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One mole of an ideal gas is contained in a cylinder with a movable piston. The initial pressure, volume, and temperature are \(P_{i}, V_{i},\) and \(T_{i},\) respectively. Find the work done on the gas for the following processes and show each process on a PV diagram: (a) An isobaric compression in which the final volume is half the initial volume. (b) An isothermal compression in which the final pressure is four times the initial pressure. (c) An isovolumetric process in which the final pressure is three times the initial pressure.

Short Answer

Expert verified
The work done on the gas is as follows: (a) In the isobaric compression, the work done is \(0.5P_{i}V_i\). (b) In the isothermal compression, the work done is \(P_{i}V_{i}ln(4)\). (c) In the isovolumetric process, the work done is 0.

Step by step solution

01

Understand and define isobaric process

An isobaric process is one in which pressure remains constant. By definition, work done, \(W\), for an isobaric process can be calculated from the equation \(W = -PΔV\), where \(P\) is the pressure and \(ΔV\) is the change in volume. For (a), the final volume is half the initial volume, therefore \(ΔV = V_f - V_i = 0.5V_i - V_i = -0.5V_i\). Substituting the values in the formula would lead to: \(W = -P_{i} * -0.5V_{i} = 0.5P_{i}V_i\).
02

Understand and define isothermal process

An isothermal process is one which takes place at a constant temperature. For an isothermal compression, the equation for work done is \(W = P_{i}V_{i}ln(V_{i}/V_f)\), \(V_f\) is the final volume and \(P_f\) is the final pressure. As per (b), the final pressure is four times the initial pressure (\(P_f = 4P_i\)). Since the gas is ideal and the process is isothermal, \(P_{i}V_{i} = P_{f}V_{f}\). We have: \(P_{i}V_{i} = 4P_{i}V_{f}\) which implies \(V_{f} = V_{i}/4\). Substituting this result back into the work done formula gives: \(W = P_{i}V_{i}ln(V_{i}/(V_{i}/4)) = P_{i}V_{i}ln(4)\).
03

Understand and define isovolumetric process

An isovolumetric process is one in which, volume remains constant. In these processes, because there is no change in volume, the work done on the gas is 0. Hence, for process (c), \(W = 0\).
04

Represent processes on a PV diagram

(a) An isobaric compression is represented by a horizontal line moving leftwards on a PV diagram. (b) An isothermal compression is represented by a curved line that goes upwards on the PV diagram. (c) An isovolumetric process is represented by a vertical line, because volume is unchanged.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Isobaric Process
An isobaric process in thermodynamics is one where the pressure remains constant while other parameters, like volume and temperature, might change. In this type of process, work is done when the volume of the gas changes. This can be either expansion or compression.

**Calculation of Work Done**
The work done in an isobaric process can be easily calculated using the formula: \[ W = -P \Delta V \]where \(W\) is the work done, \(P\) is the pressure (which remains constant), and \(\Delta V\) is the change in volume.

**Example in Ideal Gas**
For instance, if a gas is compressed from its initial volume to half of its initial volume at constant pressure, the work done would be positive, indicating work on the gas as: \[ W = 0.5 P_i V_i \]Here, \(V_i\) is the initial volume, and \(P_i\) is the initial pressure.

**PV Diagram Representation**
In a PV diagram, an isobaric process is represented by a horizontal line, reflecting constant pressure, where the direction indicates whether it's an expansion (right) or compression (left).
Isothermal Process
In an isothermal process, the temperature of the system remains unchanged. This means that the gas adapits to any change in pressure or volume such that the product \(PV\) remains constant, as outlined by the ideal gas law \(PV = nRT\).

**Recognizing Isothermal Processes**
  • Constant temperature
  • Heat exchange with surroundings maintains consistent temperature
  • Often noted in systems allowing heat flow such as pistons

**Work Done in Isothermal Process**
The formula for work done in an isothermal process is: \[ W = P_i V_i \ln \left( \frac{V_i}{V_f} \right) \]
This relationship depicts that for a gas compressing isothermally, where final pressure is increased, the work done is found in relation to volume change and temperature balance.

**Graphical Representation on PV Diagram**
On a PV diagram, an isothermal process is depicted by a curved path, indicating simultaneous change in both pressure and volume under a steady temperature. This curve moves in the direction of either expansion or compression, typically classified as hyperbolic, reflecting continuous temperature.
Isovolumetric Process
An isovolumetric process, also known as an isochoric process, occurs when the volume of the gas remains constant. This implies that there is no work done on or by the system, because work is a result of volume change.

**Characteristics of Isovolumetric Processes**
  • Volume is constant
  • Pressure can vary
  • No work done as \( \Delta V = 0 \)

Consequently, since work \(W\) is calculated by the formula \( W = P \Delta V \) and \( \Delta V = 0 \), the work done in this process remains zero, regardless of pressure changes.

**PV Diagram Representation**
On the PV diagram, an isovolumetric process is shown as a vertical line. This reinforces that as the pressure alters, the volume does not change, reflecting a purely vertical path on the graph.
PV Diagram
A PV (pressure-volume) diagram is a powerful graphical representation used in thermodynamics to illustrate the changes in pressure, volume, and sometimes temperature of a system during various processes.

**Understanding PV Diagrams**
  • Y-axis represents pressure
  • X-axis represents volume
  • Lines and curves illustrate state changes

**Using PV Diagrams**
- **Isobaric Process:** Shown as a horizontal line; reflects constant pressure as volume changes.

- **Isothermal Process:** Illustrated by a curve that signifies continuous temperature during volume and pressure changes; often lies towards the hyperbolic shape.

- **Isovolumetric Process:** Displayed as a vertical line, marking changes in pressure or temperature while maintaining volume integrity.

PV diagrams are critical tools to visually interpret and analyze the behavior of gas during thermodynamic processes.
Work Done in Thermodynamics
Work done in thermodynamics relates to energy transferred to or from a system through its boundary. In gas processes, work can be done by the gas on its surroundings or on the gas by the surroundings.

**Calculating Work Done**
The general formula for work done, when considering volume change, is: \[ W = \int P \, dV \]This integral signifies the area under the curve on a PV diagram. For standard processes, simplified equations like isobaric (\(W = -P \Delta V\)) or isothermal (\(W = P_i V_i \ln (V_i/V_f)\)) calculations are often applied.

**Direction of Work**
  • Work done by the system is positive
  • Work done on the system is negative

Work done in these processes showcases the energy interactions between a gas system and its environment during various thermodynamic transformations.

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