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Test the energy-time uncertainty principle for the wave function in Problem2.5and the observable x, by calculatingσHσXandd<x>/dtexactly.

Short Answer

Expert verified

The values are:

σH=12E2-E1σx2=a2413-54π2-329π22cos23Ӭtdxdt=8ħ3masin3Ӭt

Step by step solution

01

 Step 1: Wavefunction.

The wavefunction is given byψ(x,0)=A[ψ1x+ψ2x].

First, find the normalization constant as:

1=∫-∞∞ψx,02dx=∫-∞∞ψ*ψdx=A2∫-∞∞ψ1x+ψ2x*ψ1x+ψ2xdx=A2∫-∞∞ψ1*ψ1dx+∫-∞∞ψ1*ψ2dx+∫-∞∞ψ2*ψ1dx+∫-∞∞ψ2*ψ2dx+

Use the orthogonality condition, eliminate the second and the third integrations, whereas the first and the fourth integrations each one of them is equal to one; therefore,

1=A21+0+0+1=2A2A=12

Assume Ӭ=π2ħ/2ma2this will lead equation ( ) to becomeEn=n2Ӭħ, and therefore:

ψx,t=Aψ1xe-iE1t/ħ+ψ2xE-iE2t/ħ+=122asinπaxe-iӬt+2asin2πaxe-4iӬt=1asinπaxe-iӬt+sin2πaxe-4iӬt

The modulus squared of the wavefunction is:

ψx,t2=ψ*ψ=1asinπaxe-iӬt+sin2πaxe-4iӬt*×sin2πae-4iӬt=1asinπaxe-iӬt+sin2πaxe4iӬt*×sin2πae-4iӬt=1asin2πax+2sinπaxsin2πaxcos3Ӭt+sin22πax
02

Expectation value of the position.

Now find the expectation value of the position as follow:

x=∫-∞∞xψx,t2dx=1a∫0axsin2πax+2sinπaxsinπ2axcos3Ӭt+sin22πaxdx=1a∫0axsin2πaxdx+2cos3Ӭt∫0asinπaxsin2πaxdx+∫0asin22πaxdx

The first integral could be solve use integration by parts and assume u=x, then du=dx, anddv=sin22Ï€ax and by the use of integration table v=x2-a4Ï€sin2Ï€ax, therefore:

localid="1656316627360" =∫0axsin2πaxdx=x22-ax4πsin2πax0a-∫0ax2-a4πsin2πaxdx=x24-ax4πsin2πax-a28π2cos2πax0aa24

Do the same thing to the third integration and get the same result again. For the second integration use identity sinαsinβ=1/2cosα-β-cosα-βthen perform an integration by parts and obtain the result as:

=cos3Ӭt3a2π2cosπax+xaπsinπax-a29π2cos3πax-xa3πsin3πax0a=cos3Ӭt-16a29π2

03

Find the average energy.

Therefore, the expectation value of the position will be:

x=1aa24-cos3Ó¬t16a29Ï€2+a24=a9Ï€2-32cos3Ó¬t18Ï€2=a21-329Ï€2cos3Ó¬t

The expectation value of the momentum could be found by the use of the expectation value of the position, as:

p=mdxdt=mddta2-16a9π2cos3Ӭt=m16a9π23Ӭsin3Ӭt=m16a9π23π2ħ2ma2sin3Ӭt=8ħ3asin4Ӭt

Given below is two possible energies’ E1and E2, where,

E1=π2ħ22ma2E2=22π2ħ22ma2and each one has a probability of one half (i.e., p1=p2=1/2), therefore, the average energy (i.e., the expectation value of the energy) is:

H^=12E1+E2=5π2ħ24ma2

04

Calculate the value ofσH2.

The expression forσH2is given by:

σH2=H2-H2

The expression forH2is given by:

H2ψ=12H2ψ1e-E1t/ħ+H2ψ2e-Ent/ħ

Where,

Hψ1=E1ψ1H2ψ1=E1Hψ1=E12ψ1

And H2ψ2=E22ψ2.

The expectation value ofH2will be:

localid="1656347269478" H2=12ψ1e-iE1t/ħ+ψ2e-iE2t/ħIE12ψ1e-iE1t/ħ+E22ψ2e-iE2t/ħ12ψ1ψ1e-iE1t/ħE12e-iE2t/ħ+ψ1|ψ2e-iE1t/ħE22e-iE2t/ħ+ψ2|ψ1e-iE1t/ħE12e-iE2t/ħ+ψ2|ψ2e-iE1t/ħE22e-iE2t/ħ=12E12+E22H2=12E12+E22

Substitute all the known values in the expression of σH2.

σH2=12E12+E22-14E1+E22=142E12+2E22-E22-E12-2E1E2-E22=14E12-2E1E2+E22=14E2-E12Thus:σH=12E2-E1

05

 Find the expectation value of x2

Find the expectation value of x2, which is given by:

x2=12ψ1|x2ψ1+ψ2|x2ψ2+ψ1|x2ψ2ei(E1-E2)t/ħ+ψ2|x2ψ1ei(E2-E1)t/ħ

Solve the steps as given below,

ψn|x2|ψm=2a∫0ax2sinnπaxsinmπaxdx=2a2π2-1n-mn-m2--1n+mn+m2=2a2π2-1n+m4nmn2-m22

And from problem 2.4 obtain the result as :

ψn|x2ψn=a213-12nπ2

From the calculated values the expectation value of x2will be,

x2=12a213-12π2+a213-18π2-16a29π2e3iӬ+e-3iӬHere:E2-E1ħ=4-1π2ħ22ma2ħ=3π2ħ3Ӭbut2cos3Ӭt=e3iӬ+e-3iӬ;Thus,wecanwrite:x2=a2223-58π2-329π2cos3Ӭt

06

Calculate the value of σx2  .

Calculate σx2as:

σx2=x2-x2=a2443-54π2-649π2cos3Ӭt-1+649π2cos3Ӭt-329π22cos23Ӭt=a2413-54π2-329π22cos23Ӭt=a2413-54π2-329π22cos23ӬtTherefore,σx2=a2413-54π2-329π22cos23Ӭt

It is given that:

dxdt=8ħ3masin3ӬtNowchecktheenergy-timeuncertaintyprinciple:σH2σH2≥ħ24dxdt2TheLHSoftheequationis:σH2σx2=143ħӬ2a2413-54π2-329π22cos23Ӭt=ħӬa234213-54π2-329π22cos23ӬtAndtheRHSis:ħ24dxdt2=ħ28ħ3ma22sin23Ӭt=83π22ħӬa2sin23Ӭt

07

Test the energy-time uncertainty principle.

Theuncertaintyprincipleholdsif:34213-54π2-329π22cos23Ӭt≥83π22sin23ӬtFurthersolvingaboveequationas,13-54π2≥329π22cos23Ӭt+4383π22sin23Ӭt=329π2213-54π2≥329π22cos23Ӭt+sin23Ӭt13-54π2≥329π22Solvingforthegivenvalues:13-54π2=0.20668329π22=0.12978Thus,theuncertaintyprincipleholdsthecondition.

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