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At time t = 0 a particle is represented by the wave function

ψ(x,0)={A(x,0),0≤x≤a,A(b−x)/(b−a),a≤x≤b,0,otherwise,where A, a, and b are (positive) constants.

(a) Normalize ψ(that is, find A, in terms of a and b).

(b) Sketch ψ(x,0), as a function of x.

(c) Where is the particle most likely to be found, at t = 0?.

(d) What is the probability of finding the particle to the left of a? Check your result in the limiting cases b = a and b= 2a.

(e) What is the expectation value of x?

Short Answer

Expert verified

(a)A=3bA=b3.

(c) x=0

(d)P=∫0a|A|2dx=|A|2a2∫0ax2dx=|A|2a3=abP

(e) ⟨X⟩=2a+b4.

Step by step solution

01

(a) Normalizing ψ .

1=|A|2a2∫0ax2dx+|A|2(b−a)2∫0b(b−a)2dx=|A|21a2x330a+1(b−a)2−(b−x)33ab=|A|2a3+b−a3=|A|2b3A=3bA=b3.

02

(b) Sketching ψ(x,0)

03

(c) The particle most likely to be found at,

At x = a.

04

(d) probability of finding the particle.

P=∫0a|A|2dx=|A|2a2∫0ax2dx=|A|2a3=abP=ba,P=1ifb=aP=1/2ifb=2a.

05

(e) Expectation value of x.

⟨x⟩=∫x|Ψ|2dx=|A|21a2∫0ax3dx+1(b−a)2∫abx(b−x)2dx.

=3b1a2x440a+1(b−a)2b2x22−2bx33+x44ab.

=34b(b−a)2[a2(b−a)2+2b4−8b4/3+b4−2a2b2+8a3b/3−a4].

=34b(b−a)2b43−a2b2+23a3b=14(b−a)2(b3−3a2b+2a3)=2a+b4.

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Most popular questions from this chapter

In general, quantum mechanics is relevant when the de Broglie wavelength of the principle in question(h/p)is greater than the characteristic Size of the system (d). in thermal equilibrium at (kelvin) TemperatureTthe average kinetic energy of a particle is

p22m=32kBT

(Where kBis Boltzmann's constant), so the typical de Broglie wavelength is

λ=h3mkBT

The purpose of this problem is to anticipate which systems will have to be treated quantum mechanically, and which can safely be described classically.

(a) Solids. The lattice spacing in a typical solid is around d=0.3nm. Find the temperature below which the free 18electrons in a solid are quantum mechanical. Below what temperature are the nuclei in a solid quantum mechanical? (Use sodium as a typical case.) Moral: The free electrons in a solid are always quantum mechanical; the nuclei are almost never quantum mechanical. The same goes for liquids (for which the interatonic spacing is roughly the same), with the exception of helium below 4K.

(b) Gases. For what temperatures are the atoms in an ideal gas at pressure Pquantum mechanical? Hint: Use the ideal gas law(PV=NkBT)to deduce the interatomic spacing.

For the distribution of ages in the example in Section 1.3.1:

(a) Compute⟨j2⟩ and⟨j⟩2 .

(b) Determine ∆j for each j, and use Equation 1.11 to compute the standard deviation.

(c) Use your results in (a) and (b) to check Equation 1.12.

The needle on a broken car speedometer is free to swing, and bounces perfectly off the pins at either end, so that if you give it a flick it is equally likely to come to rest at any angle between 0 tox.

  1. What is the probability density? Hint: ÒÏ(θ)dθ is the probability that the needle will come to rest betweenθ andθ+dθ .
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A needle of lengthlis dropped at random onto a sheet of paper ruled with parallel lines a distancelapart. What is the probability that the needle will cross a line?

We consider the same device as the previous problem, but this time we are interested in thex-coordinate of the needle point-that is, the "shadow," or "projection," of the needle on the horizontal line.

(a) What is the probability density ÒÏ(x)? Graph data-custom-editor="chemistry" ÒÏ(x) as a function of x, from -2rto +2r , where ris the length of the needle. Make sure the total probability is . Hint: data-custom-editor="chemistry" ÒÏ(x)dx is the probability that the projection lies between data-custom-editor="chemistry" xand data-custom-editor="chemistry" (x+dx). You know (from Problem 1.11) the probability that data-custom-editor="chemistry" θ is in a given range; the question is, what interval data-custom-editor="chemistry" dxcorresponds to the interval data-custom-editor="chemistry" »åθ?

(b) Compute data-custom-editor="chemistry" <x>, data-custom-editor="chemistry" <x2>, and data-custom-editor="chemistry" σ, for this distribution. Explain how you could have obtained these results from part (c) of Problem 1.11.

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