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The resistivity of the silver is 1.6×10-8 Ω⋅mat room temperature of (300 K), while that of silicon is about10 Ω⋅m

(a) Show that this disparity follows, at least to a rough order of magnitude from the approximate 1 eV band gap in silicon.

(b) What would you expect for the room temperature resistivity of diamond, which has a band gap of about 5 eV.

Short Answer

Expert verified

(a)The factor is approximately similar to the ratio between the resistivity.

(b) The resistivity for the diamond is1.6×1034 Ω⋅m .

Step by step solution

01

Determine the formulas

Consider the exponential formula as per the Boltzmann’s distribution:

e-Egap2kbT ….. (1)

Here,kb is Boltzmann constant and the temperature is T.

Consider the expression for the vibrational distance as:

02

Determine the answer for part (a).

Substitute the values in the equation () and solve as:

e−Egap2kbT=e−1 e³Õ2×1.38×10−23×300 e³Õ=4×10−9 e³Õ

Note the availability of the electron is less than 4×10−9 e³Õso the resistivity is approximately14×10−9 e³Õ=2.5×108

Consider the equation for the ration between the resistivity of the silicon and the silver as:

ÒÏsiliconÒÏsilver

Substitute the values and solve as:

ÒÏsiliconÒÏsilver=1.6×10−8 Ω⋅m10 Ω⋅m=1.6×10−9

Therefore, the factor is approximately similar to the ratio between the resistivity.

03

Determine the answer for part (b).

Since, the energy gap of the diamond is−5 e³Õ .

Solve for the gap as:

Egap=−5 e³Õ=(−5 e³Õ)(1.6×10−19 J1 e³Õ)=(−5)(1.6×10−19 J)

Consider the formula for the resistivity of the diamond as:

ÒÏdiamond=e−Egap22kbTÒÏsiliconÒÏsilver

Resolve the equation as:

ÒÏdiamond=ÒÏsilvere−Egap22kbT

Substitute the values and solve as:

ÒÏdiamond=1.6×10−8 Ω⋅me−(5)(1.6×10−19 J)2×1.38×10−23×300=1.6×10−8 Ω⋅m10−42=1.6×10−8 Ω⋅m(1042)=1.6×1034 Ω⋅m

Therefore, the resistivity of the diamond is1.6×1034 Ω⋅m .

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