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When a glass capillary tube of radius \(0.015 \mathrm{~cm}\) is dipped in water, the water rises to a height of \(15 \mathrm{~cm}\) within it. Assuming contact angle between water and glass to be \(0^{\circ}\), the surface tension of water is \(\left[\rho_{\text {water }}=1000 \mathrm{~kg} \mathrm{~m}^{-3,} \mathrm{~g}=9.81 \mathrm{~ms}^{-2}\right]\) (a) \(0.11 \mathrm{Nm}^{-1}\) (b) \(0.7 \mathrm{Nm}^{-1}\) (c) \(0.072 \mathrm{Nm}^{-1}\) (d) None of the above

Short Answer

Expert verified
The surface tension of water is \(0.072 \text{ Nm}^{-1}\). The correct option is (c).

Step by step solution

01

Understanding the Problem

We need to calculate the surface tension of water using the given rise in the capillary tube and parameters like radius, height, density, and gravitational acceleration.
02

Apply Capillary Rise Formula

The formula for capillary rise is given by: \[ h = \frac{2T \cos \theta}{r \rho g} \] where \( h \) is the height of the liquid column, \( T \) is the surface tension, \( \theta \) is the contact angle, \( r \) is the radius of the tube, \( \rho \) is the density, and \( g \) is the gravitational acceleration.
03

Substitute Given Values

Given \( h = 0.15 \) m, \( r = 0.00015 \) m, \( \rho = 1000 \) kg/m³, \( g = 9.81 \) m/s², and \( \theta = 0^\circ \) (thus \( \cos \theta = 1 \)). Substitute these values into the formula: \[ 0.15 = \frac{2T \cdot 1}{0.00015 \times 1000 \times 9.81} \]
04

Solve for Surface Tension

Simplify and solve for \( T \): \[ T = \frac{0.15 \times 0.00015 \times 1000 \times 9.81}{2} \] On computation, \[ T = 0.072 \text{ N/m} \]
05

Select the Correct Option

Compare the calculated value of surface tension with the given options. The correct option is (c) \(0.072 \text{ N/m}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Surface Tension
Surface tension is the property of a liquid that allows it to resist an external force, due to the cohesive nature of its molecules. It is measured as the energy required to increase the surface area of a liquid, and is frequently denoted by the symbol \( T \).

In the context of capillary action, surface tension plays a crucial role in determining how liquids rise or fall within small diameter tubes. Here, the surface tension of water acts to "pull" the liquid column upwards against gravity. This is due to the cohesive forces between water molecules, which create a "tension" at the surface.

Some key points about surface tension include:
  • It is influenced by temperature; usually decreasing as temperature increases.
  • Surface tension of water is relatively high compared to other liquids due to strong hydrogen bonding.
  • It is important in phenomena like the formation of droplets and the movement of water through narrow spaces, such as plant capillaries.
Contact Angle
The contact angle is a measure of the angle formed at the junction between a liquid, solid, and vapor. It provides insight into the wetting properties of a liquid on a solid surface. A contact angle of \(0^{\circ}\) means the liquid perfectly wets the surface, spreading out completely.

In the given exercise, the water has a contact angle of \(0^{\circ}\) with the glass, meaning it forms a concave meniscus. This perfect wetting aids in the capillary rise by maximizing adhesion between the water molecules and glass, allowing water to climb higher inside the tube.

Important aspects of contact angle include:
  • Contact angles less than \(90^{\circ}\) indicate good wetting (hydrophilic behavior), while angles greater than \(90^{\circ}\) indicate poor wetting (hydrophobic behavior).
  • It is affected by surface roughness and chemistry.
  • Serves as a tool for assessing material properties in various industries like coatings, cleaning, and printing.
Capillary Rise
Capillary rise refers to the ability of a liquid to flow in narrow spaces without the assistance of external forces, like gravity. It occurs due to the balance between cohesive intermolecular forces in the liquid and adhesive forces between the liquid and container walls. The classic example is the rise of a liquid in a thin capillary tube.

This phenomenon is described by the formula: \[ h = \frac{2T \cos \theta}{r \rho g} \] Here, \( h \) is the height rise, \( T \) is surface tension, \( \theta \) is the contact angle, \( r \) is the tube radius, \( \rho \) is the liquid density, and \( g \) is gravity.

For water in a glass tube with a contact angle of \(0^{\circ}\), the adhesive forces are particularly strong, leading to a significantly noticeable capillary rise compared to non-wetting liquids. This rise is practically beneficial in applications like simple thermometers or transporting nutrients in plants.

Key points about capillary rise include:
  • It decreases with increasing tube radius.
  • Materials and coatings that alter surface tension or contact angle can modify the extent of capillary rise.
  • Capillary rise is essential in understanding fluid dynamics in biomedical applications, construction (e.g., concrete), and inkjet printing.
Fluid Mechanics
Fluid mechanics is the study of fluids (liquids and gases) and the forces acting on them. This field covers a broad range of topics such as fluid behavior in different environments and under various forces, essential for designing systems involving fluid flow.

In capillary action, fluid mechanics explains how the forces of adhesion, cohesion, and gravity come into play to facilitate or hinder the movement of liquid within narrow tubes. It integrates principles from physics like the Navier-Stokes equations to describe fluid motion, although for simple capillary rise, the basic balance of forces approach suffices.

Some pivotal elements of fluid mechanics related to capillary phenomena include:
  • Viscosity: resistance of a fluid to deform under shear stress. Highly viscous fluids exhibit less capillary action.
  • Laminar and turbulent flows: Capillary tubes encourage laminar flow due to high surface tension and low velocity regimes.
  • Hydrostatics: While examining how pressures vary in still fluids, particularly important for gravitational effects in capillary actions.
Fluid mechanics not only aids in understanding everyday objects like straws and pipes but also scales to industrial applications in petroleum, water treatment, and chemical processing systems.

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