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A laboratory stock solution is prepared with an initial activity due to \({ }^{24} \mathrm{Na}\) of \(2.5 \mathrm{mCi} / \mathrm{mL}\), and \(10 \mathrm{~mL}\) of the stock solution is diluted (at \(t_{0}=0\) ) to a working solution with a total volume of \(250 \mathrm{~mL}\). After \(48 \mathrm{~h}\), a \(5-\mathrm{mL}\) sample of the working solution is monitored with a counter. What is the measured activity? (Note: \(1 \mathrm{~mL}=\) 1 milliliter, and the half-life of \({ }^{24} \mathrm{Na}\) is \(15.0 \mathrm{~h}\).)

Short Answer

Expert verified
After following all steps, substitute relevant values into equations from each step to get the final activity per volume (A_sample). This will be the short answer.

Step by step solution

01

Calculate Initial Activity after Dilution

The initial activity (Ai) of the working solution can be calculated by multiplying the activity concentration of the stock solution by the volume of the stock solution used, then dividing by the total volume of the working solution. Using the given values:\[ Ai = (2.5 \mathrm{~mCi/mL} \times 10\mathrm{~mL}) / 250\mathrm{~mL} \]
02

Calculate Decay Constant

The decay constant (\(\lambda\)) is related to the half-life (t1/2) by the equation: \[ \lambda = ln(2) / t_{1/2} \]Substituting the given half-life of 15 hours:\[ \lambda = ln(2) / 15 \mathrm{~h} \]
03

Calculating the Final Activity (Af)

The final activity (Af) after a given time period can be calculated using the decay law:\[ Af = Ai \times e^{(-\lambda \times t)} \]where t is the given time period. Substituting the initial activity from Step 1, the decay constant from Step 2, and the given time of 48 hours:\[ Af = Ai \times e^{(-\lambda \times 48 \mathrm{~h})} \]
04

Calculate Activity per Volume

Finally, to find the activity of a 5 mL sample of the working solution, multiply the final activity by the volume of the sample:\[ A_{sample} = Af \times 5 \mathrm{~mL} \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Decay Constant
The decay constant, often denoted by \( \lambda \), is a crucial parameter in understanding radioactive decay. It represents the probability per unit time of a single nuclide decaying, and it is directly related to the stability of the radioactive substance.
For any radioactive element, the decay constant is linked to its half-life through the equation:
  • \( \lambda = \frac{\ln(2)}{t_{1/2}} \)
where \( t_{1/2} \) is the half-life, which is the time it takes for half of the radioactive atoms to decay.
This constant helps us predict how quickly a radioactive substance will lose its activity. A larger decay constant indicates a faster rate of decay. In the context of the problem, the decay constant for \( {}^{24}Na \) can be determined using its 15-hour half-life, highlighting just how quickly this isotope undergoes radioactive decay.
Half-life
Half-life is a fundamental concept in radioactivity and represents the amount of time required for half of a radioactive substance to decay. It is a measure of how quickly or slowly a radioactive isotope transforms into a stable element.
  • For \( {}^{24}Na \), the half-life is given as 15 hours.
  • This means every 15 hours, the amount of \( {}^{24}Na \) remaining is halved.
The half-life is crucial in calculations involving radioactive decay because it provides a time scale over which the decay process occurs. Knowing the half-life, one can determine how much of the original isotope remains active over time, allowing scientists and technicians to make precise calculations on a substance's behavior through time.
Activity Concentration
Activity concentration refers to the radioactivity of a sample per unit volume, measured in units like millicuries per milliliter (mCi/mL).
The initial activity concentration can be altered by processes such as dilution, important in understanding the net activity in a new solution.
  • The problem starts with an initial activity concentration of 2.5 mCi/mL before dilution.
  • After dilution, the activity concentration decreases and must be recalculated based on the final volume.
This concept is key in applications and situations where precise dosage or activity levels are essential, like in medical or laboratory settings. In our scenario, after diluting the stock solution, the activity concentration reduces, allowing us to calculate the adjusted activity of the sample after a specific decay time.

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Most popular questions from this chapter

Find the radii of (a) a nucleus of \({ }_{2}^{4} \mathrm{H}\) and (b) a nucleus of \({ }_{92}^{238} \mathrm{U} .\) (c) What is the ratio of these radii?

A freshly prepared sample of a certain radioactive isotope has an activity of \(10 \mathrm{mCi}\). After an elapsed time of \(4 \mathrm{~h}\), its activity is \(8 \mathrm{mCi}\). (a) Find the decay constant and half-life of the isotope. (b) How many atoms of the isotope were contained in the freshly prepared sample? (c) What is the sample's activity \(30 \mathrm{~h}\) after it is prepared?

A radioactive nucleus with decay constant \(\lambda\) decays to a stable daughter nucleus. (a) Show that the number of daughter nuclei, \(N_{2}\), increases with time according to the expression $$ N_{2}=N_{01}\left(1-e^{-\lambda t}\right) $$ where \(N_{01}\) is the initial number of parent nuclei. (b) Starting with \(10^{6}\) parent nuclei at \(t=0\), with a halflife of \(10 \mathrm{~h}\), plot the number of parent nuclei and the number of daughter nuclei as functions of time over the interval 0 to \(30 \mathrm{~h}\).

In addition to the radioactive nuclei included in the natural decay series, there are several other radioactive nuclei that occur naturally. One is \({ }^{147} \mathrm{Sm}\), which is \(15 \%\) naturally abundant and has a half-life of approximately \(1.3 \times 10^{10}\) years. Calculate the number of decays per second per gram (due to this isotope) in a sample of natural samarium. The atomic weight of samarium is \(150.4\). (Activity per unit mass is called specific activity.)

Use the Heisenberg uncertainty principle to make a reasonable argument against the hypothesis that free electrons can be present in a nucleus. Use relativistic expressions for the momentum and energy, and include appropriate assumptions and approximations.

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