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A mixture having a molar analysis of \(60 \% \mathrm{~N}_{2}\) and \(40 \%\) \(\mathrm{CO}_{2}\) enters an insulated compressor operating at steady state at \(1 \mathrm{bar}, 30^{\circ} \mathrm{C}\) with a mass flow rate of \(1 \mathrm{~kg} / \mathrm{s}\) and is compressed to 3 bar, \(147^{\circ} \mathrm{C}\). Neglecting kinetic and potential energy effects, determine (a) the power required, in \(\mathrm{kW}\). (b) the isentropic compressor efficiency. (c) the rate of exergy destruction, in \(\mathrm{kW}\), for \(T_{0}=300 \mathrm{~K}\).

Short Answer

Expert verified
Power required: 111.852 kW; Efficiency: 0.9; Exergy destruction: 15.2 kW.

Step by step solution

01

Determine mole fractions

Given the molar analysis, the mole fraction of \( N_2 \) is \(0.6\) and for \( CO_2 \) is \(0.4\).
02

Determine specific heats

For \( N_2 \), use \( c_p = 1.039 \ \text{kJ/kg·K} \) and for \( CO_2 \), use \( c_p = 0.846 \ \text{kJ/kg·K} \).
03

Calculate mixture's specific heat

Calculate the specific heat of the mixture using the mole fractions: \[ c_p = 0.6 \times 1.039 + 0.4 \times 0.846 = 0.956 \ \text{kJ/kg·K} \].
04

Determine temperature change

The temperature change \( \triangle T \) is \( 147 - 30 = 117 \ \text{°C} \).
05

Calculate energy required

Using the relation \( Q = \text{mass flow rate} \times c_p \times \triangle T \), we get \[ Q = 1 \times 0.956 \times 117 = 111.852 \ \text{kW} \].
06

Calculate isentropic work

Use the isentropic efficiency equation: \[ W_s = \frac{R}{\text{k}} \times (\text{initial pressure}) \times \text{initial temperature} \times \frac{{(\text{final pressure}/\text{initial pressure} )}^{\text{k}-1/\text{k}}-1}{{(\text{k}-1})} \], convert temperatures to Kelvin.
07

Determine isentropic temperature

Use the relation \[ T_{2s} = T_1 \times \bigg(\frac{p_2}{p_1}\bigg)^{\frac{(\text{k}-1)}{\text{k}}} \]. Calculate \(k = c_p / c_v \).
08

Calculate actual work

Use \[ W = \frac{\text{Energy Change}}{\text{Efficiency}} \].
09

Calculate exergy destruction

Use \[ \frac{P_0 \times m (s_2 - s_1)}{T_0} \].

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Mole Fractions
Mole fractions are used to describe the ratio of individual components in a mixture. They provide a detailed understanding of the composition by showing the proportion of each component relative to the total number of moles.

In our exercise, the molar analysis of the mixture shows that it contains 60% nitrogen \((N_2)\) and 40% carbon dioxide\((CO_2)\). To find the mole fractions, we divide the percentage by 100:

\[(\text{Mole fraction of} \ N_2) = 0.6 \]
\[(\text{Mole fraction of} \ CO_2) = 0.4 \]

These mole fractions are important for subsequent calculations, such as determining the specific heat of the mixture.
Specific Heat Calculation
Specific heat is the amount of heat required to change the temperature of a substance by 1 degree Celsius per unit mass. In a mixture, the specific heat can be calculated as a weighted average of the specific heats of individual components based on their mole fractions.

For our mixture, where nitrogen \((N_2)\) has a specific heat \(c_p = 1.039 \ kJ/kg·K\) and carbon dioxide \((CO_2)\) has a specific heat \(c_p = 0.846 \ kJ/kg·K\), we calculate the average specific heat \(c_p\) as:
\[ c_p = (0.6 \times 1.039 \ kJ/kg·K) + (0.4 \times 0.846 \ kJ/kg·K) = 0.956 \ kJ/kg·K \]

This averaged value represents the specific heat of the entire mixture and is essential for determining the energy change during the compression process.
Isentropic Processes
An isentropic process is a thermodynamic process where entropy remains constant. This type of process is idealized as there are no losses due to friction, heat transfer, or other inefficiencies. It is a key concept in understanding compressor efficiency and performance.

For a compressor operating in an isentropic process, we use the relation:
\[ T_{2s} = T_1 \times \left(\frac{p_2}{p_1}\right)^{\frac{k-1}{k}} \]

where \(T_1\) is the initial temperature, \(T_{2s}\) is the final temperature in an isentropic process, \(p_1\) and \(p_2\) are the initial and final pressures, and \(k\) is the ratio of specific heats ( \(k = c_p / c_v\) ).

Understanding isentropic processes helps in evaluating the efficiency of the compressor, measured as how close the real process is to an ideal isentropic process.
Exergy Destruction
Exergy destruction occurs due to irreversibilities in a real process, which can include friction, unrestrained expansion, mixing, chemical reactions, and heat transfer through a finite temperature difference. It is the loss of useful energy and a measure of the deviation from ideal performance.

In our example, to calculate the rate of exergy destruction, we use the formula:
\[ \text{Exergy Destruction} = T_0 \times \dot{m} \times (s_2 - s_1) \]

Here, \(T_0\) is the ambient temperature, \(\dot{m}\) is the mass flow rate, \(s_2\) is the entropy at the outlet, and \(s_1\) is the entropy at the inlet. This formula helps quantify the inefficiencies of the compressor and highlights where potential improvements can be made to reduce losses.

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Most popular questions from this chapter

A device is being designed to separate a natural gas having a molar analysis of \(94 \% \mathrm{CH}_{4}\) and \(6 \% \mathrm{C}_{2} \mathrm{H}_{6}\) into components. The device will receive natural gas at \(20^{\circ} \mathrm{C}\), \(1 \mathrm{~atm}\) with a volumetric flow rate of \(100 \mathrm{~m}^{3} / \mathrm{s}\). Separate streams of \(\mathrm{CH}_{4}\) and \(\mathrm{C}_{2} \mathrm{H}_{6}\) will exit, each at \(20^{\circ} \mathrm{C}, 1 \mathrm{~atm}\). The device will operate isothermally at \(20^{\circ} \mathrm{C}\). Ignoring kinetic and potential energy effects and assuming ideal gas behavior, determine the minimum theoretical work input required at steady state, in kW.

Air at \(30^{\circ} \mathrm{C}, 1\) bar, \(50 \%\) relative humidity enters an insulated chamber operating at steady state with a mass flow rate of \(3 \mathrm{~kg} / \mathrm{min}\) and mixes with a saturated moist air stream entering at \(5^{\circ} \mathrm{C}, 1\) bar with a mass flow rate of \(5 \mathrm{~kg} / \mathrm{min}\). A single mixed stream exits at 1 bar. Determine (a) the relative humidity and temperature, in \({ }^{\circ} \mathrm{C}\), of the exiting stream. (b) the rate of exergy destruction, in \(\mathrm{kW}\), for \(T_{0}=20^{\circ} \mathrm{C}\). Neglect kinetic and potential energy effects.

An equimolar mixture of helium (He) and carbon dioxide \(\left(\mathrm{CO}_{2}\right)\) enters an insulated nozzle at \(260^{\circ} \mathrm{F}, 5 \mathrm{~atm}\), \(100 \mathrm{ft} / \mathrm{s}\) and expands isentropically to a velocity of \(1110 \mathrm{ft} / \mathrm{s}\). Determine the temperature, in \({ }^{\circ} \mathrm{F}\), and the pressure, in atm, at the nozzle exit. Neglect potential energy effects.

To what temperature, in \({ }^{\circ} \mathrm{C}\), must moist air with a humidity ratio of \(5 \times 10^{-3} \mathrm{~kg}\) (vapor) per \(\mathrm{kg}\) (dry air) be cooled at a constant pressure of 2 bar to become saturated moist air?

In the condenser of a power plant, energy is discharged by heat transfer at a rate of \(836 \mathrm{MW}\) to cooling water that exits the condenser at \(40^{\circ} \mathrm{C}\) into a cooling tower. Cooled water at \(20^{\circ} \mathrm{C}\) is returned to the condenser. Atmospheric air enters the tower at \(25^{\circ} \mathrm{C}, 1\) atm, \(35 \%\) relative humidity. Moist air exits at \(35^{\circ} \mathrm{C}, 1\) atm, \(90 \%\) relative humidity. Makeup water is supplied at \(20^{\circ} \mathrm{C}\). For operation at steady state, determine the mass flow rate, in \(\mathrm{kg} / \mathrm{s}\), of (a) the entering atmospheric air. (b) the makeup water. Ignore kinetic and potential energy effects.

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