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The specific heat of a substance varies with temperature according to the function \(c=0.20+0.14 T+0.023 T^{2}\), with \(T\) in \({ }^{\circ} \mathrm{C}\) and \(c\) in \(\mathrm{cal} / \mathrm{g} \cdot \mathrm{K}\). Find the energy required to raise the temperature of \(2.0\) g of this substance from \(5.0^{\circ} \mathrm{C}\) to \(15^{\circ} \mathrm{C}\).

Short Answer

Expert verified
The energy required is 79.4 cal.

Step by step solution

01

Understanding the Problem

We are given a function for specific heat \(c\) as a function of temperature \(T\), which is \(c=0.20+0.14 T+0.023 T^{2}\). We need to calculate the energy required to raise the temperature of \(2.0\) grams of the substance from \(5.0^{\circ} \mathrm{C}\) to \(15^{\circ} \mathrm{C}\).
02

Formulate the Energy Equation

The energy \(Q\) required to change the temperature from \(T_1\) to \(T_2\) is given by \(Q = \int_{T_1}^{T_2} mc(T) \; dT\), where \(m\) is the mass and \(c(T)\) is the specific heat function.
03

Set Limits and Insert Specific Heat Function

For our problem, \(m = 2.0\, \text{g}\), \(T_1 = 5.0^{\circ} \mathrm{C}\), and \(T_2 = 15^{\circ} \mathrm{C}\). Substitute \(c(T) = 0.20 + 0.14T + 0.023T^2\) into the integral to get \(Q = \int_{5}^{15} 2(0.20 + 0.14T + 0.023T^2)\; dT\).
04

Simplify and Integrate

Simplify the integral to \(Q = 2 \int_{5}^{15} (0.20 + 0.14T + 0.023T^2)\; dT\). This expands to \(Q = 2 \left[ \int_{5}^{15} 0.20 \; dT + \int_{5}^{15} 0.14T \; dT + \int_{5}^{15} 0.023T^2 \; dT \right]\).
05

Calculate Each Integral

Calculate each integral separately: - \(\int 0.20 \; dT = 0.20T\)- \(\int 0.14T \; dT = 0.14 \frac{T^2}{2} = 0.07T^2\)- \(\int 0.023T^2 \; dT = 0.023 \frac{T^3}{3}\)Evaluate each expression from 5 to 15.
06

Evaluate Definite Integrals

Evaluate the expressions:- For \(0.20T: [0.20(15) - 0.20(5)] = 2.0\)- For \(0.07T^2: [0.07(15)^2 - 0.07(5)^2] = 14.7\)- For \(0.023 \frac{T^3}{3}: [0.023 \frac{15^3}{3} - 0.023 \frac{5^3}{3}] = 24.92 - 1.92 = 23.0\)
07

Sum and Multiply by Mass Factor

Sum the evaluated integrals: \(2.0 + 14.7 + 23.0 = 39.7\). Multiply by the mass factor (2.0 g): \(Q = 2 \times 39.7 = 79.4 \; \text{cal}\).
08

Conclusion

The energy required to raise the temperature of the substance from \(5.0^{\circ} \mathrm{C}\) to \(15^{\circ} \mathrm{C}\) is \(79.4 \; \mathrm{cal}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Specific Heat Capacity
Specific heat capacity is a crucial concept in thermodynamics. It represents the amount of heat energy required to raise the temperature of a unit mass of a substance by one degree Celsius (or Kelvin). Different substances have different specific heat capacities, which means they react to heat differently. In this problem, the specific heat is not constant, but rather varies with temperature, following the equation \(c = 0.20 + 0.14T + 0.023T^2\). This variation means that, as the temperature changes, the specific heat capacity changes too, which makes our calculation more complex. Understanding this variation is essential for accurately calculating the energy needed to change the temperature of a substance.
Energy Calculation
Energy calculation in this context typically involves determining how much energy, measured in calories or joules, is needed to change the temperature of a given mass of a substance. The formula used is derived from the principle that energy \(Q\) is equal to the mass \(m\) of the substance multiplied by the specific heat capacity \(c(T)\), integrated over the change in temperature \(T\):
  • \(Q = \int_{T_1}^{T_2} mc(T) \, \mathrm{d}T\)
In our exercise, \( m = 2.0 \, \mathrm{g}\) and the temperature range is from 5°C to 15°C. By inserting the specific heat function into this integral, we are able to calculate the energy required for this temperature change. This process involves using calculus to accommodate the fact that \(c\) changes with \(T\).
Temperature Change
Temperature change is a fundamental part of many physics and chemistry problems. Here, we're dealing with raising the temperature of a substance from 5°C to 15°C. The total temperature change \(\Delta T\) is the difference between the final and initial temperatures. In our case, \(\Delta T = 15^{\circ}\mathrm{C} - 5^{\circ}\mathrm{C} = 10^{\circ}\mathrm{C}\). Understanding this change is critical because it defines the limits of our integration for calculating energy. It's also important because the energy required is directly influenced by both the magnitude of the temperature change and how the specific heat capacity varies over that range.
Integral Calculus in Physics
Integral calculus is indispensable in physics for calculating quantities that are accumulative in nature. In this case, it allows us to add up all the tiny bits of energy needed as the temperature changes from 5°C to 15°C, where the specific heat \(c\) isn't constant. The integral
  • \(\int_{5}^{15} (0.20 + 0.14T + 0.023T^2) \, \mathrm{d}T\)
is simplified by calculating each term separately:
  • Constant term: \(0.20 \times \Delta T\)
  • Linear term: \(0.14 \frac{T^2}{2}\)
  • Quadratic term: \(0.023 \frac{T^3}{3}\)
These terms are then evaluated between the limits of 5 and 15, added together, and multiplied by the mass of the substance. This process illustrates how calculus helps handle changes across differential elements in a system.

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Most popular questions from this chapter

Suppose that you intercept \(5.0 \times 10^{-3}\) of the energy radiated by a hot sphere that has a radius of \(0.020 \mathrm{~m}\), an emissivity of \(0.80\), and a surface temperature of \(500 \mathrm{~K} .\) How much energy do you intercept in \(2.0 \mathrm{~min} ?\)

A person makes a quantity of iced tea by mixing \(500 \mathrm{~g}\) of hot tea (essentially water) with an equal mass of ice at its melting point. Assume the mixture has negligible energy exchanges with its environment. If the tea's initial temperature is \(T_{i}=90^{\circ} \mathrm{C}\), when thermal equilibrium is reached what are (a) the mixture's temperature \(T_{f}\) and (b) the remaining mass \(m_{f}\) of ice? If \(T_{i}=70^{\circ} \mathrm{C}\), when thermal equilibrium is reached what are (c) \(T_{f}\) and (d) \(m_{f}\) ?

A small electric immersion heater is used to heat \(100 \mathrm{~g}\) of water for a cup of instant coffee. The heater is labeled "200 watts" (it converts electrical energy to thermal energy at this rate). Calculate the time required to bring all this water from \(23.0^{\circ} \mathrm{C}\) to \(100^{\circ} \mathrm{C}\), ignoring any heat losses.

\({ }^}\) "as The giant hornet Vespa mandarinia japonica preys on Japanese bees. However, if one of the hornets attempts to invade a beehive, several hundred of the bees quickly form a compact ball around the hornet to stop it. They don't sting, bite, crush, or suffocate it. Rather they overheat it by quickly raising their body temperatures from the normal \(35^{\circ} \mathrm{C}\) to \(47^{\circ} \mathrm{C}\) or \(48^{\circ} \mathrm{C}\), which is lethal to the hornet but not to the bees (Fig. 18-43). Assume the following: 500 bees form a ball of radius \(R=2.0 \mathrm{~cm}\) for a time \(t=20 \mathrm{~min}\), the primary loss of energy by the ball is by thermal radiation, the ball's surface has emissivity \(\varepsilon=0.80\), and the ball has a uniform temperature. On average, how much additional energy must each bee produce during the 20 min to maintain \(47^{\circ} \mathrm{C}\) ?

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