Chapter 15: Problem 34
List two important characteristics for polymers that are to be used in fiber applications
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Chapter 15: Problem 34
List two important characteristics for polymers that are to be used in fiber applications
These are the key concepts you need to understand to accurately answer the question.
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List the two molecular characteristics that are essential for elastomers.
For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to \(\sigma(t)=\sigma(0) \exp \left(-\frac{t}{\tau}\right)\) where \(\sigma(t)\) and \(\sigma(0)\) represent the timedependent and initial (i.e., time \(=0\) ) stresses, respectively, and \(t\) and \(\tau\) denote elapsed time and the relaxation time; \(\tau\) is a time independent constant characteristic of the material. A specimen of some viscoelastic polymer with the stress relaxation that obeys Equation 15.10 was suddenly pulled in tension to a measured strain of \(0.5 ;\) the stress necessary to maintain this constant strain was measured as a function of time. Deter\(\operatorname{mine} E_{r}(10)\) for this material if the initial stress level was 3.5 MPa \((500\) psi), which dropped to \(0.5 \mathrm{MPa}(70 \mathrm{psi})\) after \(30 \mathrm{s}\).
Demonstrate, in a manner similar to Equation \(15.4,\) how vulcanization may occur in a chloroprene rubber.
In your own words, briefly describe the phenomenon of viscoelasticity.
Normal butane and isobutane have boiling temperatures of -0.5 and \(-12.3^{\circ} \mathrm{C}(31.1\) and \(\left.9.9^{\circ} \mathrm{F}\right),\) respectively. Briefly explain this behavior on the basis of their molecular structures, as presented in Section 14.2.
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