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Red light having a wavelength of \(700 \mathrm{nm}\) is projected onto magnesium metal to which electrons are bound by 3.68 eV. (a) Use \(\mathrm{KE}_{e}=h f-\mathrm{BE}\) to calculate the kinetic energy of the ejected electrons. (b) What is unreasonable about this result? (c) Which assumptions are unreasonable or inconsistent?

Short Answer

Expert verified
The kinetic energy of the ejected electrons is negative, implying that the red light does not have sufficient energy to eject electrons from magnesium metal. The assumption that red light would lead to electron emission is the unreasonable aspect in this scenario.

Step by step solution

01

Convert Wavelength to Frequency

First, use the formula for the speed of light, \( c = \lambda f \), to convert the wavelength of red light (700 nm) to frequency (f). Since the speed of light (c) is approximately \(3.00 \times 10^{8} \text{m/s}\), and \(1 \text{nm} = 10^{-9} \text{m}\), we have: \[ f = \frac{c}{\lambda} = \frac{3.00 \times 10^{8} \text{m/s}}{700 \times 10^{-9} \text{m}} = \frac{3.00 \times 10^{8}}{700 \times 10^{-9}} \] Calculate the frequency using this formula.
02

Calculate the Energy of Photons

Use the calculated frequency to find the energy of the photons using Planck's equation, \(E = hf\), where \(h\) is Planck's constant (\(h = 6.626 \times 10^{-34} \text{J}\cdot\text{s}\)). Substitute the frequency value from Step 1 into the equation.
03

Calculate the Kinetic Energy of Ejected Electrons

Use the equation for kinetic energy of the ejected electrons, \( KE_e = hf - BE \), where \(BE\) is the binding energy (3.68 eV). Convert the binding energy from electronvolts to joules (1 eV = \(1.602 \times 10^{-19}\) J) and then substitute the photon energy and binding energy into the equation to find the kinetic energy.
04

Analyze the Result

Examine the result. If the calculated kinetic energy is negative, this means that the photons do not have enough energy to eject electrons from the metal, which implies an error or an unrealistic scenario.
05

Evaluate the Assumptions

Determine which assumptions might be unreasonable or inconsistent. In this case, it could be related to the energy of the light used or the work function of the material.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Wavelength to Frequency Conversion
To understand the photoelectric effect, we must first know how to convert the wavelength of light into frequency as this gives us insight into the energy of photons. The speed of light, denoted as \( c \), is a fundamental constant approximately equal to \(3.00 \times 10^{8} \text{m/s}\). The relationship between the speed of light, the frequency \( f \), and the wavelength \( \lambda \) is given by the equation \( c = \lambda f \).

Therefore, to convert wavelength to frequency, we rearrange this formula to \( f = \frac{c}{\lambda} \). For instance, if the wavelength of light is 700 nanometers (nm), we first convert this to meters as follows: \(700 \text{nm} = 700 \times 10^{-9} \text{m}\), and then we can calculate the frequency. Such calculations are essential when delving into phenomena like the photoelectric effect, which hinges on the frequency of the incident light.
Planck's Equation
Planck's equation is fundamental in quantum mechanics and is used to describe the energy of a photon. The equation is given by \( E = hf \), where \( E \) is the energy of a photon, \( h \) is Planck's constant, and \( f \) is the frequency of the photon. Planck's constant, \( h \), has a value of \(6.626 \times 10^{-34} \text{J} \cdot \text{s}\).

By using the frequency obtained from the wavelength to frequency conversion, we can substitute it into Planck's equation to find the energy of individual photons. This energy is crucial in determining whether a photon has sufficient energy to effect the release of an electron from a material, which is the central aspect of the photoelectric effect.
Kinetic Energy of Ejected Electrons
In the photoelectric effect, not all the energy from a photon is used to eject an electron. The kinetic energy \( KE_e \) of an ejected electron is the difference between the photon energy and the electron's binding energy (or work function) to the metal. The equation \( KE_e = hf - BE \) encapsulates this, where \( BE \) is the binding energy in electronvolts (eV).

This equation tells us that if a photon's energy (as given by Planck's equation) exceeds the binding energy of an electron in a material, the surplus energy manifests as the kinetic energy of the ejected electron. If the photon's energy is equal to the binding energy, the electron will be ejected but with zero kinetic energy, meaning it will not move. If the photon's energy is less than the binding energy, no electrons will be ejected, which hints at a critical point of analysis in assessing whether a scenario in the photoelectric effect is realistic or not.
eV to Joules Conversion
Understanding how to convert electronvolts (eV) to joules (J) is vital in solving physics problems involving the photoelectric effect. An electronvolt is the amount of kinetic energy gained or lost by an electron as it moves through an electric potential difference of one volt. It's a convenient unit of energy used in atomic and particle physics. The conversion factor between eV and joules is \(1 \text{eV} = 1.602 \times 10^{-19} \text{J}\).

When we deal with binding energy or work function in electronvolts, as is common in photoelectric effect scenarios, we must convert this value into joules to use it with Planck's equation, which is in joules. This conversion ensures that all units are consistent, allowing for proper calculation of the kinetic energy of ejected electrons using the energy obtained from Planck's equation.

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Most popular questions from this chapter

Sunlight above the Earth's atmosphere has an intensity of \(1.30 \mathrm{kW} / \mathrm{m}^{2} .\) If this is reflected straight back from a mirror that has only a small recoil, the light's momentum is exactly reversed, giving the mirror twice the incident momentum. (a) Calculate the force per square meter of mirror. (b) Very low mass mirrors can be constructed in the near weightlessness of space, and attached to a spaceship to sail it. Once done, the average mass per square meter of the spaceship is 0.100 kg. Find the acceleration of the spaceship if all other forces are balanced. (c) How fast is it moving 24 hours later?

(a) Calculate the velocity of an electron that has a wavelength of \(1.00 \mu \mathrm{m}\). (b) Through what voltage must the electron be accelerated to have this velocity?

(a) The lifetime of a highly unstable nucleus is \(10^{-20} \mathrm{s}\) What is the smallest uncertainty in its decay energy? (b) Compare this with the rest energy of an electron.

The momentum of light is exactly reversed when reflected straight back from a mirror, assuming negligible recoil of the mirror. Thus the change in momentum is twice the photon momentum. Suppose light of intensity \(1.00 \mathrm{kW} / \mathrm{m}^{2}\) reflects from a mirror of area \(2.00 \mathrm{m}^{2}\). (a) Calculate the energy reflected in 1.00 s. (b) What is the momentum imparted to the mirror? (c) Using the most general form of Newton's second law, what is the force on the mirror? (d) Does the assumption of no mirror recoil seem reasonable?

(a) If the position of a chlorine ion in a membrane is measured to an accuracy of \(1.00 \mu \mathrm{m}\), what is its minimum uncertainty in velocity, given its mass is \(5.86 \times 10^{-26} \mathrm{kg}\) ?

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