/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 53 Estimate the spacing between the... [FREE SOLUTION] | 91Ó°ÊÓ

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Estimate the spacing between the centers of neighboring atoms in a piece of solid aluminum, based on a knowledge of the density \(\left(2700 \mathrm{~kg} / \mathrm{m}^{3}\right)\) and atomic mass (26.9815 u) of aluminum.

Short Answer

Expert verified
The spacing between centers of aluminum atoms is approximately 0.252 nm.

Step by step solution

01

Understand the Density Formula

Density (\( \rho \)) is defined as mass per unit volume. The formula is: \[ \rho = \frac{m}{V} \]where \( m \) is the mass and \( V \) is the volume. For a given volume, the mass can be found using this formula if the density is known.
02

Convert Atomic Mass to Kilograms

The atomic mass of aluminum is given as 26.9815 u (atomic mass units). To find the mass in kilograms, use the conversion: \[ 1 \, \text{u} = 1.66053906660 \times 10^{-27} \, \text{kg} \]Thus, the mass of a single aluminum atom in kilograms is: \[ m = 26.9815 \, \text{u} \times 1.66053906660 \times 10^{-27} \, \text{kg/u} \approx 4.480 \times 10^{-26} \, \text{kg} \]
03

Calculate the Volume Per Atom

Given the density formula and the mass of a single aluminum atom, solve for the volume occupied by a single atom:\[ V = \frac{m}{\rho} \]Plugging in the values:\[ V = \frac{4.480 \times 10^{-26} \, \text{kg}}{2700 \, \text{kg/m}^3} \approx 1.659 \times 10^{-29} \, \text{m}^3 \]
04

Find the Edge Length of the Cube (Atom Spacing)

Assuming each atom is at the center of a cube, the volume of one cubic space around an atom can be given by \((\text{edge length})^3 = 1.659 \times 10^{-29} \, \text{m}^3\). Take the cube root to find the edge length:\[ \text{Edge length} = (1.659 \times 10^{-29} \, \text{m}^3)^{1/3} \approx 2.52 \times 10^{-10} \, \text{m} \]
05

Convert to a Convenient Unit (Optional)

Finally, convert the spacing into nanometers for easier interpretation:\[ 2.52 \times 10^{-10} \, \text{m} = 0.252 \, \text{nm} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Density Formula
The density of a material is a critical concept in understanding the properties of materials like aluminum. Density, denoted as \( \rho \), is the ratio of mass \( m \) to volume \( V \). The formula is given by:\[ \rho = \frac{m}{V} \]This tells us how much mass is packed into a unit of volume. Knowing the density allows you to determine the mass if you know the volume, or vice versa. In this way, density connects the macroscopic properties like volume and mass which are vital for calculations related to atomic structures.
  • Density is always expressed in \( \text{kg/m}^3 \) for scientific calculations.
  • For any metal like aluminum, density helps infer atomic arrangements.
For our exercise, aluminum's density is \( 2700 \, \text{kg/m}^3 \). This helps us find out how tightly packed the aluminum atoms are within a solid structure.
Atomic Mass
Atomic mass is an essential parameter in calculations involving atoms. It is usually expressed in atomic mass units (u), where 1 u is approximately equal to the mass of a single nucleon. For aluminum, the atomic mass is \( 26.9815 \text{ u} \). To incorporate this value into our calculations, especially in the density formula, we need to convert it into kilograms:

- First, remember that 1 u equals \( 1.66053906660 \times 10^{-27} \text{ kg} \).- Thus, the mass of a single aluminum atom is \[ m = 26.9815 \times 1.66053906660 \times 10^{-27} \approx 4.480 \times 10^{-26} \text{ kg} \]This conversion allows us to integrate atomic mass into our density-related calculations and helps coordinate between atomic scale and practical measurements.
Volume Calculation
Calculating the volume occupied by a single atom is crucial for understanding atomic spacing. Given the mass of an aluminum atom and the density of aluminum, we use the formula to find volume from density:\[ V = \frac{m}{\rho} \]This calculation supplies the volume that an individual atom occupies in the solid matrix.
  • For aluminum, using the mass \( 4.480 \times 10^{-26} \text{ kg} \) and density \( 2700 \text{ kg/m}^3 \), we calculate:
  • \( V \approx 1.659 \times 10^{-29} \text{ m}^3 \)
This volume measured is immensely small but signifies the space an aluminum atom occupies and is useful in deducing how tightly atoms are placed in a material, as further shown by the cube root calculation.
Cube Root Calculation
Once we determine the volume per atom, we treat this as the volume of a cube, with the atom centrally placed. To find the atomic spacing, which is the edge of the cube, we calculate the cube root of the volume:

- Volume of one cube: is calculated as \( 1.659 \times 10^{-29} \text{ m}^3 \).- The edge length, or atomic spacing, is calculated by cube rooting the found volume:\[ \text{Edge length} = (1.659 \times 10^{-29} \text{ m}^3)^{1/3} \approx 2.52 \times 10^{-10} \text{ m} \]This edge length represents the spacing between the centers of neighboring atoms in aluminum. For easier interpretation in nanometers, this is \( 0.252 \text{ nm} \). Understanding this spacing is key for insights into material properties like strength and conductivity.

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Most popular questions from this chapter

A spherical balloon is made from a material whose mass is \(3.00 \mathrm{~kg} .\) The thickness of the material is negligible compared to the 1.50 -m radius of the balloon. The balloon is filled with helium (He) at a temperature of \(305 \mathrm{~K}\) and just floats in air, neither rising nor falling. The density of the surrounding air is \(1.19 \mathrm{~kg} / \mathrm{m}^{3}\). Find the absolute pressure of the helium gas.

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