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Chapter 2: Time-Independent Schrodinger Equation

Q5P

Page 38

A particle in the infinite square well has as its initial wave function an even mixture of the first two stationary states:

(x,0)=A[1(x)+2(x)]

You can look up the series

116+136+156+=6960

and

114+134+154+=496

in math tables. under "Sums of Reciprocal Powers" or "Riemann Zeta Function."

(a) Normalize (x,0). (That is, find A. This is very easy, if you exploit the orthonormality of 1 and 2. Recall that, having normalized at , t=0 , you can rest assured that is stays normalized鈥攊f you doubt this, check it explicitly after doing part(b).

(b) Find(x,t) and|(x,t)|2 . Express the latter as a sinusoidal function of time. To simplify the result, let22ma2

(c)Compute x . Notice that it oscillates in time. What is the angular frequency of the oscillation? What is the amplitude of the oscillation?(If your amplitude is greater than a2, go directly to jail.

(d) Compute p.

(e) If you measured the energy of this particle, what values might you get, and what is the probability of getting each of them? Find the expectation value ofH . How does it compare with E1 and E2

Q6P

Page 39

Although the overall phase constant of the wave function is of no physical significance (it cancels out whenever you calculate a measurable quantity), the relative phase of the coefficients in Equation 2.17 does matter. For example, suppose we change the relative phase of 1and2in problem 2.5:(x,0)=A[1x+ei2x]Where is some constant. Find (x,t),|x,t|2, and (x), and compare your results with what you got before. Study the special cases =2and=.

Q7P

Page 39

A particle in the infinite square well has the initial wave function

(X,0)={Ax,0xa2Aa-x,a2xa

(a) Sketch (x,0), and determine the constant A

(b) Find(x,t)

(c) What is the probability that a measurement of the energy would yield the valueE1 ?

(d) Find the expectation value of the energy.

Q8P

Page 40

A particle of mass m in the infinite square well (of width a) starts out in the left half of the well, and is (at t=0) equally likely to be found at any point in that region

(a) What is its initial wave function, (x,0)? (Assume it is real. Don鈥檛 forget to normalize it.)

(b) What is the probability that a measurement of the energy would yield the values2h22ma2?

Q9P

Page 40

For the wave function in Example 2.2, find the expectation value of H, at time t=0 ,the 鈥渙ld fashioned way:

H=(x,0)H^(x,0)dx.

Compare the result obtained in Example 2.3. Note: BecauseH is independent of time, there is no loss of generality in usingt=0

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