Chapter 19: Problem 12
Why doesn't the evolution of human civilization violate the second law of thermodynamics?
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Chapter 19: Problem 12
Why doesn't the evolution of human civilization violate the second law of thermodynamics?
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A refrigerator maintains an interior temperature of \(4^{\circ} \mathrm{C}\) while its exhaust temperature is \(30^{\circ} \mathrm{C}\). The refrigerator's insulation is imperfect, and heat leaks in at the rate of 340 W. Assuming the refrigerator is reversible, at what rate must it consume electrical energy to maintain a constant \(4^{\circ} \mathrm{C}\) interior?
Could you heat the kitchen by leaving the oven open? Explain.
The molar specific heat at constant pressure for a certain gas is given by \(C_{p}=a+b T+c T^{2},\) where \(a=33.6 \mathrm{J} / \mathrm{mol} \cdot \mathrm{K}\) \(\mathrm{b}=2.93 \times 10^{-3} \mathrm{J} / \mathrm{mol} \cdot \mathrm{K}^{2},\) and \(c=2.13 \times 10^{-5} \mathrm{J} / \mathrm{mol} \cdot \mathrm{K}^{3} .\) Find the entropy change when 2.00 moles of this gas are heated from \(20.0^{\circ} \mathrm{C}\) to \(200^{\circ} \mathrm{C}\)
How much energy becomes unavailable for work in an isothermal process at \(440 \mathrm{K},\) if the entropy increase is \(25 \mathrm{J} / \mathrm{K} ?\)
A 6.36 -mol sample of ideal diatomic gas is at 1.00 atm pressure and \(288 \mathrm{K}\). Find the entropy change as the gas is heated reversibly to \(552 \mathrm{K}\) (a) at constant volume, (b) at constant pressure, and (c) adiabatically.
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