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Argon is a monatomic gas whose atomic mass is 39.9 u. The temperature of eight grams of argon is raised by \(75 \mathrm{K}\) under conditions of constant pressure. Assuming that argon behaves as an ideal gas, how much heat is required?

Short Answer

Expert verified
Approximately 312.75 J of heat is required.

Step by step solution

01

Define the Problem

We need to calculate the heat required to raise the temperature of 8 grams of argon gas by 75 K at constant pressure. Argon is a monatomic ideal gas.
02

Calculate the Moles of Argon

First, calculate the number of moles of argon. Using the formula \( n = \frac{m}{M} \), where \( m = 8 \) grams is the mass and \( M = 39.9 \) grams/mol is the molar mass of argon, we find:\[ n = \frac{8}{39.9} \approx 0.2005 \text{ moles} \]
03

Use the Ideal Gas Law for Constant Pressure

At constant pressure, the heat \( Q \) added to the gas is calculated using the formula \( Q = nC_p\Delta T \), where \( C_p \) is the molar heat capacity at constant pressure for a monatomic gas, which is \( C_p = \frac{5}{2}R \).
04

Calculate the Heat Capacity at Constant Pressure

Substitute the universal gas constant \( R = 8.314 \text{ J/mol K} \) to find \( C_p = \frac{5}{2} \times 8.314 \approx 20.785 \text{ J/mol K} \).
05

Calculate the Heat Required

Now, substitute the values into the formula from Step 3:\[ Q = nC_p\Delta T = 0.2005 \times 20.785 \times 75 \approx 312.75 \text{ J} \].

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
The Ideal Gas Law is a fundamental principle in thermodynamics, describing the behavior of an ideal gas. An ideal gas is a theoretical model that helps scientists understand real gases under many conditions. The law can be represented by the equation \( PV = nRT \), where \( P \) is pressure, \( V \) is volume, \( n \) is the number of moles, \( R \) is the universal gas constant (8.314 J/mol·K), and \( T \) is temperature in Kelvin.

This equation highlights how pressure, volume, and temperature are interrelated for a given quantity of gas.
  • For constant pressure experiments, such as heating argon in the given exercise, the changes in volume and temperature are directly correlated.
  • When the volume remains unchanged, and only temperature increases, the energy affects the pressure.
Understanding the Ideal Gas Law is crucial for calculating the heat required, as it connects pressure, volume, and temperature changes in gas systems.
Heat Capacity
Heat capacity is an essential concept in thermodynamics, especially when dealing with how substances absorb heat. It is defined as the amount of heat required to change the temperature of a substance by one degree Celsius.For gases, we often talk about molar heat capacity, which is the heat capacity per mole of substance. There are two types:
  • Molar heat capacity at constant volume (\(C_v\))
  • Molar heat capacity at constant pressure (\(C_p\))
For a monatomic ideal gas, like argon, the molar heat capacity at constant pressure \( (C_p) \) can be calculated using the formula \( C_p = \frac{5}{2}R \). This relationship enables us to determine how much heat is needed to increase argon's temperature by 75 K when it’s kept at constant pressure.

The specific heat capacity value helps predict the amount of energy required for temperature changes in a substance.
Molar Mass
Molar mass is a critical concept when dealing with gases, as it connects macroscopic properties to atomic characteristics. It is defined as the mass of one mole of a given substance, usually expressed in grams per mole (g/mol).For argon, the molar mass is 39.9 g/mol. This figure is crucial when calculating the number of moles in a sample. When given a specific mass of a substance, you can calculate the moles using the equation:

\[ n = \frac{m}{M} \]

where \( n \) is the number of moles, \( m \) is the mass in grams, and \( M \) is the molar mass.

In the exercise, 8 grams of argon are used, leading to a calculation that yields approximately 0.2005 moles. This value is necessary for figuring out the energy needed to heat the gas.
Heat Transfer
Heat transfer describes the movement of thermal energy from one object or substance to another. In thermodynamics, it's a pivotal concept, particularly for understanding temperature changes in gases.When dealing with an ideal gas under constant pressure, the heat transfer is calculated using the formula \( Q = nC_p\Delta T \):
  • \( Q \) is the heat added to the gas,
  • \( n \) is the number of moles,
  • \( C_p \) is the heat capacity at constant pressure,
  • \( \Delta T \) is the change in temperature.
In the step-by-step solution, this formula is used to determine how much heat energy is needed to increase the temperature of 8 grams of argon by 75 Kelvin.

Understanding heat transfer allows us to calculate the energy influx necessary for desired temperature modifications in various gas samples, pivotal for energy management and engineering applications.

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Most popular questions from this chapter

Suppose a monatomic ideal gas is contained within a vertical cylinder that is fitted with a movable piston. The piston is frictionless and has a negligible mass. The area of the piston is \(3.14 \times 10^{-2} \mathrm{m}^{2},\) and the pressure outside the cylinder is \(1.01 \times 10^{5}\) Pa. Heat \((2093 \mathrm{J})\) is removed from the gas. Through what distance does the piston drop?

A system gains 2780 J of heat at a constant pressure of \(1.26 \times\) \(10^{5} \mathrm{Pa},\) and its internal energy increases by \(3990 \mathrm{J} .\) What is the change in the volume of the system, and is it an increase or a decrease?

A Carnot engine operates between temperatures of 650 and \(350 \mathrm{K} .\) To improve the efficiency of the engine, it is decided either to raise the temperature of the hot reservoir by \(40 \mathrm{K}\) or to lower the temperature of the cold reservoir by \(40 \mathrm{K}\). Which change gives the greater improvement? Justify your answer by calculating the efficiency in each case.

A monatomic ideal gas \(\left(\gamma=\frac{5}{3}\right)\) is contained within a perfectly insulated cylinder that is fitted with a movable piston. The initial pressure of the gas is \(1.50 \times 10^{5}\) Pa. The piston is pushed so as to compress the gas, with the result that the Kelvin temperature doubles. What is the final pressure of the gas?

The sun is a sphere with a radius of \(6.96 \times 10^{8} \mathrm{m}\) and an average surface temperature of \(5800 \mathrm{K}\). Determine the amount by which the sun's thermal radiation increases the entropy of the entire universe each second. Assume that the sun is a perfect blackbody, and that the average temperature of the rest of the universe is \(2.73 \mathrm{K}\). Do not consider the thermal radiation absorbed by the sun from the rest of the universe.

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