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Light of wavelength 121.6 nm is emitted by a hydrogen atom. What are the (a) higher quantum number and (b) lower quantum number of the transition producing this emission? (c) What is the series that includes the transition?

Short Answer

Expert verified

(a) Higher quantum number, n1=2

(b) Lower quantum number,n2=1

(c) Lyman series.

Step by step solution

01

Identification of the given data:

The given data is listed below.

Wavelength of light is =121.6nm.

02

The principal Quantum number:

The principal quantum number is used to describe the electron鈥檚 state and is the one-four quantum number assigned to each electron in an atom.

The value of the principal quantum number is a natural number.

03

(a) Determine the value of the higher quantum number:

The energy emitted by the hydrogen atom of the photon is expressed as,

Eph=A1n22-1n12

Now, multiply both sides by 1hc, and you have

Ephhc=Ahc1n22-1n12

Also as the wavelength is,

1=EPhhc

SubstituteAhc1n22-1n12forEPhhcin the above equation.

1=Ahc1n22-1n12hcA=1n22-1n12

Substitute 121.6 nm for , 6.2610-34J.sfor h , 3108m/sfor c , and 13.6 eV for A in the above equation.

6.2610-34J.s3108m/s121.610-9m13.61.60210-9J=1n22-1n120.75=1n22-1n12

To satisfy the above equation, the values of n2and n1are 1 and 2 respectively. Thus,

112-122=0.75

Thus, the higher quantum number is n1=2.

04

(b) Determine the value of lower quantum number:

And so,

112-122=0.75

Thus, the lower quantum number is n2=1.

05

(c) Determine the name of the series that includes the transition:

The name of the series that includes the transition is Lyman series transition as this transition occurs when the electron goes from n1to n2emitting a photon.

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