Hydrothermal vents deep on the ocean floor spout water at temperatures as high
as \(570^{\circ} \mathrm{C}\). This temperature is below the boiling point of
water because of the immense pressure at that depth. Because the surrounding
ocean temperature is at \(4.0^{\circ} \mathrm{C}\), an organism could use the
temperature gradient as a source of energy. (a) Assuming the specific heat of
water under these conditions is \(1.0 \mathrm{cal} / \mathrm{g} \cdot{
}^{\circ} \mathrm{C}\), how much energy is released when \(1.0\) liter of water
is cooled from \(570^{\circ} \mathrm{C}\) to \(4.0^{\circ} \mathrm{C}\) ? (b) What
is the maximum usable energy an organism can extract from this energy source?
(Assume the organism has some internal type of heat engine acting between the
two temperature extremes.) (c) Water from these vents contains hydrogen
sulfide \(\left(\mathrm{H}_{2} \mathrm{~S}\right)\) at a concentration of \(0.90
\mathrm{mmole} / \mathrm{liter}\). Oxidation of \(1.0\) mole of \(\mathrm{H}_{2}
\mathrm{~S}\) produces \(310 \mathrm{~kJ}\) of energy. How much energy is
available through \(\mathrm{H}_{2} \mathrm{~S}\) oxidation of \(1.0 \mathrm{~L}\)
of water?