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A 350 -mL spherical flask contains 0.075 mol of an ideal gas at a temperature of \(293 \mathrm{K}\). What is the average force exerted on the walls of the flask by a single molecule?

Short Answer

Expert verified
The average force exerted on the walls by a single molecule is approximately \(2.66 \times 10^{-19}\) N.

Step by step solution

01

Identify Key Variables

To solve this, we need to extract the given values from the problem statement. We are given: the volume of the flask = 350 mL (which is 0.350 L), the amount of gas = 0.075 mol, and the temperature = 293 K. These will be used along with the ideal gas law.
02

Convert Volume to m³

We need the volume in cubic meters for calculations:\[350 \text{ mL} = 0.350 \text{ L} = 0.350 \times 10^{-3} \text{ m}^3 = 3.50 \times 10^{-4} \text{ m}^3\]
03

Calculate Pressure Using the Ideal Gas Law

We apply the ideal gas law \( PV = nRT \) to find the pressure. Here, \( R = 8.314 \text{ J/(mol K)} \):\[ P = \frac{nRT}{V} = \frac{0.075 \times 8.314 \times 293}{3.50 \times 10^{-4}} \approx 522125 \text{ Pa} \]
04

Convert Pressure to Force

To find the total force on the container, we multiply pressure by the surface area. For a spherical flask with radius \( r \), \( A = 4\pi r^2 \):- First find the radius: \( V = \frac{4}{3}\pi r^3 \Rightarrow r = \left( \frac{3V}{4\pi} \right)^{1/3} \approx 0.043 \text{ m} \)- Use the surface area formula \( A = 4\pi (0.043)^2 \approx 0.023 \text{ m}^2 \)- Force \( F = PA = 522125 \times 0.023 \approx 12000 \text{ N} \)
05

Calculate the Number of Molecules

Using Avogadro's number \(6.022 \times 10^{23} \text{ molecules/mol}\), calculate the total number of molecules:\[ 0.075 \text{ mol} \times 6.022 \times 10^{23} \approx 4.517 \times 10^{22} \text{ molecules} \]
06

Average Force Per Molecule

To find the average force per molecule, divide the total force by the total number of molecules:\[ \text{Average Force} = \frac{12000 \text{ N}}{4.517 \times 10^{22}} \approx 2.66 \times 10^{-19} \text{ N}\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Average Force
When studying an ideal gas enclosed in a spherical flask, one key parameter to determine is the average force exerted by individual molecules on the container walls. This average force helps understand molecular interactions at a microscopic level.
To calculate this, we first determine the total force exerted by the gas, which is obtained from the pressure applied over the flask's surface area. As described in the step-by-step solution, once the total force is known, we utilize Avogadro's number to find the number of gas molecules within the flask.
Finally, dividing the total force by the number of molecules yields the average force per molecule. This value, while small, reflects the persistent impact these molecules have as they collide with the container, contributing to the gas pressure.
Molecular Dynamics
Molecular dynamics is the study of how molecules move and interact with one another. In our scenario with the ideal gas in a spherical flask, molecules are in constant random motion. This results from thermal energy, where higher temperatures increase the speed and energy of molecular movement.
The average kinetic energy of these molecules can be derived from their thermal energy, and their random interactions lead to measurable macroscopic properties like temperature and pressure. Understanding molecular dynamics is crucial for predicting how changes in temperature or volume affect the gas behavior and how the average force exerted by the molecules changes in response.
  • Average kinetic energy is directly proportional to temperature.
  • Gas molecules continually collide with the flask walls, exerting force.
  • Molecular speed increases with temperature, contributing to pressure.
Pressure Calculations
Calculating pressure accurately in a contained gas system is essential for understanding how gases behave. The ideal gas law, represented as \( PV = nRT \), allows us to calculate the pressure exerted by a gas when we know the volume, temperature, and number of moles.
Pressure is defined as the force applied per unit area. In the calculation involving a spherical flask, it is necessary to find the pressure first as it is directly related to the force the gas exerts on the walls. The resulting pressure gives us insight into the amount of energy transfer happening due to molecular collisions.
  • Pressure increases with a rise in temperature or a decrease in volume.
  • More moles of gas imply higher pressure, affecting the average force.
  • Ideal gas law helps in translating macroscopic observations into molecular interactions.
Spherical Flask
A spherical flask is an important consideration when studying gas behavior because its geometric properties affect how pressure and force are distributed. The volume of a spherical flask is given by the formula \( V = \frac{4}{3}\pi r^3 \), and its surface area is \( A = 4\pi r^2 \).
The spherical shape ensures that pressure is exerted uniformly across the surface. To find the radius of the spherical flask, you can manipulate the volume formula, which is necessary for calculating both surface area and pressure-related force accurately. This information is vital when translating the macroscopic measurements, such as pressure, back into the microscopic behavior of gas molecules.
  • The spherical shape ensures even distribution of force.
  • Knowing the surface area is key to accurate force calculations.
  • Uniform pressure distribution aids in better understanding molecular interactions.

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Most popular questions from this chapter

The rms speed of \(\mathrm{O}_{2}\) is \(1550 \mathrm{m} / \mathrm{s}\) at a given temperature. (a) Is the rms speed of \(\mathrm{H}_{2} \mathrm{O}\) at this temperature greater than, less than, or equal to \(1550 \mathrm{m} / \mathrm{s}\) ? Explain. (b) Find the rms speed of \(\mathrm{H}_{2} \mathrm{O}\) at this temperature.

Suppose the Celsius temperature of an ideal gas is doubled from \(100^{\circ} \mathrm{C}\) to \(200^{\circ} \mathrm{C}\). (a) Does the average kinetic energy of the molecules in this gas increase by a factor that is greater than, less than, or equal to \(2 ?\) (b) Choose the best explanation from among the following: I. Changing the temperature from \(100^{\circ} \mathrm{C}\) to \(200^{\circ} \mathrm{C}\) goes beyond the boiling point, which will increase the kinetic energy by more than a factor of \(2 .\) II. The average kinetic energy is directly proportional to the temperature, so doubling the temperature doubles the kinetic energy. III. Doubling the Celsius temperature from \(100^{\circ} \mathrm{C}\) to \(200^{\circ} \mathrm{C}\) changes the Kelvin temperature from \(373.15 \mathrm{K}\) to \(473.15 \mathrm{K}\) which is an increase of less than a factor of 2 .

A hollow cylindrical rod (rod 1) and a a solid cylindrical rod (rod 2 ) are made of the same material. The two rods have the same length and the same outer radius. If the same compressional force is applied to each rod, (a) is the change in length of rod 1 greater than, less than, or equal to the change in length of rod \(2 ?\) (b) Choose the best explanation from among the following: I. The solid rod has the larger effective cross-sectional area, since the empty part of the hollow rod doesn't resist compression. Therefore, the solid rod has the smaller change in length. II. The rods have the same outer radius and hence the same cross-sectional area. As a result, their change in length is the same. III. The walls of the hollow rod are hard and resist compression more than the uniform material in the solid rod. Therefore the hollow rod has the smaller change in length.

Two containers hold ideal gases at the same temperature. Container A has twice the volume and half the number of molecules as container B. What is the ratio \(P_{\mathrm{A}} / P_{B},\) where \(P_{A}\) is the pressure in container A and \(P_{8}\) is the pressure in container B?

The rms speed of a sample of gas is increased by \(1 \%\). (a) What is the percent change in the temperature of the gas? (b) What is the percent change in the pressure of the gas, assuming its volume is held constant?

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