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Argon is a monatomic gas whose atomic mass is 39.9 u. The temperature of eight grams of argon is raised by 75 \(\mathrm{K}\) under conditions of constant pressure. Assuming that argon behaves as an ideal gas, how much heat is required?

Short Answer

Expert verified
312.3 J

Step by step solution

01

Calculate the number of moles of Argon

The atomic mass of argon is 39.9 u, which means 1 mole of argon has a mass of 39.9 grams. Since we have 8 grams of argon, the number of moles can be calculated as: \( n = \frac{\text{mass}}{\text{molar mass}} = \frac{8}{39.9} \approx 0.2005 \) moles.
02

Determine the molar heat capacity at constant pressure

For a monatomic ideal gas, the molar heat capacity at constant pressure is given by: \( C_p = \frac{5}{2}R \), where \( R \) is the ideal gas constant \( R = 8.314 \text{ J/mol K} \). Thus, the molar heat capacity is \( C_p \approx 20.785 \text{ J/mol K} \).
03

Calculate the heat required using the formula Q = nCpΔT

The heat added to the gas can be calculated using the formula \( Q = nC_p\Delta T \), where \( \Delta T = 75 \text{ K} \) is the change in temperature. Substituting the known values: \( Q = 0.2005 \times 20.785 \times 75 \approx 312.3 \text{ J} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Behavior
In understanding heat transfer in gases, it's important to consider the concept of ideal gas behavior. An ideal gas is a theoretical gas composed of many randomly moving point particles that interact only through elastic collisions. These gases follow a simple set of rules outlined in the ideal gas law, which is given by the equation \( PV = nRT \), where:
  • \( P \) is the pressure of the gas.
  • \( V \) is the volume of the gas.
  • \( n \) is the number of moles of the gas.
  • \( R \) is the ideal gas constant, approximately 8.314 J/mol·K.
  • \( T \) is the temperature of the gas.
Assuming a gas behaves ideally means assuming it follows these laws under most conditions, not being influenced by the volume of the particles themselves or any intermolecular forces. This assumption simplifies calculations such as determining heat capacity or amount of heat required for temperature changes in gases. For the exercise, assuming that argon behaves as an ideal gas allows us to use standard formulas to find the heat needed to raise its temperature.
Molar Heat Capacity
The molar heat capacity of a substance indicates how much heat is required to raise the temperature of one mole of the substance by one Kelvin. For gases, it's often convenient to consider the heat capacity at constant pressure (\( C_p \)). For monatomic gases like argon, \( C_p \) is known to be \( \frac{5}{2}R \). Given \( R \) is 8.314 J/mol·K, we find:
  • \( C_p = \frac{5}{2} \times 8.314 \approx 20.785 \text{ J/mol K} \)
This value is broadly applicable to all monatomic gases behaving ideally under similar conditions. Understanding \( C_p \) is crucial for determining how much heat energy is required to effect a temperature change under constant pressure conditions, as the heat required is given by \( Q = nC_p\Delta T \). This helps comprehend the energy dynamics involved in practical applications like heating gases in industrial processes.
Calculation of Moles
Calculating the number of moles is a fundamental step in solving many problems related to gases, including heat transfer. Moles are a measure of quantity that relates directly to the atomic or molecular scale of the substance. For argon, due to its atomic mass of 39.9 grams per mole, we can determine the number of moles present in a given mass using the formula:
  • \( n = \frac{\text{mass of the substance}}{\text{molar mass}} \)
  • In the exercise, \( n = \frac{8}{39.9} \approx 0.2005 \text{ moles} \)
This calculation is essential because it links the macroscopic measurements of mass and energy to the molecular scale through the ideal gas law and thermodynamic equations. It's a foundational element for being able to further determine energy transfers and transformations, such as heating, in gas systems.
Temperature Change Effects
When examining how temperature change affects a gas, especially in the context of heat transfer, it's vital to understand how energy relates to thermal changes. The change in temperature (\( \Delta T \)) directly determines the amount of heat energy required to increase that temperature, calculated using the formula \( Q = nC_p\Delta T \).
  • \( \Delta T \) represents the change in temperature, which in this scenario is 75 K.
  • \( Q \) is the heat added or removed.
  • \( n \) and \( C_p \) have been previously determined.
With \( C_p \) for argon being 20.785 J/mol·K and \( n \) being 0.2005 moles, the formula allows for computing the heat required as \( Q \approx 312.3 \text{ J} \). Recognizing how temperature alterations impact heat energy surrounds the ability to control and predict thermal processes in gases, crucial for various applications, from scientific research to industrial operations.

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Most popular questions from this chapter

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