Chapter 15: Problem 39
What is the distinction between dye and pigment colorants?
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Chapter 15: Problem 39
What is the distinction between dye and pigment colorants?
These are the key concepts you need to understand to accurately answer the question.
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For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to \(\sigma(t)=\sigma(0) \exp \left(-\frac{t}{\tau}\right)\) where \(\sigma(t)\) and \(\sigma(0)\) represent the timedependent and initial (i.e., time \(=0\) ) stresses, respectively, and \(t\) and \(\tau\) denote elapsed time and the relaxation time; \(\tau\) is a time independent constant characteristic of the material. A specimen of some viscoelastic polymer with the stress relaxation that obeys Equation 15.10 was suddenly pulled in tension to a measured strain of \(0.5 ;\) the stress necessary to maintain this constant strain was measured as a function of time. Deter\(\operatorname{mine} E_{r}(10)\) for this material if the initial stress level was 3.5 MPa \((500\) psi), which dropped to \(0.5 \mathrm{MPa}(70 \mathrm{psi})\) after \(30 \mathrm{s}\).
Briefly explain the difference in molecular chemistry between silicone polymers and other polymeric materials.
Demonstrate, in a manner similar to Equation \(15.4,\) how vulcanization may occur in a chloroprene rubber.
Nylon 6,6 may be formed by means of a condensation polymerization reaction in which hexamethylene diamine \(\left[\mathrm{NH}_{2}-\left(\mathrm{CH}_{2}\right)_{6}-\right.\) \(\left.\mathrm{NH}_{2}\right]\) and adipic acid react with one another with the formation of water as a byproduct. What masses of hexamethylene diamine and adipic acid are necessary to yield \(20 \mathrm{kg}\) of completely linear nylon \(6,6 ?\) (Note: the chemical equation for this reaction is the answer to Concept Check \(15.12 .\) )
Which of the following would you expect to be elastomers and which thermosetting polymers at room temperature? Justify each choice. (a) Linear and highly crystalline polyethylene (b) Phenol-formaldehyde (c) Heavily crosslinked polyisoprene having a glass-transition temperature of \(50^{\circ} \mathrm{C}\) \(\left(122^{\circ} \mathrm{F}\right)\) (d) Lightly crosslinked polyisoprene having a glass-transition temperature of \(-60^{\circ} \mathrm{C}\) \(\left(-76^{\circ} \mathrm{F}\right)\) (e) Linear and partially amorphous poly(vinyl chloride)
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