Chapter 41: Problem 20
What is the number of occupied states in the energy range of \(0.0300 \mathrm{eV}\) that is centered at a height of \(6.10 \mathrm{eV}\) in the valence band if the sample volume is \(5.00 \times 10^{-8} \mathrm{~m}^{3}\), the Fermi level is \(5.00 \mathrm{eV},\) and the temperature is \(1500 \mathrm{~K} ?\)
Short Answer
Step by step solution
Understanding the Given Problem
Identify Key Values
Calculate Density of States (DOS)
Determine Occupied State Probability with Fermi-Dirac Distribution
Calculate Number of Occupied States
Estimate and Provide the Final Solution
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Density of States
In a simplified model where the density of states is approximated for a parabolic band, it is represented by the equation: \[ g(E) = \frac{1}{2\pi^2} \left(\frac{2m}{\hbar^2}\right)^{3/2} \sqrt{E} \]
- \(g(E)\) is the density of states at energy \(E\).
- \(m\) is the effective mass of the electron, often assumed to be similar to the electron mass \(m_e\).
- \(\hbar\) is the reduced Planck's constant.
Fermi Level
At temperatures greater than absolute zero, electrons have enough thermal energy to move to higher energy states, and not all of them will be at or below the Fermi level. However, this level still acts as a pivotal point for distribution calculations.
In our problem, the Fermi level is given as 5.00 eV. This is used to calculate the probability that an electron occupies a specific energy level using the Fermi-Dirac distribution. When dealing with temperatures such as 1500 K, the Fermi level helps us understand how electrons are distributed across various energy states.
Valence Band
Electrons in the valence band are crucial for determining a material's properties, such as electrical conductivity. In semiconductors, the valence band's occupation by electrons plays a major role in band gaps and how electrons move across bands.
In our example, we are interested in the number of occupied states in the valence band with an energy range centered at 6.10 eV. This involves examining how these states are filled within the specified band, often using the density of states calculations paired with probabilities from Fermi-Dirac distribution.
Fermi-Dirac Distribution
The distribution function is given by:\[ f(E) = \frac{1}{e^{(E-E_f)/kT} + 1} \]
- \(f(E)\) is the probability of an electron occupying an energy state \(E\).
- \(E_f\) is the Fermi level energy.
- \(k\) is Boltzmann's constant (\(8.617 \times 10^{-5} \text{ eV/K}\)).
- \(T\) is the absolute temperature in Kelvin.