Chapter 19: Problem 1
Could you cool the kitchen by leaving the refrigerator open? Explain.
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Chapter 19: Problem 1
Could you cool the kitchen by leaving the refrigerator open? Explain.
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A cosmic heat engine might operate between the Sun's \(5800 \mathrm{~K}\) surface and the \(2.7 \mathrm{~K}\) temperature of intergalactic space. What would be its maximum efficiency?
(a) Continue the calculation begun on page 372 in the subsection "Irreversible Heat Transfer" to derive the expression given in the text for the entropy change when equal masses \(m\) of hot and cold water, at temperatures \(T_{\mathrm{h}}\) and \(T_{c}\), respectively, are mixed: \(\Delta S=m c \ln \left[\left(T_{c}+T_{\mathrm{h}}\right)^{2} / 4 T_{\mathrm{c}} T_{\mathrm{h}}\right]\). (b) Show that the argument of the logarithm in this expression is greater than 1 for \(T_{\mathrm{h}} \neq T_{c}\), thus showing that \(\Delta S\) is positive. Hint: This is equivalent to showing that \(\left(T_{c}+T_{\mathrm{h}}\right)^{2}>4 T_{\mathrm{c}} T_{\mathrm{h}}\). Expand the left side of this inequality, subtract \(4 T_{\mathrm{c}} T_{\mathrm{h}}\) from both sides, factor the resulting left side, and you'll have your result.
The molar specific heat at constant pressure for a certain gas is given by \(C_{p}=a+b T+c T^{2}\), where \(a=33.6 \mathrm{~J} / \mathrm{mol} \cdot \mathrm{K}\), \(b=2.93 \times 10^{-3} \mathrm{~J} / \mathrm{mol} \cdot \mathrm{K}^{2}\), and \(c=2.13 \times 10^{-5} \mathrm{~J} / \mathrm{mol} \cdot \mathrm{K}^{3}\). Find the entropy change when \(2.00\) moles of this gas are heated from \(20.0^{\circ} \mathrm{C}\) to \(200^{\circ} \mathrm{C}\).
Problem 76 of Chapter 16 provided an approximate expression for the specific heat of copper at low absolute temperatures: \(c=31(T / 343 \mathrm{~K})^{3} \mathrm{~J} / \mathrm{kg} \cdot \mathrm{K}\). Use this to find the entropy change when \(40 \mathrm{~g}\) of copper are cooled from \(25 \mathrm{~K}\) to \(10 \mathrm{~K}\). Why is the change negative?
A power plant extracts energy from steam at \(280^{\circ} \mathrm{C}\) and delivers \(880 \mathrm{MW}\) of electric power. It discharges waste heat to a river at \(30^{\circ} \mathrm{C}\). The plant's overall efficiency is \(29 \%\). (a) How does this efficiency compare with the maximum possible at these temperatures? (b) Find the rate of waste-heat discharge to the river. (c) How many houses, each requiring \(23 \mathrm{~kW}\) of heating power, could be heated with the waste heat from this plant?
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