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  1. Using the Maxwell speed distribution, determine the most probable speed of a particle of mass min a gas at temperature T
  2. How does this compare with vrms ? Explain.

Short Answer

Expert verified
  1. The most probable speed is 2kBTm.
  2. The most probable speed is 23times vrms.

Step by step solution

01

Maxwell Probability Distribution.

  1. P(v)=(m2Ï€°ìBT)324Ï€±¹2e-mv22kBT…..(1)

Where,

m is the mass of the particle.

vis velocity of particle.

T is temperature.

kB is Boltzmann constant.

dPdv=ddv2Ï€mkBT32v2e-mv22kBTdPdv=2Ï€mkBT32ddvv2e-mv22kBTdPdv=2Ï€mkBT322ve-mv22kBT-2vmkBTv2e-mv22kBTdPdv=22Ï€mkBT321-mv22kBTve-mv22kBT0=22Ï€mkBT321-mv22kBTve-mv22kBT0=1-mv22kBTmv22kBT=1v2=2kBTmv=2kBTm

Therefore, the most probable speed is 2kBTm.

02

Mathematical Expression of rms Speed.

vrms=3kBTm

Rearrange for kBTm,

kBTm=vrms3

The mathematical expression for the most probable speed is,

v=2kBTm

Substitute vrms3for kBTm,

v=2vrms3=23vrms

Therefore, the most probable speed is 23times vrms.

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Most popular questions from this chapter

We claim that the famous exponential decrease of probability with energy is natural, the vastly most probable and disordered state given the constraints on total energy and number of particles. It should be a state of maximum entropy ! The proof involves mathematical techniques beyond the scope of the text, but finding support is good exercise and not difficult. Consider a system of11oscillators sharing a total energy of just5³óÓ¬0 . In the symbols of Section 9.3. N=11andM=5 .

  1. Using equation(9-9) , calculate the probabilities ofn , being0,1,2, and3 .
  2. How many particlesNn , would be expected in each level? Round each to the nearest integer. (Happily. the number is still 11. and the energy still5³óÓ¬0 .) What you have is a distribution of the energy that is as close to expectations is possible. given that numbers at each level in a real case are integers.
  3. Entropy is related to the number of microscopic ways the macro state can be obtained. and the number of ways of permuting particle labels withN0 ,N1,N2 , and N3fixed and totaling11 is11!(N0!N1!N2!N3!) . (See Appendix J for the proof.) Calculate the number of ways for your distribution.
  4. Calculate the number of ways if there were6 particles inn=0.5 inn=1 and none higher. Note that this also has the same total energy.
  5. Find at least one other distribution in which the 11 oscillators share the same energy, and calculate the number of ways.
  6. What do your finding suggests?

Not surprisingly. in a collection of oscillators, as in other thermodynamic systems, raising the temperature causes particles' energies to increase. Why shouldn’t point be reached where there are more panicles in some high energy state than in a lower energy. state? (The fundamental idea, not a formula that might arise from it. is the object.)

A two-sided room contains six particles, a, b, c, d, e and f, with two on the left and four on the right.

(a) Describe the macrostate.

(b) Identify the possible microstates. (Note: With only six particles, this isn't a thermodynamic system, but the general idea still applies, and the number of combinations is tractable.)

Exercise 67 calculates the minimum total energy in a system of spin fermions and is applicable to conduction electrons in a metal. The average particle energy is the total energy divided by the number of particlesN .Show that the average particle energy E→of a conduction electron at low temperature(T=0) is(3/5)EF . This form is convenient, being rather simple, and it can easily he put in terms of N,Vandm via equation .

Heat capacity (at constant volume) is defined as∂U/∂T. (a) Using a result derived in Example 9.6. obtain an expression for the heat capacity per unit volume, inJ/K⋅mi3, of a photon gas. (b) What is its value at300K?

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