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What mass of steam at 1000C must be mixed with 150gof ice at its melting point, in a thermally insulated container, to produce liquid water at 500C?

Short Answer

Expert verified

The mass of the steam is 33g

Step by step solution

01

Identification of given data

i) The mass of the ice is mi=150g

ii) The initial temperature of the steam is Ti=100°°ä

iii) The final temperature of the liquid water is Tf=50°°ä

02

 Step 2: Significance of specific heat

The specific heat capacity of the material is the amount of heat required to change the temperature of a unit mass of material by one degree.

We can use the concept of specific heat and heat of transformation. The steam mixes with ice and forms liquid water. Hence, there is a phase change, so we can use the expression of the heat of vaporization. At the same time, the ice is converted to water, so there is the heat of fusion.

Formulae:

The heat energy required by a bodyQ=mcΔT , …(i)

Here, m = mass

c= specific heat capacity

ΔT= change in temperature

data-custom-editor="chemistry" Q= required heat energy

The heat energy released or absorbed by the bodyQ=Lm , …(ii)

L= specific latent heat

03

 Step 3: Determining the mass of the steam

Let msbe the mass of the steam, the energy transferred by the steam when mixed with ice by the expression of specific heat and heat of vaporization is given by using equations (i) and (ii) as:

Q=cwms|Ti−Tf|+LVms

The specific heat of water iscw=1 cal/g°°ä

The heat of vaporization is LV=539cal/g

The initial temperature of the steam isTi=100 °°ä, then

Q=cwms|1000C−Tf|+LVms …(¾±¾±¾±)

Let mibe the mass of ice, the energy used by the ice when mixed with steam by the expression of specific heat and heat of fusion using equations (i) and (ii) is given by:

Q=cwmi(Tf−Ti)+LFmi

Where heat of fusion of water isLF=79.5cal/g

The initial temperature of the ice is Ti=0.0 °C, then

Q=cwmi(Tf−0.00C)+LFmi …(¾±±¹)

When ice is mixed with steam, the energy given by the steam is equal to the energy accepted by the ice, hence, equating equation (iii) with equation (iv) as

cwms|100°C−Tf|+LVms=cwmi(Tf−0.0°C)+LFmims=cwmi(Tf−0.0°C)+LFmicw|100°C−Tf|+LV=1calg°C×150g(50°C−0.0°C)+79.5calg×150 g1calg°°ä|100°C−50°C|+539cal/g=33g

Hence, the value of the mass of the steam is 33g

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