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\(\bullet\) An ideal gas expands while the pressure is kept constant. During this process, does heat flow into the gas or out of the gas? Justify your answer.

Short Answer

Expert verified
Heat flows into the gas because work is done during expansion and internal energy needs to be constant or increase.

Step by step solution

01

Understanding the Ideal Gas Process

Since the gas is expanding at constant pressure, it is undergoing an isobaric process. In this type of process, work is done by the gas as it pushes against external pressure while expanding.
02

Application of the First Law of Thermodynamics

The first law of thermodynamics is given by the equation \( \Delta U = Q - W \), where \( \Delta U \) is the change in internal energy, \( Q \) is the heat added to the system, and \( W \) is the work done by the system. Since the gas expands, work \( W \) is done by the system and is positive.
03

Considering Internal Energy Change

For an ideal gas, any attempt to change internal energy \( \Delta U \) depends on changes in temperature. Since the gas expands and does work, and there is no mention of temperature decrease, some heat energy \( Q \) must have been added to maintain energy balance.
04

Conclusion on Heat Flow

To satisfy the energy balance equation and since \( W \) is positive due to expansion, \( Q \) must also be positive for the internal energy \( \Delta U \) not to decrease. Therefore, heat flows into the gas.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Isobaric Process
An isobaric process is one where the pressure of a gas remains constant. In an isobaric expansion, like the one described in the exercise, a gas increases its volume while maintaining a steady pressure.
During such processes, the gas does work on its surroundings. This happens because, as it expands, it pushes against the external pressure. The nature of an isobaric process is quite common; for example, imagine a piston-cylinder system where the piston can move freely without changing the pressure inside.
Key Points about Isobaric Processes:
  • Pressure remains constant throughout the process.
  • Volume changes, usually increasing in the case of expansion.
  • Work is done by the gas during expansion, which means energy is transferred from the gas to its surroundings.
First Law of Thermodynamics
The first law of thermodynamics is a fundamental principle in physics that relates to the conservation of energy. It is often expressed in the equation: \[ \Delta U = Q - W \]
Here, \( \Delta U \) is the change in internal energy of the system, \( Q \) is the heat added to the system, and \( W \) is the work done by the system.
This law states that the energy of a closed system is conserved. For an expanding gas in an isobaric process, the work \( W \) is positive, as the system does work on the surroundings. Therefore, if the internal energy \( \Delta U \) is to remain constant or increase, the heat \( Q \) added must compensate for the work done. This principle helps us understand energy flow and balance in thermodynamic processes.
Internal Energy Change
Internal energy is a measure of the total energy contained within a system, including kinetic and potential energies of the particles. For an ideal gas, the internal energy is strictly a function of temperature.
When an ideal gas expands isobarically, it performs work on its surroundings. To maintain a constant internal energy \( \Delta U \), or for it to increase, additional heat energy \( Q \) must be added to the system. This is because the work done by the gas uses some of the internal energy.
  • If the internal energy remains constant, it means that the amount of heat added \( Q \) equals the work done \( W \).
  • If the internal energy increases, the heat added \( Q \) is greater than the work done \( W \).
Thus, understanding internal energy change is crucial in predicting the behavior of an ideal gas during isobaric processes.
Heat Flow in Gases
Heat flow refers to the movement of thermal energy from one body or system to another, and it plays a crucial role in thermodynamic processes. In the context of an isobaric process, heat flow in a gas can determine changes in other state variables such as volume and internal energy.
During an isobaric expansion, heat must flow into the gas to enable it to do work and possibly increase its internal energy. The positive value of \( Q \) in such scenarios indicates that heat addition is necessary to balance the equation from the first law of thermodynamics.
Important Aspects of Heat Flow in Gases:
  • Incoming heat is needed to counterbalance work performed during expansion.
  • Heat flow can lead to an increase in internal energy if enough heat is provided.
  • The efficiency of heat flow is essential in processes like engine cycles, where energy conservation and transfer efficiency are critical.
Understanding heat flow is vital in ensuring energy is adequately managed within a system during thermodynamic processes.

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Most popular questions from this chapter

\(\bullet$$\bullet$$\bullet\) A hot-air balloon stays aloft because hot air at atmospheric pressure is less dense than cooler air at the same pressure. (The calculation of the buoyant force is discussed in Chapter \(13 .\) ) If the volume of the balloon is 500.0 \(\mathrm{m}^{3}\) and the surrounding air is at \(15.0^{\circ} \mathrm{C},\) what must the temperature of the air in the balloon be for it to lift a total load of 290 \(\mathrm{kg}\) (in addition to the mass of the hot air)? The density of air at \(15.0^{\circ} \mathrm{C}\) and atmospheric pressure is 1.23 \(\mathrm{kg} / \mathrm{m}^{3}.\) BIO Temperature and degrees of freedom. The internal energy of an ideal monatomic gas is simply the kinetic energy associated with the translational motion of its atoms as they move randomly in each of the three independent spatial dimensions. However, for a diatomic ideal gas we must also take into account the kinetic and potential energies associated with molecular vibration, and the kinetic energy associated with molecular rotation. Roughly speaking, each independent way that energy can be stored is known as a degree of freedom. Although translational motion can occur at any temperature, rotational and vibrational motions typically cannot occur at lower temperatures- thus, the number of available degrees of freedom can change as the temperature changes. For example, an ideal monatomic gas has three degrees of freedom (one for each of its independent directions of translational motion) at all temperatures. In contrast, diatomic hydrogen \(\left(\mathrm{H}_{2}\right)\) has five degrees of freedom near room temperature \((3\) translational and 2 rotational). However, at higher temperatures, where molecular vibrations can occur, diatomic hydrogen has seven degrees of freedom \((3\) translational, 2 rotational, and 2 vibrational). The equipartition theorem states that equilibrium each degree of freedom contributes \(\frac{1}{2} n R T\) to the internal energy of the gas. For example, the internal energy of a monatomic gas, which has 3 degrees of freedom, would be \(\frac{3}{2} n R T\).

\(\bullet\) Lung volume. The total lung volume for a typical person is 6.00 L. A person fills her lungs with air at an absolute pressure of 1.00 atm. Then, holding her breath, she compresses her chest cavity, decreasing her lung volume to 5.70 L. What is the pressure of the air in her compressed lungs, assuming that the temperature of the air remains constant?

\(\bullet\) A gas under a constant pressure of \(1.50 \times 10^{5} \mathrm{Pa}\) and with an initial volume of 0.0900 \(\mathrm{m}^{3}\) is cooled until its volume becomes 0.0600 \(\mathrm{m}^{3} .\) (a) Draw a \(p V\) diagram of this process. (b) Calculate the work done by the gas.

\(\bullet$$\bullet\) (a) Calculate the mass of nitrogen present in a volume of 3000 \(\mathrm{cm}^{3}\) if the temperature of the gas is \(22.0^{\circ} \mathrm{C}\) and the absolute pressure is \(2.00 \times 10^{-13}\) atm, a partial vacuum easily obtained in laboratories. The molar mass of nitrogen \(\left(\mathrm{N}_{2}\right)\) is 28.0 \(\mathrm{g} / \mathrm{mol} .\) (b) What is the density (in \(\mathrm{kg} / \mathrm{m}^{3} )\) of the \(\mathrm{N}_{2} ?\)

\(\bullet$$\bullet\) The atmosphere of the planet Mars is 95.3\(\%\) carbon dioxide \(\left(\mathrm{CO}_{2}\right)\) and about 0.03\(\%\) water vapor. The atmospheric pressure is only about 600 \(\mathrm{Pa}\) , and the surface temperature varies from \(-30^{\circ} \mathrm{C}\) to \(-100^{\circ} \mathrm{C}\) . The polar ice caps contain both \(\mathrm{CO}_{2}\) ice and water ice. Could there be liquid \(\mathrm{CO}_{2}\) on the surface of Mars? Could there be liquid water? Why or why not?

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