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Estimate characteristic X-ray wavelengths: A hole has already been produced in the n=1 shell, and an n=2 electron is poised to jump in. Assume that the electron behaves as though in a "hydrogenlike" atom (see Section 7.8), with energy given byZef2(-13.6eV/n2) . Before the jump, it orbits Z protons, one remaining n=1electron. and (on average) half its seven fellow n=2 electrons, for a ZeffofZ-4.5 . After the jump, it orbits Z protons and half of its fellown=1 electron, for a ZeffofZ-0.5 . Obtain a formula for1/ versus Z . Compare the predictions of this model with the experimental data given in Figure8.19 and Table .

Short Answer

Expert verified

The formula for 1/ versus Z is 1=3.4hc3Z2+5Z-19.25 and on comparison, the theoretical and experimental values are reasonably close.

Step by step solution

01

Given data

Before the jump n=2, the electron effectively orbits an effective atomic number ofZe=Z-4.5, where Z is the number of protons.

After the jump n=1, the electron effectively orbits an effective atomic number of Ze=Z=0.5.

02

Concept of Energy

For a hydrogen like atom, the energy Enis given by

En=-13.6eVZe2n2

Where is the principal quantum number.

In terms of the wavelength of the photon , the energy difference before and after the jumpE is given by

E=hc

Where his Planck's constant and is the speed of light in vacuum.

03

Determine the energy

Whenn=2, then Z2=Z-4.5and when n=1thenZ1=Z-0.5.

The expression for 1is calculated as follows:

hc=13.6Z1n12-Z2n22hc=13.6Z-0.512-Z-4.522hc=13.644Z2-Z+0.25-Z2-9Z+20.25hc=3.44Z2-4Z+1-Z2+9Z-20.25

Simplify further as shown below.

hc=3.43Z2+5Z-19.251=3.4hc3Z2+5Z-19.251=3.412403Z2+5Z-19.251=2.7410-33Z2+5Z-19.25

On comparison of the calculated values with the theoretical values:

It is visible from Table (1), the theoretical value and the experimental values are reasonably close.

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