Chapter 5: Problem 4
Briefly explain the concept of steady state as it applies to diffusion.
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Chapter 5: Problem 4
Briefly explain the concept of steady state as it applies to diffusion.
These are the key concepts you need to understand to accurately answer the question.
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Consider a diffusion couple composed of two semi-infinite solids of the same metal, and that each side of the diffusion couple has a different concentration of the same elemental impurity; furthermore, assume each impurity level is constant throughout its side of the diffusion couple. For this situation, the solution to Fick's second law (assuming that the diffusion coefficient for the impurity is independent of concentration), is as follows: $$C_{x}=\left(\frac{C_{1}+C_{2}}{2}\right)-\left(\frac{C_{1}-C_{2}}{2}\right) \operatorname{erf}\left(\frac{x}{2 \sqrt{D t}}\right).$$In this expression, when the \(x=0\) position is taken as the initial diffusion couple interface, then \(C_{1}\) is the impurity concentration for \(x<0\) likewise, \(C_{2}\) is the impurity content for \(x>0\).A diffusion couple composed of two platinum-gold alloys is formed; these alloys have compositions of \(99.0 \mathrm{wt} \% \mathrm{Pt}-1.0 \mathrm{wt} \%\) Au and 96.0 wt \(\%\) Pt- 4.0 wt\% Au. Determine the time this diffusion couple must be heated at \(1000^{\circ} \mathrm{C}(1273 \mathrm{K})\) in order for the composition to be 2.8 wt \(\%\) Au at the \(10 \mu \mathrm{m}\) position into the \(4.0 \mathrm{wt} \%\) Au side of the diffusion couple. Preexponential and activation energy values for Au diffusion in \(\mathrm{Pt}\) are \(1.3 \times 10^{-5}\) \(\mathrm{m}^{2} / \mathrm{s}\) and \(252,000 \mathrm{J} / \mathrm{mol},\) respectively.
Nitrogen from a gaseous phase is to be diffused into pure iron at \(675^{\circ} \mathrm{C}\). If the surface concentration is maintained at \(0.2 \mathrm{wt} \% \mathrm{N}\) what will be the concentration \(2 \mathrm{mm}\) from the surface after 25 h? The diffusion coefficient for nitrogen in iron at \(675^{\circ} \mathrm{C}\) is \(1.9 \times 10^{-11} \mathrm{m}^{2} / \mathrm{s}\).
An FCC iron-carbon alloy initially containing 0.10 wt \(\% \mathrm{C}\) is carburized at an elevated temperature and in an atmosphere wherein the surface carbon concentration is maintained at 1.10 wt\%. If after 48 h the concentration of carbon is \(0.30 \mathrm{wt} \%\) at a position \(3.5 \mathrm{mm}\) below the surface, determine the temperature at which the treatment was carried out.
The diffusion coefficients for nickel in iron are given at two temperatures: $$\begin{array}{cc} \boldsymbol{T}(\boldsymbol{K}) & \boldsymbol{D}\left(\boldsymbol{m}^{2} / \boldsymbol{s}\right) \\ \hline 1473 & 2.2 \times 10^{-15} \\ 1673 & 4.8 \times 10^{-14} \end{array}$$ (a) Determine the values of \(D_{0}\) and the activation energy \(Q_{d}\) (b) What is the magnitude of \(D\) at \(1300^{\circ} \mathrm{C}\) \((1573 \mathrm{K}) ?\)
The preexponential and activation energy for the diffusion of chromium in nickel are \(1.1 \times 10^{-4} \mathrm{m}^{2} / \mathrm{s}\) and \(272,000 \mathrm{J} / \mathrm{mol},\) respec- tively. At what temperature will the diffusion coefficient have a value of \(1.2 \times 10^{-14} \mathrm{m}^{2} / \mathrm{s} ?\)
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