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Consider a two-dimensional square crystal structure, such as one side of the structure shown in Fig. 36-28a.The largest interplanar spacing of reflecting planes is the unit cell size ao. Calculate and sketch the (a) second largest, (b) third largest, (c) fourth largest, (d) fifth largest, and (e) sixth largest interplanar spacing. (f) Show that your results in (a) through (e) are consistent with the general formula

d=aoh2+k2

where h and k are relatively prime integers (they have no common factor other than unity).

Short Answer

Expert verified

a d2=ao2

b. d3=ao5

c. d4=ao10

d. d5=ao17

e.d6=ao26

Step by step solution

01

Bragg’s law

If the incident direction of the wave, measured from the surfaces of these planes, and the radiation's wavelengthλ fulfil Bragg's equation, diffraction maxima (caused by constructive interference) happen

2»å²õ¾±²Ôθ=³¾Î»; m=1,2,3...(Bragg’s equation)

Where dis the interplanar distance,θ is the angle of the incident beam,λ is the wavelength of the incident beam, andm is the order of the maximum intensity.

The largest interplanar spacing is given is equal to the cell size ao.

02

(a) Second largest interplanar spacing.

Family of planes whose interplanar spacing is second largest is shown below,

The planes are diagonal to horizontal family of planes. As the total length between the lines is 2d2( whered2 is second largest interplanar spacing) and it forms a right-angled triangle from which we can determine usingd2 Pythagoras theorem,

(2d2)2=(ao)2+(ao)2d22=ao22d2=ao2

03

(b) The third largest Interplanar spacing

The Family of planes whose interplanar spacing is third largest is shown below,

As the total length between the lines is5d3( where d3is third largest interplanar spacing) and it forms a right-angled triangle from which we can determine role="math" localid="1663405458726" d3using Pythagoras theorem,

(5d3)2=(ao)2+(2ao)225d32=5ao2d3=ao5

04

(c) The fourth largest Interplanar spacing

The Family of planes whose interplanar spacing is fourth largest is shown below,

As the total length between the lines is 10d4( where d4is fourth largest interplanar spacing) and it forms a right-angled triangle from which we can determine d4using Pythagoras theorem,

(10d4)2=(ao)2+(3ao)2100d42=10ao2d4=ao10

05

(d) Fifth largest interplanar spacing    

The family of planes which have fifth largest spacing is shown below

As the total length between the lines is 17d5( where d5is fifth largest interplanar spacing) and it forms a right-angled triangle from which we can determine d5using Pythagoras theorem,

(17d5)2=(ao)2+(4ao)2289d52=17ao2d5=ao17

06

(e) Sixth largest interplanar spacing.

The family of planes which have sixth largest spacing is shown below

As the total length between the lines is 26d6( where d6is sixth largest interplanar spacing) and it forms a right-angled triangle from which we can determine d6using Pythagoras theorem,

(26d6)2=(ao)2+(5ao)2676d62=26ao2d6=ao26

07

(f) Verify the values of interplanar spacings using the given formula.

In the figures, the distance between the family of lines can represented as position vector with its lower end of the segment as origin (0,0). Just like position vector, this segment can be represented as a linear combination of x^and y^as

d=hx^ + ky^

Where, x^and y^are smallest unit of distance in x and y direction whose magnitude in this case is aoand h&kare integers.

For the second largest, the distance can be written as

d2=x^+y^

With values of h=1 & k=1. Putting these values in the given formula

d2=ao(1)2+(1)2=ao2

For third largest spacing, the distance can be written as

d3=x^+2y^

With values of h=1 & k=2. Putting these values in the given formula

d3=ao(1)2+(2)2=ao5

For fourth largest spacing, the distance can be written as

d4=x^+3y^

With values of h=1 & k=3. Putting these values in the given formula

d4=ao(1)2+(3)2=ao10

For fifth largest spacing, the distance can be written as

d5=x^+4y^

With values of h=1 & k=4. Putting these values in the given formula

d5=ao(1)2+(4)2=ao17

For sixth largest spacing, the distance can be written as

d6=x^+5y^

With values of h=1 & k=5. Putting these values in the given formula

d6=ao(1)2+(5)2=ao26

Thus, all values of interplanar distance are verified using the given formula.

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