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An ideal gas at pressure \(2.5 \times 10^{5} \mathrm{~Pa}\) and temperature \(300 \mathrm{~K}\) occupies \(100 \mathrm{cc}\). It is adiabatically compressed to half its original volume. Calculate (a) the final pressure, (b) the final temperature and (c) the work done by the gas in the process. Take \(\gamma=1 \cdot 5\).

Short Answer

Expert verified
(a) Final pressure: \(7.07 \times 10^5\) Pa. (b) Final temperature: 424.2 K. (c) Work done: -20.7 J.

Step by step solution

01

Convert Volume to Cubic Meters

First, convert the initial volume from cubic centimeters to cubic meters. We know that 1 cubic meter (m³) is equivalent to 1,000,000 cubic centimeters (cc). Therefore, the initial volume \( V_1 \) is:\[ V_1 = 100 \, \text{cc} = 100 \times 10^{-6} \text{m}^3 = 10^{-4} \text{m}^3 \]
02

Calculate Final Volume

The gas is compressed adiabatically to half its original volume. Therefore, the final volume \( V_2 \) is:\[ V_2 = \frac{V_1}{2} = \frac{10^{-4}}{2} \text{ m}^3 = 5 \times 10^{-5} \text{ m}^3 \]
03

Use Adiabatic Condition to Find Final Pressure

For adiabatic compression, the relation between initial and final states is given by:\[ P_1 V_1^\gamma = P_2 V_2^\gamma \]Rearrange this to find \( P_2 \):\[ \frac{P_2}{P_1} = \left( \frac{V_1}{V_2} \right)^{\gamma} \]Substitute values:\[ \frac{P_2}{2.5 \times 10^5} = \left( \frac{10^{-4}}{5 \times 10^{-5}} \right)^{1.5} = 2^{1.5} = 2.828 \]Thus, the final pressure \( P_2 \) is:\[ P_2 = 2.828 \times 2.5 \times 10^5 = 7.07 \times 10^5 \, \text{Pa} \]
04

Find Final Temperature Using Adiabatic Relation

The adiabatic relation for temperature is:\[ \frac{T_2}{T_1} = \left( \frac{V_1}{V_2} \right)^{\gamma - 1} \]Substitute given values:\[ \frac{T_2}{300} = 2^{0.5} = \sqrt{2} = 1.414 \]So, the final temperature \( T_2 \) is:\[ T_2 = 1.414 \times 300 = 424.2 \text{K} \]
05

Calculate Work Done in Adiabatic Process

For an adiabatic process, work done \( W \) is given by:\[ W = \frac{P_1 V_1 - P_2 V_2}{\gamma - 1} \]Substitute known values:\[ W = \frac{(2.5 \times 10^5 \times 10^{-4}) - (7.07 \times 10^5 \times 5 \times 10^{-5})}{1.5 - 1} \]Calculate individually:- \( 2.5 \times 10^5 \times 10^{-4} = 25.0 \) Joules- \( 7.07 \times 10^5 \times 5 \times 10^{-5} = 35.35 \) JoulesNow compute work:\[ W = \frac{25.0 - 35.35}{0.5} = \frac{-10.35}{0.5} = -20.7 \, \text{Joules} \]The work done by the gas is negative, indicating work done on the gas.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
The ideal gas law is a fundamental equation that describes the behavior of an ideal gas. It relates the pressure, volume, and temperature of the gas. The ideal gas law is expressed as \( PV = nRT \), where:
  • \( P \) is the pressure of the gas in Pascals (Pa).
  • \( V \) is the volume in cubic meters (m³).
  • \( n \) is the number of moles of gas.
  • \( R \) is the universal gas constant \( 8.314 \) J/mol·K.
  • \( T \) is the temperature in Kelvin (K).
In this exercise, we're dealing with an adiabatic compression, which means the ideal gas law is not applied directly to relate final and initial states, but it's important to understand that gas behavior in any state would conform to this law.
Adiabatic Process
An adiabatic process is one where no heat is exchanged between the system and its surroundings. This means the entire energy transfer within the system is work. In the context of gases, an adiabatic process signifies a change in state without gain or loss of thermal energy.
During adiabatic compression, the product of pressure times volume raised to the power of \( \gamma \) is constant, i.e., \( P_1 V_1^\gamma = P_2 V_2^\gamma \). Here, \( \gamma \) (the heat capacity ratio), is the crucial factor influencing how pressure and volume interact.
This principle is the backbone of the solution in calculating final pressure and understanding the nature of work done and temperature change.
Work Done
Work done in an adiabatic process is an important concept in thermodynamics. Work done \( W \) by the gas, or on it, can be calculated using the equation:
\[ W = \frac{P_1 V_1 - P_2 V_2}{\gamma - 1} \]Here, it's crucial to note that because there is no heat exchange, internal energy must also change.
If the work done is negative, it tells us that work is done on the gas rather than by the gas. This simply implies that during the compression, the energy goes into changing the volume rather than escaping as heat.
Temperature Change
In an adiabatic process, the temperature of the gas changes due to the work done. This change is given by the relation:
\[ \frac{T_2}{T_1} = \left( \frac{V_1}{V_2} \right)^{\gamma - 1} \]This shows that the temperature is linked to the change in volume raised to the power of \( \gamma - 1 \).
  • If the gas is compressed (volume decreases), temperature increases.
  • If the gas expands, temperature decreases.
In this exercise, since the gas is compressed, the final temperature is higher than the initial temperature, which is expected.
Pressure Change
Pressure change in an adiabatic process can be calculated using:
\[ P_2 = P_1 \left( \frac{V_1}{V_2} \right)^\gamma \]This formula highlights that pressure change is directly related to how the volume changes, influenced by the value of \( \gamma \).
The increase in pressure with reduced volume during adiabatic compression results from the gas molecules being forced together, which naturally elevates pressure.
Understanding this concept is vital for solving various problems in gas physics, as it ties together the ideas of pressure, temperature, and volume in a closed system.

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Most popular questions from this chapter

Consider a given sample of an ideal gas \(\left(C_{p} / C_{V}=\gamma\right)\) having initial pressure \(p_{0}\) and volume \(V_{c}\). (a) The gas is isothermally taken to a pressure \(p_{0} / 2\) and from there adiabatically to a pressure \(p_{0} / 4\). Find the final volume. (b) The gas is brought back to its initial state. It is adiabatically taken to a pressure \(p_{0} / 2\) and from there isothermally to a pressure \(p_{0} / 4\). Find the final volume.

Air \((\gamma=1.4)\) is pumped at 2 atm pressure in a motor tyre at \(20^{\circ} \mathrm{C}\). If the tyre suddenly bursts, what would be the temperature of the air coming out of the tyre. Neglect any mixing with the atmospheric air.

The volume of an ideal gas \((\gamma=1 \cdot 5)\) is changed adiabatically from \(4.00\) litres to \(3.00\) litres. Find the ratio of (a) the final pressure to the initial pressure and (b) the final temperature to the initial temperature.

Two vessels \(A\) and \(B\) of equal volume \(V_{0}\) are connected by a narrow tube which can be closed by a valve. The vessels are fitted with pistons which can be moved to change the volumes. Initially, the valve is open and the vessels contain an ideal gas \(\left(C_{p} / C_{V}=\gamma\right)\) at atmospheric pressure \(p_{0}\) and atmospheric temperature \(T_{0}\). The walls of the vessel \(A\) are diathermic and those of \(B\) are adiabatic. The valve is now closed and the pistons are slowly pulled out to increase the volumes of the vessels to double the original value. (a) Find the temperatures and pressures in the two vessels. (b) The valve is now opened for sufficient time so that the gases acquire a common temperature and pressure. Find the new values of the temperature and the pressure.

In Joly's differential steam calorimeter, \(3 \mathrm{~g}\) of an ideal gas is contained in a rigid closed sphere at \(20^{\circ} \mathrm{C}\). The sphere is heated by steam at \(100^{\circ} \mathrm{C}\) and it is found that an extra \(0.095 \mathrm{~g}\) of steam has condensed into water as the temperature of the gas becomes constant. Calculate the specific heat capacity of the gas in \(\mathrm{J} \mathrm{g}^{-1} \mathrm{~K}^{-1}\). The latent heat of vaporization of water \(=540 \mathrm{cal} \mathrm{g}^{-1}\).

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