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One-half mole of a monatomic ideal gas absorbs \(1200 \mathrm{~J}\) of heat while \(2500 \mathrm{~J}\) of work is done by the gas. (a) What is the temperature change of the gas? (b) Is the change an increase or a decrease?

Short Answer

Expert verified
The temperature decreases by 208.5 K.

Step by step solution

01

Identify the problem and given data

The problem provides a scenario where a monatomic ideal gas absorbs heat and does work. We must find the temperature change of the gas. The known values are 0.5 moles, 1200 J of heat absorbed, and 2500 J of work done.
02

Apply the first law of thermodynamics

The first law of thermodynamics states \( \Delta U = Q - W \), where \( \Delta U \) is the change in internal energy, \( Q \) is the heat added to the system, and \( W \) is the work done by the system. Substitute the given values: \( \Delta U = 1200 \, \text{J} - 2500 \, \text{J} = -1300 \, \text{J} \).
03

Relate internal energy change to temperature change

For a monatomic ideal gas, the change in internal energy can also be expressed as \( \Delta U = \frac{3}{2} n R \Delta T \), where \( n \) is the number of moles, \( R = 8.314 \, \text{J/mol·K} \) is the gas constant, and \( \Delta T \) is the temperature change. Set \( \Delta U = -1300 \, \text{J} \) and solve for \( \Delta T \).
04

Calculate temperature change

Substitute the values into the formula: \(-1300 = \frac{3}{2} \times 0.5 \times 8.314 \times \Delta T \). Simplify and solve for \( \Delta T \): \(-1300 = 6.2355 \times \Delta T \), thus \( \Delta T \approx -208.5 \, \text{K} \).
05

Determine the direction of temperature change

Since \( \Delta T = -208.5 \, \text{K} \), the temperature change is a decrease of 208.5 K.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Monatomic Ideal Gas
A monatomic ideal gas consists of single-atom molecules, like helium or neon. Ideal gases follow the ideal gas law, which assumes that:
  • Particles are in constant random motion, colliding elastically with each other and the walls of the container.
  • The volume of gas particles themselves is negligible compared to the volume of their container.
  • No forces act upon the gas particles except during collisions.
These properties make ideal gases simple to analyze using fundamental thermodynamic equations. When dealing with a monatomic ideal gas, we often engage with concepts such as pressure, volume, temperature, and internal energy. Its behavior is governed by statistical mechanics and can be described accurately by mathematical models like the one used in the exercise.
Internal Energy
Internal energy in thermodynamics refers to the total energy contained within a system, largely due to the random motion of its particles. For a monatomic ideal gas, the internal energy depends only on its temperature and is given by:\[ U = \frac{3}{2} nRT \]Here, \( n \) is the number of moles and \( R \) is the ideal gas constant. Internal energy changes when heat is added or removed or when work is done by or on the system. According to the first law of thermodynamics, \[ \Delta U = Q - W \]where \( Q \) is the heat transferred to the system, and \( W \) is the work done by the system. In the given problem, the internal energy decreases by 1300 J as the gas performs work while absorbing heat, illustrating these dynamic exchanges.
Temperature Change
The temperature of a gas often changes when heat is absorbed or when work is performed. In the context of a monatomic ideal gas, the change in temperature is directly linked to a change in its internal energy.For this exercise, we apply the equation relating change in internal energy to temperature change:\[ \Delta U = \frac{3}{2} nR \Delta T \]Given the change in internal energy \( \Delta U = -1300 \text{ J} \) and known values for \( n \) and \( R \), we can solve for the temperature change \( \Delta T \). Substituting the given values shows that \( \Delta T \approx -208.5 \text{ K} \), indicating a decrease in temperature due to a net energy reduction.
Work Done
Work done by a gas involves energy being transferred as the gas expands or contracts against an external pressure. In this problem, 2500 J of work is done by the monatomic ideal gas, which expands while doing so. This work contributes to the decrease in the system’s internal energy as part of the energy is used to perform work rather than increasing the internal energy. This principle highlights the trade-off in energy distribution according to the first law of thermodynamics:\[ \Delta U = Q - W \]As the gas does work, its tendency is to lose internal energy, emphasizing that energy within a system can take different forms, such as kinetic (increasing motion) or being utilized in external work.
Heat Absorbed
Heat absorbed by a system is one form of energy transfer that can lead to an increase in the system’s internal energy. It involves the introduction of external energy into the gas, which could result in increased particle motion, increasing the temperature.In this scenario, the monatomic ideal gas absorbs 1200 J of heat. However, because the gas also does 2500 J of work, the overall internal energy decreases. This net effect on internal energy is quantitatively expressed as:\[ \Delta U = Q - W = 1200 \text{ J} - 2500 \text{ J} = -1300 \text{ J} \]Hence, even as it absorbs heat, more energy is expended in doing work, resulting in a decrease in temperature, demonstrating how heat and work are interconnected in thermodynamic processes.

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Most popular questions from this chapter

Multiple-Concept Example 6 deals with the same concepts as this problem does. What is the efficiency of a heat engine that uses an input heat of \(5.6 \times 10^{4} \mathrm{~J}\) and rejects \(1.8 \times 10^{4} \mathrm{~J}\) of heat?

A Carnot refrigerator transfers heat from its inside \(\left(6.0^{\circ} \mathrm{C}\right)\) to the room air outside \(\left(20.0^{\circ} \mathrm{C}\right)\). (a) Find the coefficient of performance of the refrigerator. (b) Determine the magnitude of the minimum work needed to \(\operatorname{cool} 5.00 \mathrm{~kg}\) of water from 20.0 to \(6.0^{\circ} \mathrm{C}\) when it is placed in the refrigerator.

The pressure of a monatomic ideal gas \(\left(\gamma=\frac{5}{3}\right)\) doubles during an adiabatic compression. What is the ratio of the final volume to the initial volume?

A monatomic ideal gas has an initial temperature of \(405 \mathrm{~K}\). This gas expands and does the same amount of work whether the expansion is adiabatic or isothermal. When the expansion is adiabatic, the final temperature of the gas is \(245 \mathrm{~K}\). What is the ratio of the final to the initial volume when the expansion is isothermal?

\(55 \mathrm{~m}\) A monatomic ideal gas \(\left(\gamma=\frac{5}{3}\right)\) is contained within a perfectly insulated cylinder that is fitted with a movable piston. The initial pressure of the gas is \(1.50 \times 10^{5} \mathrm{~Pa}\). The piston is pushed so as to compress the gas, with the result that the Kelvin temperature doubles. What is the final pressure of the gas?

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