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\(\bullet\) Helium gas with a volume of 2.60 \(\mathrm{L}\) under a pressure of 1.30 atm and at a temperature of \(41.0^{\circ} \mathrm{C}\) is warmed until both the pressure and volume of the gare are doubled. (a) What is the final temperature? (b) How many grams of helium are there? The molar mass of helium is 4.00 \(\mathrm{g} / \mathrm{mol}.\)

Short Answer

Expert verified
(a) Final temperature is 628.30 K. (b) Mass of helium is 0.516 g.

Step by step solution

01

Convert Initial Temperature to Kelvin

The initial temperature is given as \(41.0^{\circ}C\). To convert this to Kelvin, use the formula: \(T(K) = T(^{\circ}C) + 273.15\). So, \(T_{1} = 41.0 + 273.15 = 314.15\, K\).
02

Use Ideal Gas Law to Find Initial Moles

The ideal gas law is \(PV = nRT\), where \(P\) is pressure, \(V\) is volume, \(n\) is number of moles, \(R\) is the gas constant \(0.0821\, \text{L atm/mol K}\), and \(T\) is temperature in Kelvin. Substitute the known values: \(1.30 \times 2.60 = n \times 0.0821 \times 314.15\). Solving for \(n\), \(n = \frac{1.30 \times 2.60}{0.0821 \times 314.15} \approx 0.129\, \text{moles}\).
03

Determine Final Pressure, Volume, and Temperature

The problem states both pressure and volume are doubled, so \(P_{2} = 2.60\, \text{atm}\) and \(V_{2} = 5.20\, \text{L}\). Use the combined gas law \(\frac{P_{1}V_{1}}{T_{1}} = \frac{P_{2}V_{2}}{T_{2}}\) to find \(T_{2}\): \(\frac{1.30 \times 2.60}{314.15} = \frac{2.60 \times 5.20}{T_{2}}\). Solve for \(T_{2}\) to get \(T_{2} = \frac{2.60 \times 5.20 \times 314.15}{1.30 \times 2.60} \approx 628.30\, K\).
04

Find Mass of Helium

Use the number of moles from Step 2 and the molar mass of helium \(4.00\, \text{g/mol}\). The mass \(m = n \times \text{molar mass} = 0.129 \times 4.00 = 0.516\, \text{g}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Gas Laws
Gas laws help us understand the physical behaviors of gases. They relate the pressure, volume, and temperature of a gas. The Ideal Gas Law is a key concept, expressed as \( PV = nRT \), where \( P \) is pressure, \( V \) is volume, \( n \) is the number of moles, \( R \) is the gas constant, and \( T \) is temperature.
This law assumes an ideal behavior where gases follow certain characteristics. Such assumptions include negligible volume of gas molecules and no intermolecular forces. The Ideal Gas Law combines properties from Boyle's Law (pressure and volume), Charles's Law (volume and temperature), and Avogadro’s Law (volume and amount of gas).
Remember, it's an approximation for real gases. However, it works well under normal conditions for many gases, helping predict behavior when a gas's state changes.
Temperature Conversion
To work with gas laws, temperature needs to be in Kelvin. This is because the Kelvin scale starts at absolute zero, where theoretically particles have minimum thermal motion.
Converting Celsius to Kelvin is simple: add 273.15. For instance, if we have \(41.0^{\circ}C\), it becomes \(41.0 + 273.15 = 314.15 \, K\).
Why Kelvin? Because in gas laws, temperature needs a true scale. Negative temperatures in Celsius can cause errors. Kelvin's absolute scale ensures temperature results make physical sense.
Molar Mass
Molar mass connects the concept of moles to mass. It's the weight of one mole of a substance, measured in grams per mole (g/mol). For helium, this is 4.00 g/mol.
How do you find mass using molar mass? Once you know the number of moles, multiply by molar mass. For helium's number of moles at 0.129, the mass is \( 0.129 \times 4.00 = 0.516 \, g \).
This step is essential for linking microscopic molecular behavior to macroscopic weight, essential in many chemistry calculations.
Pressure and Volume Changes
When pressure and volume of a gas change, understanding how they affect temperature is crucial. In the given problem, both pressure and volume double.
Use the combined gas law \( \frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2} \) to find the final temperature. Substitute initial and final values to solve \( T_2 \): \( \frac{1.30 \times 2.60}{314.15} = \frac{2.60 \times 5.20}{T_2} \). Solving gives \( T_2 = 628.30 \, K \).
This illustrates the interdependence of gas properties. Doubling pressure and volume requires understanding their influence on temperature for accurate predictions.

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Most popular questions from this chapter

\(\bullet$$\bullet\) The effect of altitude on the lungs. (a) Calculate the change in air pressure you will experience if you climb a 1000 \(\mathrm{m}\) moun- tain, assuming that the temperature and air density do not change over this distance and that they were \(22^{\circ} \mathrm{Cand} 1.2 \mathrm{kg} / \mathrm{m}^{3},\) respectively, at the bottom of the mountain. (b) If you took a 0.50 \(\mathrm{L}\) breath at the foot of the mountain and managed to hold it until you reached the top, what would be the volume of this breath when you exhaled it there?

\(\bullet$$\bullet\) A flask with a volume of 1.50 \(\mathrm{L}\) , provided with a stopcock, contains ethane gas \(\left(\mathrm{C}_{2} \mathrm{H}_{6}\right)\) at 300 \(\mathrm{K}\) and atmospheric pressure \(\left(1.013 \times 10^{5} \mathrm{Pa}\right) .\) The molar mass of ethane is 30.1 \(\mathrm{g} / \mathrm{mol}\) . The system is warmed to a temperature of \(380 \mathrm{K},\) with the stopcock open to the atmosphere. The stopcock is then closed, and the flask is cooled to its original temperature. (a) What is the final pressure of the ethane in the flask? (b) How many grams of ethane remain in the flask?

\(\bullet$$\bullet\) (a) Calculate the mass of nitrogen present in a volume of 3000 \(\mathrm{cm}^{3}\) if the temperature of the gas is \(22.0^{\circ} \mathrm{C}\) and the absolute pressure is \(2.00 \times 10^{-13}\) atm, a partial vacuum easily obtained in laboratories. The molar mass of nitrogen \(\left(\mathrm{N}_{2}\right)\) is 28.0 \(\mathrm{g} / \mathrm{mol} .\) (b) What is the density (in \(\mathrm{kg} / \mathrm{m}^{3} )\) of the \(\mathrm{N}_{2} ?\)

\(\bullet$$\bullet\) The surface of the sun. The surface of the sun has a temperature of about 5800 \(\mathrm{K}\) and consists largely of hydrogen atoms. (a) Find the rms speed of a hydrogen atom at this temperature. (The mass of a single hydrogen atom is \(1.67 \times\) \(10^{-27} \mathrm{kg} .\) (b) What would be the mass of an atom that had half the rms speed of hydrogen?

\(\bullet\) A cylinder contains 0.250 mol of carbon dioxide \(\left(\mathrm{CO}_{2}\right)\) gas at a temperature of \(27.0^{\circ} \mathrm{C}\) . The cylinder is provided with a frictionless piston, which maintains a constant pressure of 1.00 atm on the gas. The gas is heated until its temperature increases to \(127.0^{\circ} \mathrm{C}\) . Assume that the \(\mathrm{CO}_{2}\) may be treated as an ideal gas. (a) Draw a \(p V\) diagram of this process. (b) How much work is done by the gas in the process? (c) On what is this work done? (d) What is the change in internal energy of the gas? (e) How much heat was supplied to the gas? (f) How much work would have been done if the pressure had been 0.50 atm?

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