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A gas flows through a one-inlet, one-exit control volume operating at steady state. Heat transfer at the rate \(\dot{Q}_{\mathrm{cv}}\) takes place only at a location on the boundary where the temperature is \(T_{\mathrm{b}}\). For each of the following cases, determine whether the specific entropy of the gas at the exit is greater than, equal to, or less than the specific entropy of the gas at the inlet: (a) no internal irreversibilities, \(\dot{Q}_{\mathrm{cv}}=0\). (b) no internal irreversibilities, \(\dot{Q}_{\mathrm{cv}}<0\). (c) no internal irreversibilities, \(\dot{Q}_{\mathrm{cv}}>0\). (d) internal irreversibilities, \(\dot{Q}_{\mathrm{cv}}<0\). (e) internal irreversibilities, \(\dot{Q}_{\mathrm{cv}} \geq 0\)

Short Answer

Expert verified
a) Equal, b) Less, c) Greater, d) Uncertain, e) Greater.

Step by step solution

01

- Understand the entropy balance equation

For a control volume operating at steady state, the entropy balance can be expressed as: \[ \frac{dS_{cv}}{dt} = \frac{\text{d}\text{mi}_{in}}{T_{in}} - \frac{\text{d}\text{mi}_{out}}{T_{out}} + \frac{Q_{cv}}{T_b} + \text{entropy generation} \] Since the system is at steady state, there is no accumulation of entropy within the control volume, so \[ \frac{dS_{cv}}{dt} = 0 \].
02

- Simplify the entropy balance equation

Given that \( \frac{dS_{cv}}{dt} = 0 \), the entropy balance equation becomes: \[ \frac{\text{d}\text{mi}_{in}}{T_{in}} - \frac{\text{d}\text{mi}_{out}}{T_{out}} + \frac{Q_{cv}}{T_b} + \text{entropy generation} = 0 \]
03

- Analyze the case \( \text{(a)} \)

For case \( \text{(a)} \), no internal irreversibilities and \( \text{Q}_{\text{cv}} = 0 \): Since there are no internal irreversibilities, entropy generation is zero. The entropy balance reduces to: \[ \frac{\text{d}\text{mi}_{in}}{T_{in}} = \frac{\text{d}\text{mi}_{out}}{T_{out}} \] Therefore, the specific entropy at the exit is equal to that at the inlet.
04

- Analyze the case \( \text{(b)} \)

For case \( \text{(b)} \), no internal irreversibilities and \( \text{Q}_{\text{cv}} < 0 \): Negative heat transfer means heat is leaving the system. Since there are no internal irreversibilities, entropy generation is zero. The entropy balance reduces to: \[ \frac{\text{d}\text{mi}_{in}}{T_{in}} = \frac{\text{d}\text{mi}_{out}}{T_{out}} - \frac{|Q_{cv}|}{T_b} \] Therefore, specific entropy at the exit is less than that at the inlet.
05

- Analyze the case \( \text{(c)} \)

For case \( \text{(c)} \), no internal irreversibilities and \( \text{Q}_{\text{cv}} > 0 \): Positive heat transfer means heat is entering the system. Since there are no internal irreversibilities, entropy generation is zero. The entropy balance reduces to: \[ \frac{\text{d}\text{mi}_{in}}{T_{in}} = \frac{\text{d}\text{mi}_{out}}{T_{out}} + \frac{Q_{cv}}{T_b} \] Therefore, specific entropy at the exit is greater than that at the inlet.
06

- Analyze the case \( \text{(d)} \)

For case \( \text{(d)} \), internal irreversibilities and \( \text{Q}_{\text{cv}} < 0 \): Negative heat transfer means heat is leaving the system. Since there are internal irreversibilities, entropy generation is positive. The entropy balance equation becomes: \[ \frac{\text{d}\text{mi}_{in}}{T_{in}} = \frac{\text{d}\text{mi}_{out}}{T_{out}} - \frac{|Q_{cv}|}{T_b} + \text{entropy generation} \] Therefore, specific entropy at the exit is not necessarily less than the inlet because the entropy generation might counteract heat loss.
07

- Analyze the case \( \text{(e)} \)

For case \( \text{(e)} \), internal irreversibilities and \( \text{Q}_{\text{cv}} \text{is greater than or equal to} 0 \): Positive or zero heat transfer means heat is entering or there is no heat transfer, respectively. Since there are internal irreversibilities, entropy generation is positive. The entropy balance equation becomes: \[ \frac{\text{d}\text{mi}_{in}}{T_{in}} = \frac{\text{d}\text{mi}_{out}}{T_{out}} + \frac{Q_{cv}}{T_b} + \text{entropy generation} \] Therefore, specific entropy at the exit is greater than the inlet due to positive entropy generation and possible heat transfer.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

steady-state analysis
In thermodynamics, a steady-state analysis is crucial for understanding systems where conditions remain constant over time. This means that properties such as temperature, pressure, and specific entropy do not change as time passes.
Analysis of a system at steady state simplifies our calculations because we can ignore time-dependent changes. We assume that all inflows and outflows are constant.
In our exercise, the gas flows through a control volume in steady state. This implies a steady flow of mass and energy, which is helpful for applying the entropy balance equation to determine specific entropy changes.
heat transfer
Heat transfer is the movement of thermal energy from one place to another due to temperature differences. In the context of our exercise, heat transfer at a given rate \(\theta{Q}_{cv}\) takes place at the system's boundary where the temperature is \(T_{b}\).
Heat transfer can affect the entropy of a system. When heat is transferred into the system (positive \(Q_{cv}\)), it increases the system's entropy. Conversely, when heat is transferred out of the system (negative \(Q_{cv}\)), it decreases the system's entropy.
Understanding how heat transfer interacts with entropy helps us determine whether the specific entropy at the exit is greater than, equal to, or less than the specific entropy at the inlet.
internal irreversibilities
Internal irreversibilities refer to inefficiencies within a thermodynamic system that generate additional entropy. These can be caused by friction, turbulence, or other non-ideal processes.
In the exercise, internal irreversibilities influence whether entropy generation is zero or positive. For scenarios without internal irreversibilities, it's assumed there is no additional entropy generation.
Understanding the presence of internal irreversibilities helps us analyze the changes in specific entropy. For example, if internal irreversibilities are present, it means positive entropy generation, leading to potentially higher specific entropy at the exit compared to the inlet.
specific entropy
Specific entropy is a measure of the disorder or randomness per unit mass in a system. It's denoted as \(s\) and is typically measured in units of J/(kg·K).
In the entropy balance equation, specific entropy helps us understand how the entropy values at the inlet and outlet of the control volume compare.
For this exercise, we want to determine the effect of different scenarios on specific entropy. Factors like heat transfer, presence of internal irreversibilities, and steady-state analysis provide the context for determining whether specific entropy at the exit is greater than, equal to, or less than at the inlet.
thermodynamic systems
A thermodynamic system is a defined space or quantity of matter where we study energy and mass interactions with its surroundings.
In this exercise, the gas flowing through a one-inlet, one-exit control volume is our thermodynamic system. To analyze it, we apply principles from thermodynamics, such as the entropy balance equation, under the assumption of steady state.
Understanding the behavior of thermodynamic systems enables us to predict how variables like heat transfer and internal irreversibilities impact specific entropy, helping us solve for the conditions at the inlet and exit.

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Most popular questions from this chapter

Ammonia enters a valve as a saturated liquid at 7 bar with a mass flow rate of \(0.06 \mathrm{~kg} / \mathrm{min}\) and is steadily throttled to a pressure of 1 bar. Determine the rate of entropy production in \(\mathrm{kW} / \mathrm{K}\). If the valve were replaced by a power-recovery turbine operating at steady state, determine the maximum theoretical power that could be developed, in \(\mathrm{kW}\). In each case, ignore heat transfer with the surroundings and changes in kinetic and potential energy. Would you recommend using such a turbine?

Nitrogen \(\left(\mathrm{N}_{2}\right)\) initially occupying \(0.5 \mathrm{~m}^{3}\) at \(1.0\) bar, \(20^{\circ} \mathrm{C}\) undergoes an internally reversible compression during which \(p V^{1.30}=\) constant to a final state where the temperature is \(200^{\circ} \mathrm{C}\). Determine assuming the ideal gas model (a) the pressure at the final state, in bar. (b) the work and heat transfer, each in \(\mathrm{kJ}\). (c) the entropy change, in \(\mathrm{kJ} / \mathrm{K}\).

One-half kilogram of propane initially at 4 bar, \(30^{\circ} \mathrm{C}\) undergoes a process to 14 bar, \(100^{\circ} \mathrm{C}\) while being rapidly compressed in a piston-cylinder assembly. Heat transfer with the surroundings at \(20^{\circ} \mathrm{C}\) occurs through a thin wall. The net work is measured as \(-72.5 \mathrm{~kJ}\). Kinetic and potential energy effects can be ignored. Determine whether it is possible for the work measurement to be correct.

Employing the ideal gas model, determine the change in specific entropy between the indicated states, in \(\mathrm{kJ} / \mathrm{kg} \cdot \mathrm{K}\). Solve three ways: Use the appropriate ideal gas table, \(I T\), and a constant specific heat value from Table A-20. (a) air, \(p_{1}=100 \mathrm{kPa}, T_{1}=20^{\circ} \mathrm{C}, p_{2}=100 \mathrm{kPa}, T_{2}=\) \(100^{\circ} \mathrm{C} .\) (b) air, \(p_{1}=1\) bar, \(T_{1}=27^{\circ} \mathrm{C}, p_{2}=3\) bar, \(T_{2}=377^{\circ} \mathrm{C}\). (c) carbon dioxide, \(p_{1}=150 \mathrm{kPa}, T_{1}=30^{\circ} \mathrm{C}, p_{2}=300 \mathrm{kPa}\), \(T_{2}=300^{\circ} \mathrm{C}\) (d) carbon monoxide, \(T_{1}=300 \mathrm{~K}, v_{1}=1.1 \mathrm{~m}^{3} / \mathrm{kg}, T_{2}=500 \mathrm{~K}\), \(v_{2}=0.75 \mathrm{~m}^{3} / \mathrm{kg}\) (e) nitrogen, \(p_{1}=2 \mathrm{MPa}, T_{1}=800 \mathrm{~K}, p_{2}=1 \mathrm{MPa}\), \(T_{2}=300 \mathrm{~K}\)

An insulated cylinder is initially divided into halves by a frictionless, thermally conducting piston. On one side of the piston is \(1 \mathrm{~m}^{3}\) of a gas at \(300 \mathrm{~K}, 2\) bar. On the other side is \(1 \mathrm{~m}^{3}\) of the same gas at \(300 \mathrm{~K}, 1\) bar. The piston is released and equilibrium is attained, with the piston experiencing no change of state. Employing the ideal gas model for the gas, determine (a) the final temperature, in \(\mathrm{K}\). (b) the final pressure, in bar. (c) the amount of entropy produced, in \(\mathrm{kJ} / \mathrm{kg}\).

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