1~atm = 1.013x10^5~J/m^3\). Therefore, \[W = 1.00~atm * 3 * V_1 = 1.013x10^5~J/m^3 * 3*V_1 = 3.039x10^5 * V_1~J\], where \(V_1\) is in \(m^3\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Isobaric Process
An isobaric process is a thermodynamic process that occurs under constant pressure. This is a key concept when understanding ideal gases and is one of the simpler types of processes because the pressure value does not change. In this kind of process, when an ideal gas expands or compresses at a constant pressure, you will see changes primarily in temperature and volume.

One of the main characteristics is that during an expansion at constant pressure, the work done on or by the gas is very straightforward to calculate. The work done, as we will discover in a later section, is directly related to the change in volume. This makes the isobaric process easy to analyze and understand, especially with knowledge of the Ideal Gas Law.

The ideal gas law, which is expressed as \(PV = nRT\), holds well here, where \(P\) is the pressure, \(V\) is the volume, \(n\) is the number of moles of the gas, \(R\) is the ideal gas constant, and \(T\) is the temperature in Kelvin. Understanding each component is crucial when solving any physics problem related to gases and thermodynamics.
Temperature-Volume Relationship
In an isobaric process, the Temperature-Volume relationship is governed by Charles's Law. This law states that at constant pressure, the volume of a gas is directly proportional to its absolute temperature. In formula terms, it is expressed as \(V_1 / T_1 = V_2 / T_2\), where \(V_1\) and \(T_1\) are the initial volume and temperature respectively, and \(V_2\) and \(T_2\) are the final volume and temperature respectively.
This proportionality relationship means that if the temperature increases, the volume of the gas will also increase, and vice versa, as long as the pressure remains constant. This is what happens when a gas undergoes an isobaric expansion, like the one in the exercise, where the volume expands to four times its original volume.
Let's see how it works in practice. Initially, we have a temperature, \(T_1\), converted from Celsius to Kelvin by adding 273 (since Celsius and Kelvin are related by this constant offset). Knowing that the final volume \(V_2\) is four times the initial volume \(V_1\), the final temperature \(T_2\) can be calculated using \(T_2 = T_1 \times 4\). The direct proportional relationship enables the calculation of the new temperature in Kelvin, making the process of expanding gases easy to track.
Work Done on Gas
When analyzing how much work is done on or by an ideal gas during an isobaric process, it is essential to appreciate how this work relates to changes in volume. Work in physics is defined as the energy transferred to or from an object via the application of force along a displacement.
In an isobaric process, the work done, \(W\), is calculated using the formula \(W = P \times \Delta V\), where \(P\) is the constant pressure, and \(\Delta V\) is the change in volume (i.e., \(V_2 - V_1\)). This relationship shows that the work depends not on the absolute volumes but purely on the difference between them, making it more straightforward to calculate.
To convert this into a real-world unit, \(atm\) (atmospheres) must be converted into joules, since work in scientific contexts is usually defined in terms of energy or Joules. The conversion states that \(1~atm\) equals \(1.013 \times 10^5\) Pascals, and thus \(1~atm \) is equivalent to \(1.013 \times 10^5~J/m^3\). Using this conversion helps paint a clear picture of the energy involved in such thermodynamic processes. This understanding is crucial in a variety of scientific and engineering applications.

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Most popular questions from this chapter

Sketch a PV diagram of the following processes: (a) A gas expands at constant pressure \(P_{1}\) from volume \(V_{1}\) to volume \(V_{2} .\) It is then kept at constant volume while the pressure is reduced to \(P_{2}\). (b) A gas is reduced in pressure from \(P_{1}\) to \(P_{2}\) while its volume is held constant at \(V_{1} .\) It \(i s\) then expanded at constant pressure \(P_{2}\) to a final volume \(V_{2} .(c)\) In which of the processes is more work done by the gas? Why?

Hydrothermal vents deep on the ocean floor spout water at temperatures as high as \(570^{\circ} \mathrm{C}\). This temperature is below the boiling point of water because of the immense pressure at that depth. Because the surrounding ocean temperature is at \(4.0^{\circ} \mathrm{C}\), an organism could use the temperature gradient as a source of energy. (a) Assuming the specific heat of water under these conditions is \(1.0 \mathrm{cal} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}\), how much energy is released when \(1.0\) liter of water is cooled from \(570^{\circ} \mathrm{C}\) to \(4.0^{\circ} \mathrm{C}\) ? (b) What is the maximum usable energy an organism can extract from this energy source? (Assume the organism has some internal type of heat engine acting between the two temperature extremes.) (c) Water from these vents contains hydrogen sulfide \(\left(\mathrm{H}_{2} \mathrm{~S}\right)\) at a concentration of \(0.90 \mathrm{mmole} / \mathrm{liter}\). Oxidation of \(1.0\) mole of \(\mathrm{H}_{2} \mathrm{~S}\) produces \(310 \mathrm{~kJ}\) of energy. How much energy is available through \(\mathrm{H}_{2} \mathrm{~S}\) oxidation of \(1.0 \mathrm{~L}\) of water?

A gas changes in volume from \(0.750 \mathrm{~m}^{3}\) to \(0.250 \mathrm{~m}^{3}\) at a constant pressure of \(1.50 \times 10^{\circ}\) Pa. (a) How much work is done on the gas? (b) How much work is done by the gas on its environment? (c) Which of Newton's laws best explains why the work done on the gas is the negative of the work done on the environment?

An ideal gas expands at constant pressure. (a) Show that \(P \Delta V=n R \Delta T\). (b) If the gas is monatomic, start from the definition of internal energy and show that \(\Delta U=\frac{3}{2} W_{\text {env }}\) where \(W_{\text {ew }}\) is the work done by the gas on its environmenL. (c) For the same monatomic ideal gas, show with the first law that \(Q=\frac{5}{2} W_{\text {env }}\) (d) Is it possible for an ideal gas to expand at constant pressure while exhausting thermal energy? Explain.

Gas in a container is at a pressure of \(1.5 \mathrm{~atm}\) and a volame of \(4.0 \mathrm{~m}^{3}\). What is the work done on the gas (a) if it expands at constant pressure to twice its initial volume, and (b) if it is compressed at constant pressure to onequarter its initial volume?

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