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The internal energy of a system changes because the system gains 165 \(\mathrm{J}\) of heat and performs 312 \(\mathrm{J}\) of work. In returning to its initial state, the system loses 114 \(\mathrm{J}\) of heat. During this return process, (a) what work is involved, and \((\mathrm{b})\) is the work done by the system or on the system?

Short Answer

Expert verified
(a) 114 J of work is involved. (b) Work is done on the system.

Step by step solution

01

Understanding the Problem

To solve the problem, we need to determine the work involved when the system returns to its initial state, given that it loses 114 J of heat during this process. Additionally, we need to determine if the work is done by the system or on the system.
02

Analyzing the First Process

In the initial process, the system gains 165 J of heat and performs 312 J of work. According to the first law of thermodynamics, \( \Delta U = Q - W \), where \( \Delta U \) is the change in internal energy, \( Q \) is the heat added to the system, and \( W \) is the work done by the system. So, \( \Delta U = 165 \ \text{J} - 312 \ \text{J} = -147 \ \text{J} \).
03

Analyzing the Return Process

When the system returns to its initial state, \( \Delta U = 0 \). Therefore, the heat lost \( Q' = -114 \ \text{J} \) and the work done \( W' \) in this process must satisfy \( 0 = -114 \ \text{J} - W' \).
04

Solving for Work in Return Process

Rearranging the equation from Step 3, we get \( W' = -114 \ \text{J} \). This indicates that 114 J of work is done on the system to compensate for the heat lost.
05

Determining the Nature of Work

Since \( W' = -114 \ \text{J} \), the negative sign indicates the work is done on the system. When work is done on the system, it indicates the system is being compressed or energy is being added.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Internal Energy
In thermodynamics, internal energy is a very important concept. It represents the total energy contained within a system, including both kinetic and potential energies of all particles. The first law of thermodynamics helps us understand how this internal energy changes. It states that the change in internal energy (\( \Delta U \)) of a system is equal to the heat added to the system (\( Q \)) minus the work done by the system (\( W \)).
The equation is expressed as:
  • \( \Delta U = Q - W \)
Consider an example where a system gains 165 J of heat and performs 312 J of work. The change in internal energy here is:
  • \( \Delta U = 165 \, \text{J} - 312 \, \text{J} = -147 \, \text{J} \)
This result tells us that the system's internal energy decreases by 147 J.
Understanding these changes is vital for analyzing how energy transformations take place in physical processes.
Work Done on a System
Work and thermodynamics go hand in hand. The work done on or by a system plays a crucial role in energy transformations. When we say work is done "on" the system, external forces are compressing or transferring energy into the system.
In our exercise, when the system returns to its initial state, we calculate the work done during this phase as follows. According to the problem, 114 J of heat is lost. Since no net change in internal energy occurs during the whole cycle, we have:
  • \( 0 = -114 \, \text{J} - W' \)
From here, solving for work (\( W' \)), we find:
  • \( W' = -114 \, \text{J} \)
This negative sign indicates that 114 J of work is done on the system. In practice, this would mean external compression or another form of energy insertion.
By knowing whether work is done on or by the system, one can predict how energy transformations affect the system's state.
Heat Loss
Heat loss signifies the transfer of thermal energy from a system to its surroundings. In thermodynamic processes, this often results in a decrease in the system's internal energy.
Referring to our given scenario, after the system performed 312 J of work, it returns to its initial state by losing 114 J of heat. This is typical in cyclical processes, where the exchange of energy ensures no net gain or loss of internal energy over a full cycle.
  • The heat lost was \(-114\, \text{J} \), a clear indicator of energy moving out of the system.
Understanding heat loss is fundamental to thermodynamics. This transfer of energy helps in diagnosing how systems interact with their environments and aids in maximizing efficiency or altering states via heating and cooling mechanisms.
Recognizing how heat behaves in a system gives insight into the broader understanding of processes and their thermodynamic cycles.

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Most popular questions from this chapter

An air conditioner keeps the inside of a house at a temperature of \(19.0^{\circ} \mathrm{C}\) when the outdoor temperature is \(33.0^{\circ} \mathrm{C} .\) Heat, leaking into the house at the rate of 10500 joules per second, is removed by the air conditioner. Assuming that the air conditioner is a Carnot air conditioner, what is the work per second that must be done by the electrical energy in order to keep the inside temperature constant?

Suppose that 31.4 \(\mathrm{J}\) of heat is added to an ideal gas. The gas expands at a constant pressure of \(1.40 \times 10^{4}\) Pa while changing its volume from \(3.00 \times 10^{-4}\) to \(8.00 \times 10^{-4} \mathrm{m}^{3}\) . The gas is not monatomic, so the relation \(C_{P}=\frac{5}{2} R\) does not apply. (a) Determine the change in the internal energy of the gas. (b) Calculate its molar specific heat capacity \(C_{p} .\)

Consider three engines that each use 1650 \(\mathrm{J}\) of heat from a hot reservoir (temperature \(=550 \mathrm{K} ) .\) These three engines reject heat to a cold reservoir (temperature \(=330 \mathrm{K} ) .\) Engine I rejects 1120 \(\mathrm{J}\) of heat. Engine II rejects 990 \(\mathrm{J}\) of heat. Engine III rejects 660 \(\mathrm{J}\) of heat. One of the two irreversible engines, one violates the second law of thermodynamics and could not exist. For each of the engines determine the total entropy change of the universe, which is the sum of the entropy changes of the hot and cold reservoirs. On the basis of your calculations, identify which engine operates reversibly, which operates irreversibly and could exist, and which operates irreversibly and could not exist.

A monatomic ideal gas is heated while at a constant volume of \(1.00 \times 10^{-3} \mathrm{m}^{3},\) using a ten-watt heater. The pressure of the gas increases by \(5.0 \times 10^{4}\) Pa. How long was the heater on?

Five moles of a monatomic ideal gas expand adiabatically, and its temperature decreases from 370 to 290 \(\mathrm{K}\) . Determine \(\quad\) (a) the work done (including the algebraic sign) by the gas, and (b) the change in its internal energy.

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