Chapter 38: Problem 6
(1) The lifetime of a typical excited state in an atom is about 10 ns. Suppose an atom falls from one such excited state and emits a photon of wavelength about 500 \(\mathrm{nm}\) . Find the fractional energy uncertainty \(\Delta E / E\) and wavelength uncertainty \(\Delta \lambda / \lambda\) of this photon.
Short Answer
Step by step solution
Understanding the Problem
Identify Given Data
Use Uncertainty Principle for Energy
Calculate \(\Delta E\)
Calculate Energy \(E\) of Photon
Calculate \(\frac{\Delta E}{E}\)
Use Energy-Wavelength Relation
Calculate \(\Delta \lambda \)
Compute \(\Delta \lambda / \lambda \)
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Energy-Time Uncertainty
This principle comes into play when atoms transition from an excited state back to a lower energy state. The lifetime of an excited state (\( \Delta t \)) plays a crucial role in determining the energy's uncertainty. For instance, a shorter-lived excited state would imply a larger \( \Delta E \). In the exercise, we are given \( \Delta t = 10 \text{ ns} \), leading to the calculation of \( \Delta E \geq 5.3 \times 10^{-27} \text{ J} \).
This uncertainty not only highlights the fundamental limits of precision in measuring energy over time but also dictates the precision with which we can ascertain other properties of emitted particles, like their wavelength.
Photon Emission
Understanding photon emission helps us predict how atoms release energy and the kind of light they produce. In this exercise, we investigate photons with a wavelength of \( 500 \text{ nm} \). Using the known constants, we calculated the energy of this emitted photon to be approximately \( 3.972 \times 10^{-19} \text{ J} \).
One important aspect of photon emission is its link to the energy-time uncertainty. The uncertainty in the energy of the photon (\( \Delta E \)) directly affects how precisely we can measure the wavelength, making the understanding of this process essential for predicting light behavior in various scientific fields.
Wavelength Uncertainty
The exercise guides us to compute \( \Delta \lambda \,/\, \lambda \), representing the fractional wavelength uncertainty. It's calculated from the earlier determined \( \Delta E \) and the given \( \lambda \) value. This calculation results in \( \Delta \lambda \approx 6.63 \times 10^{-12} \text{ m} \), and \( \Delta \lambda / \lambda \approx 1.326 \times 10^{-8} \).
This means that while the wavelength can be precisely measured, there's always an inherent uncertainty due to the quantum mechanical principles. Comprehending wavelength uncertainty is crucial for applications requiring high precision, such as spectroscopy and quantum computing, where slight changes in wavelength can lead to significant variations in outcomes.