Chapter 13: Problem 19
Cite the two desirable characteristics of clay minerals relative to fabrication processes.
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Chapter 13: Problem 19
Cite the two desirable characteristics of clay minerals relative to fabrication processes.
These are the key concepts you need to understand to accurately answer the question.
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Compare the temperatures at which sodalime, borosilicate, \(96 \%\) silica, and fused silica may be annealed.
For many viscous materials, the viscosity \(\eta\) may be defined in terms of the expression $$ \eta=\frac{\sigma}{d \epsilon / d t} $$ where \(\sigma\) and \(d \epsilon / d t\) are, respectively, the tensile stress and the strain rate. A cylindrical specimen of a soda-lime glass of diameter 5 \(\mathrm{mm}(0.2\) in.) and length \(100 \mathrm{~mm}\) (4 in.) is subjected to a tensile force of \(1 \mathrm{~N}\left(0.224 \mathrm{lb}_{\mathrm{f}}\right)\) along its axis. If its deformation is to be less than \(1 \mathrm{~mm}(0.04\) in.) over a week's time, using Figure 13.7, determine the maximum temperature to which the specimen may be heated.
The viscosity \(\eta\) of a glass varies with temperature according to the relationship $$ \eta=A \exp \left(\frac{Q_{\mathrm{vis}}}{R T}\right) $$ where \(Q_{\text {vis }}\) is the energy of activation for viscous flow, \(A\) is a temperature-independent constant, and \(R\) and \(T\) are, respectively, the gas constant and the absolute temperature. A plot of \(\ln \eta\) versus \(1 / T\) should be nearly linear, and with a slope of \(Q_{\text {vis }} / R\). Using the data in Figure 13.7, (a) make such a plot for the borosilicate glass, and (b) determine the activation energy between temperatures of 500 and \(900^{\circ} \mathrm{C}\).
Compare the softening points for \(96 \%\) silica, borosilicate, and soda-lime glasses.
Compare the manner in which the aggregate particles become bonded together in claybased mixtures during firing and in cements during setting,
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