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To determine the two bound state energies for the well.

Short Answer

Expert verified

The two bound state energies for a well is E1=7.2822mL2 and E2=27.9h22mL2.

Step by step solution

01

formula used to determine the two bound state energies for the well.

Given Information:

U0=4222mL2

Formula Used:

The result of the exercise 40 is

Ecot2mEhL=U0E

Here, E is the energy,m is the mass, h is the reduced Planck's constant, L is the width of the infinite well and U0 is the potential energy of the particle.

02

Calculating the two bound state energies using the formula 

Multiply the above equation by 2mEhL on both sides

This modifies the equation to:

2mhLEcot2mEhL=2mhL(U0E)2mEhLcot2mEhL=2mU0L22mEL2h2

Make the substitution,x=2mEhL

xcot(x)=2mU0L22x2 鈥︹ (1)

The potential energyU0 is

U0=4222mL2

Substitute the above equation in the equation (1) and simplify.

xcot(x)=2m42h22mL2L2h2x2xcot(x)=42x2

This is a very nice function to plug into computer program of choice.

Solutions are:

x=2.698and5.284Forx=2.6982.698=2mE1hLE12.6982=hh2mL2=7.28h22mL2

And forx=5.284we get

5.284=2mE2hLE25.2842=h2mL2=27.9h22mL2

Hence, the two bound state energies for a well is E1=7.28h22mL2 and E2=27.9h22mL2.

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Most popular questions from this chapter

Simple models are very useful. Consider the twin finite wells shown in the figure, at First with a tiny separation. Then with increasingly distant separations, In all case, the four lowest allowed wave functions are planned on axes proportional to their energies. We see that they pass through the classically forbidden region between the wells, and we also see a trend. When the wells are very close, the four functions and energies are what we might expect of a single finite well, but as they move apart, pairs of functions converge to intermediate energies.

(a) The energies of the second and fourth states decrease. Based on changing wavelength alone, argue that is reasonable.

(b) The energies of the first and third states increase. Why? (Hint: Study bow the behaviour required in the classically forbidden region affects these two relative to the others.)

(c) The distant wells case might represent two distant atoms. If each atom had one electron, what advantage is there in bringing the atoms closer to form a molecule? (Note: Two electrons can have the same wave function.)

The particle has E=0.

(a) Show that the potential energy for x>0is given by

U(x)=-2am1x+2a22m

(b) What is the potential energy for x<0?

Show that the uncertainty in the position of a ground state harmonic oscillator is 1/22/mk1/4.

Quantum-mechanical stationary states are of the general form (x,t)=(x)e-it. For the basic plane wave (Chapter 4), this is (x,t)=Aeikxe-it=Aei(kx-t), and for a particle in a box it is Asinkxe-i蝇t. Although both are sinusoidal, we claim that the plane wave alone is the prototype function whose momentum is pure-a well-defined value in one direction. Reinforcing the claim is the fact that the plane wave alone lacks features that we expect to see only when, effectively, waves are moving in both directions. What features are these, and, considering the probability densities, are they indeed present for a particle in a box and absent for a plane wave?

Consider a particle of mass mand energy E in a region where the potential energy is constant U0. Greater than E and the region extends tox=+

(a) Guess a physically acceptable solution of the Schrodinger equation in this region and demonstrate that it is solution,

(b) The region noted in part extends from x = + 1 nm to +. To the left of x = 1nm. The particle鈥檚 wave function is Dcos (109m-1 x). Is also greater than Ehere?

(c) The particle鈥檚 mass m is 10-3 kg. By how much (in eV) doesthe potential energy prevailing from x=1 nm to U0. Exceed the particle鈥檚 energy?

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