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In a cylinder of an automobile engine, just after combustion, the gas is confined to a volume of \(50.0 \mathrm{cm}^{3}\) and has an initial pressure of \(3.00 \times 10^{6} \mathrm{Pa}\). The piston moves outward to a final volume of \(300 \mathrm{cm}^{3},\) and the gas expands without energy loss by heat. (a) If \(\gamma=1.40\) for the gas, what is the final pressure? (b) How much work is done by the gas in expanding?

Short Answer

Expert verified
The final pressure \(P_f\) is approximately \(505 \, kPa\) and the work done by the gas is \(-257.5 \, J\).

Step by step solution

01

Initial Parameters

Initially, it is given that the volume of the gas, \(V_i = 50.0 \, cm^{3}\), the initial pressure, \(P_i = 3.00 \times 10^{6} \, Pa\) and \( \gamma = 1.40\). Convert the initial volume from \(cm^{3}\) to \(m^{3}\): \(V_i = 50.0 \times 10^{-6} \, m^{3}\). The final volume, \(V_f = 300 \, cm^{3} = 300 \times 10^{-6} \, m^{3}\).
02

Apply the adiabatic equation

The adiabatic process equation is given by: \(P_i V_i^{\gamma} = P_f V_f^{\gamma}\). Where, \(P_f\) is the final pressure that we are required to calculate. Solve this equation for \(P_f\) to find: \(P_f = P_i (V_i/V_f)^{\gamma}\).
03

Substitute the values in equation to find \(P_f\)

Substitute the known values into the equation to compute the final pressure: \(P_f = (3.00 \times 10^{6} \, Pa) (50.0 \times 10^{-6} / 300 \times 10^{-6})^{1.4}.\) After calculating, we get \(P_f = 504719 \, Pa\) or \(505 \, kPa\).
04

Work done calculation formula and substitution

The work done by the gas in the adiabatic process is given by: \(W = (P_f V_f - P_i V_i) / (1 - \gamma)\). Substitute known values into the equation: \(W = ((504719 \, Pa * 300 \times 10^{-6} \, m^3) - (3.00 \times 10^6 \, Pa * 50.0 \times 10^{-6} \, m^3)) / (1 - 1.4)\). After calculating, we find the work done by the gas is approximately \(W = -257.5 \, J\). The negative sign indicates that work is done by the gas on the surroundings, so the system is losing energy.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Thermodynamics
Understanding thermodynamics is essential when exploring the behavior of gases during processes like the adiabatic expansion of a car engine's cylinder. Thermodynamics deals with heat, work, and temperature, and their relation to energy, radiation, and physical properties of matter. The fundamental principles of thermodynamics are encapsulated in its four laws, which lay the groundwork for various concepts regarding the conservation of energy and the directionality of processes.

The adiabatic process, which this exercise examines, is particularly important in thermodynamics. It is a process where no heat is transferred to or from the system, meaning the system is insulated from its surroundings. In the context of an automobile engine, the adiabatic process describes the expansion of gases post-combustion when energy is conserved within the system, and no heat is exchanged with the engine or surroundings. This is an idealized scenario often used to simplify calculations and understand the fundamental behavior of gases under certain constraints.
Gas Expansion
The expansion of a gas refers to the increase in its volume, which is a common phenomenon in thermodynamic processes, especially in engines where combustion leads to high-pressure gases that push pistons outward. Expansion is inherently related to the concept of work, as when gas expands against a force, it performs work on its surroundings.

In an adiabatic expansion, the energy to perform this work comes from the internal energy of the gas since heat exchange is disallowed. Understanding the nature of this expansion is crucial because it allows the prediction of changes in properties like temperature and pressure, which in turn informs the efficiency and work output of mechanical systems such as engines. It’s emphasized from the exercise that knowing the initial and final volumes of a gas, along with its pressure and specific heat ratios, allows us to calculate other thermodynamic properties using the appropriate equations.
Work Done by Gas
When tackling problems regarding the work done by a gas, it is important to recognize that work represents energy transfer. In the context of a gas expanding adiabatically, we focus on work done by the gas during its change in volume. The calculation of this work is crucial for understanding power generation and efficiency in thermal systems.

Mathematically, the work done in an adiabatic process can be determined using specific equations derived from the first law of thermodynamics. The negative result obtained in the exercise suggests that the gas does work on its surroundings, consistent with the conception that an expanding gas in an engine cylinder pushes the piston. Understanding this concept helps students grasp why and how internal combustion engines convert fuel into mechanical energy.

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Most popular questions from this chapter

Suppose a heat engine is connected to two energy reservoirs, one a pool of molten aluminum \(\left(660^{\circ} \mathrm{C}\right)\) and the other a block of solid mercury \(\left(-38.9^{\circ} \mathrm{C}\right) .\) The engine runs by freezing \(1.00 \mathrm{g}\) of aluminum and melting \(15.0 \mathrm{g}\) of mercury during each cycle. The heat of fusion of aluminum is \(3.97 \times 10^{5} \mathrm{J} / \mathrm{kg}\); the heat of fusion of mercury is \(1.18 \times 10^{4} \mathrm{J} / \mathrm{kg} .\) What is the efficiency of this engine?

Here is a clever idea. Suppose you build a two-engine device such that the exhaust energy output from one heat engine is the input energy for a second heat engine. We say that the two engines are running in series. Let \(e_{1}\) and \(e_{2}\) represent the efficiencies of the two engines. (a) The overall efficiency of the two-engine device is defined as the total work output divided by the energy put into the first engine by heat. Show that the overall efficiency is given by $$e=e_{1}+e_{2}-e_{1} e_{2}$$ (b) What If? Assume the two engines are Carnot engines. Engine 1 operates between temperatures \(T_{h}\) and \(T_{i} .\) The gas in engine 2 varies in temperature between \(T_{i}\) and \(T_{c}\) In terms of the temperatures, what is the efficiency of the combination engine? (c) What value of the intermediate temperature \(T_{i}\) will result in equal work being done by each of the two engines in series? (d) What value of \(T_{i}\) will result in each of the two engines in series having the same efficiency?

In making raspberry jelly, \(900 \mathrm{g}\) of raspberry juice is combined with \(930 \mathrm{g}\) of sugar. The mixture starts at room temperature, \(23.0^{\circ} \mathrm{C},\) and is slowly heated on a stove until it reaches \(220^{\circ} \mathrm{F}\). It is then poured into heated jars and allowed to cool. Assume that the juice has the same specific heat as water. The specific heat of sucrose is \(0.299 \mathrm{cal} / \mathrm{g} \cdot^{\circ} \mathrm{C}\) Consider the heating process. (a) Which of the following terms describe(s) this process: adiabatic, isobaric, isothermal, isovolumetric, cyclic, reversible, isentropic? (b) How much energy does the mixture absorb? (c) What is the minimum change in entropy of the jelly while it is heated?

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An ideal gas is taken through a Carnot cycle. The isothermal expansion occurs at \(250^{\circ} \mathrm{C},\) and the isothermal compression takes place at \(50.0^{\circ} \mathrm{C}\). The gas takes in \(1200 \mathrm{J}\) of energy from the hot reservoir during the isothermal expansion. Find (a) the energy expelled to the cold reservoir in each cycle and (b) the net work done by the gas in each cycle.

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