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Magnetic resonance. A spin-1/2 particle with gyromagnetic ratio at rest in a static magnetic fieldB0k^ precesses at the Larmor frequency0=纬叠0 (Example 4.3). Now we turn on a small transverse radiofrequency (rf) field,Brf[cos(t)^sin(t)j^]$, so that the total field is

role="math" localid="1659004119542" B=Brfcos(t)^Brfsin(t)j^+B0k^

(a) Construct the 22Hamiltonian matrix (Equation 4.158) for this system.

(b) If (t)=(a(t)b(t))is the spin state at time t, show that

a=i2(惟别i蝇tb+0a):鈥夆赌夆赌b=i2(惟别i蝇ta0b)

where 纬叠rfis related to the strength of the rf field.

(c) Check that the general solution fora(t) andb(t) in terms of their initial valuesa0 andb0 is

role="math" localid="1659004637631" a(t)={a0cos('t/2)+i'[a0(0)+b0]sin('t/2)}ei蝇t/2b(t)={b0cos('t/2)+i'[b0(0)+a0]sin('t/2)}ei蝇t/2

Where

'(0)2+2

(d) If the particle starts out with spin up (i.e. a0=1,b0=0,), find the probability of a transition to spin down, as a function of time. Answer:P(t)={2/[(0)2+2]}sin2('t/2)

(e) Sketch the resonance curve,

role="math" localid="1659004767993" P()=2(0)2+2,

as a function of the driving frequency (for fixed 0and ). Note that the maximum occurs at=0 Find the "full width at half maximum,"螖蝇

(f) Since 0=纬叠0we can use the experimentally observed resonance to determine the magnetic dipole moment of the particle. In a nuclear magnetic resonance (nmr) experiment the factor of the proton is to be measured, using a static field of 10,000 gauss and an rf field of amplitude gauss. What will the resonant frequency be? (See Section for the magnetic moment of the proton.) Find the width of the resonance curve. (Give your answers in Hz.)

Short Answer

Expert verified

a) Hamiltonian matrix H=2B0Brfei蝇tBrfei蝇tB0

b) The strength of the field a=i2(惟别i蝇tb+0a)b=i2(惟别i蝇ta0b)

c) The general solution a(t)=a0cos't2+i'(b0+a0(0))sin't2ei蝇t/2b(t)=b0cos't2+i'(a0b0(0))sin't2ei蝇t/2

d) The probability of a transitionP(t)=2(0)2+2sin2't2

e) The resonance curve 螖蝇=2

f) The width of the resonance curvevres=4.26107贬锄鈥鈥夆赌螖惫=85.2Hz

Step by step solution

01

Hamiltonian matrix.

(a)

Consider a particle with spin of 1/2and gyromagnetic ratio of the particle is at rest in a static magnetic field B0k^tin this case it processes at the Larmor frequency 0=B0Turn a transverse radio-frequency field, Brf[cos(t)^sin(t)j^], so the total magnetic field that the particle experiences is: B=Brfcos(蝇t)Bzi^Brfsin(蝇t)Byj^+B0Bzk^

The spin Hamiltonian is given by:

H=BS

Where;

S=2and,

x=0110;鈥夆赌夆赌y=0ii0;鈥夆赌夆赌z=1001

The Hamiltonian is therefore:

H=(BxSx+BySy+BzSz)=2(Bxx+Byy+Bzz)=2Bx011+By0ii0+Bz1001=2BzBxiByBx+iByBz

H=2B0Brf(cos蝇t+isin蝇t)Brf(cos蝇tisin蝇t)B0=2B0Brrei蝇tBrfei蝇tB0=2B0Brfei蝇tBrfei蝇tB0

(1)

02

The spin state at time.

(b)

Let(t)be the spin state at timetwhich is given by:

role="math" localid="1659005644415" (t)=a(t)b(t)

To finda(t) andb(t)in order to do this we need to apply Schrodinger equation on this state, the time dependent Schrodinger is given by:

ih=H

Using the result of part (a) we get:

iab=2B0BrtitBrftitB0ab=h2B0aBrftittbBrlcitaB0b

Thus:

a=i2(B0a+Brfci蝇tb)b=i2(B00bBrfei蝇ta)

Let纬叠rr$, thus:

a=i2(惟别i蝇tb+0a)b=i2(惟别i蝇ta0b) 鈥︹ (2)

03

Checking the general equation.

a. We need to solve the equations in part (b), first we need to write the first equation in (2) for bas

b=1ei蝇t2ia0a 鈥︹ (3)

The derivative of the first equation in (2), so the result will be in terms a,band bwe substitute with bfrom (3) and withbfor (2)

role="math" localid="1659006175845" a=i2(惟i蝇ei蝇tb+ei蝇tb+0a)=i2惟i蝇ei蝇t1ei蝇t2ia0a+惟别i蝇ti2(惟别i蝇ta0b)+0a=22ia0a14惟别i蝇t(惟别i蝇ta01ei蝇t2ia0a+i20a=i蝇a14(2+022蝇蝇0)a

So, the second order ODE with constant coefficient,

ai蝇a+14(2+022蝇蝇0)a=0

Write the last two terms in the bracket as:

022蝇蝇0=022蝇蝇0+22=(0)22

Thus:

ai蝇a+14(2+(0)22)a=0 鈥︹赌..(4)

The characteristic equation is therefore:

2i蝇位+14(2+(0)22)=0

The roots of this equation,

=i蝇(2+(0)22)2=i2((0)2+2)=i2(')

Where;

'(0)2+2

The general solution is:

a(t)=Ae1+Be2=Aei(+')t/2+Bei(')t/2鈥︹赌︹赌︹赌︹赌(5)

The solution ofb(t) is similar toa(t) but with signs reversed onand0so the sign of 'stays the same. So,

b(t)=Cei(+')l/2+Dei(')t/2 鈥︹赌︹赌︹赌︹赌(6)

To apply the initial conditions, which area(0)=a0and b(0)=b0From (6) and (7) we get

a0=A+B鈥夆赌夆赌b0=C+D鈥︹赌︹赌︹赌(7)

To find the constant, substitute with the solutions (6) and (7) into the first equation of so we get:

role="math" localid="1659006658486" a=Ai2(+')ei(i+')t/2+Bi2(')ei(')t/2=i2eit[Cei(+')/2+Dei(')t/2]+0a

Att=0

鈥︹ (8)

Ai2(+')+Bi2(')=i2(C+D)+0a0a0+(AB)'i2b0+0a0AB1'(b0+a0(0))

The three equations with four constants, we can't solve for them, so what we will do is to write the solution in equation (5) in terms of the cosine and sine then let collect the common terms, will notice that the constants appear as a sum of subtract between them, and we have this relation in (7) and (8).

a(t)=Aei蝇't/2+Bei蝇't/2ei蝇t/2=(A+B)cos't2+i(AB)sin't2ei蝇t/2

Substitute from (7) and (8), we get:

a(t)=a0cos't2+i'(b0+a0(0))sin't2ei蝇t/2

The solution of b(t)is similar to a(t), but with signs reversed on and 0so the sign of 'stays the same, thus:

b(t)=b0cos't2+i'(a0b0(0))sin't2ei蝇t/2

04

The probability of a transition  

(d)

Now consider a particle that starts out with a spin up,a0=1 andb0=0 the probability of a transition to the spin down is:

P(t)=|b(t)|2

The result of part cwe get:

P(t)=2(')2sin2't2=2(0)2+2sin2't2P(t)=2(0)2+2sin2't2

05

The resonance curve.

(e)

Now we need to sketch the resonance curve, which is given by:

P()=2(0)2+2

Let 0=1and =2 Use any values, the graph is shown in the following figure. That the maximum occurs at =0to find at which point half of the maximum lie let setP()=0.5 and then solve for so:

2(0)2+2=0.50=

The full width at half maximum is therefore:

螖蝇=2

06

The gyro-magnetic ration

(f)

The gyro-magnetic ratio for a proton is given by:

=gpe2mp

Wheregp=5.59

To find the resonant frequency, which is:

res=02

But 0=纬叠0

so:

res=gpe4mpB0for B0=10,000gauss =1T, we get:

res=(5.59)(1.61019C)4(1.671027kg)(1T)=4.26107Hzres=4.26107Hz

To find the width of the resonance curve, which is given by:

螖谓=螖蝇2=

螖谓=Brf=22Brf=res2BrfB0

For Brf=0.01 gauss =1106T,we get:

螖谓=(4.26107)(2106)=85.2Hz

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