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Verify for the angular solutions ()()of Table 7.3 that replacing with + and replacing with -gives the same function whenis even and the negative of the function when lis odd.

Short Answer

Expert verified

And for all the cases when l=0 and l=2 , either both or neither of them will change signs and hence the function will remain unchanged.

Step by step solution

01

Replacing ϕ with ϕ+π :

A function which acts as a mathematical description of a quantum state of an isolated quantum system, is called a wave function.

In Azimuthal wave function,()=eiml,

Where, is the colatitude and m1is the magnetic quantum number.

By replacing with(+) , you get,
role="math" localid="1659699420914" (+)=eiml(+)=eiml()=eiml(cosml+isinml)

From the above equation, you get, sine term is zero, while cosine term is + 1 while is even and cosine term is -1 when it is odd.

Hence,() the changes sign when is odd and remains changed otherwise.

02

Replacing θ with π-θ :

In the function (), here, is the colatitude

By replacing with- you get,
cos(-)=-cos()sin(-)=sin()

Hence, only the terms having odd power of cos()will change.

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