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Plot a graph of the mass fraction of water vapor in saturated water vapor-air mixtures at 1 atm pressure for \(273.15 \mathrm{~K}

Short Answer

Expert verified
Calculate the mass fraction using saturation pressures from a steam table and plot it across the temperature range 273.15 K to 373.15 K.

Step by step solution

01

Understand the Problem

We need to plot a graph showing the mass fraction of water vapor in saturated water vapor-air mixtures for a temperature range from 273.15 K to 373.15 K at a constant pressure of 1 atm. The mass fraction is the ratio of the mass of water vapor to the total mass of the mixture.
02

Relation of Vapor Pressure and Temperature

We should first understand that the vapor pressure of water increases with temperature. The vapor pressure of water at a given temperature can be found using the Antoine equation, or a steam table can be used for more precise values in this range of temperatures.
03

Find Saturation Pressure of Water Vapor

At each temperature within the range, find the saturation pressure of water vapor using data from a steam table or through an empirical equation such as the Antoine equation: \[\log_{10}(P_{\text{sat}}) = A - \frac{B}{C + T}\]Where \(P_{\text{sat}}\) is the saturation pressure, \(T\) is the temperature in °C, and A, B, and C are empirical constants.
04

Calculate the Mass Fraction

Using the saturation pressure obtained for each temperature, calculate the mass fraction of water vapor in the mixture. The mass fraction is given by the formula:\[y_{\text{water vapor}} = \frac{P_{\text{sat}}}{P_{\text{total}}}\times \frac{M_{\text{water vapor}}}{M_{\text{air}}}\]where \(P_{\text{total}}\) is the atmospheric pressure (1 atm), \(M_{\text{water vapor}} = 18.01528 \text{ g/mol}\) and \(M_{\text{air}} = 28.97 \text{ g/mol}\).
05

Plot the Graph

Create a plot with temperature on the x-axis and the mass fraction of water vapor on the y-axis. Use the calculated values across the given temperature range to plot the mass fraction versus temperature.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Saturated Water Vapor
When we talk about saturated water vapor, we are referring to the phase of water in which the air holds the maximum amount of water vapor it can contain at a specific temperature and pressure. This state is important in many fields, including meteorology and chemical engineering, because it represents the point of maximum humidity.
Saturation occurs after water vapor has been added to the air up to its capacity. Thus, in a saturated vapor condition, any further addition of water vapor or a decrease in temperature will result in condensation. This knowledge is crucial for understanding processes like rain formation and various industrial drying processes.

  • Saturated water vapor ensures no more water can evaporate without forming condensation.
  • Temperature and pressure are critical in determining the saturation point.
Vapor Pressure
Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid or solid form in a closed container. It is a measure of the tendency of molecules to escape from the liquid phase into the gas phase. In simpler terms, it's how "puff-out" ready the water molecules are at a given temperature. The higher the temperature, the higher the vapor pressure because more molecules have the energy to escape the liquid.
Vapor pressure is significant in calculating boiling points, understanding humidity, and for various engineering applications involving phase changes. At a given temperature, water has a specific vapor pressure that plays a part in climate systems and many chemical processes.

  • Vapor pressure increases with temperature.
  • Determines the point at which a liquid transitions to gas (boiling).
Mass Fraction
Mass fraction is a way to express the concentration of a particular component within a mixture. In the context of water vapor in air, it refers to the ratio of the mass of water vapor to the total mass of the water vapor-air mixture. This is particularly useful in understanding humid air in various scenarios, such as weather forecasting and air conditioning systems.
To calculate the mass fraction, one uses the formula
\[ y_{ ext{water vapor}} = \frac{P_{ ext{sat}}}{P_{ ext{total}}} \times \frac{M_{ ext{water vapor}}}{M_{ ext{air}}} \]
This formula shows how the mass fraction depends on the saturation pressure of the water vapor and the molecular weights of water vapor and air.

  • Mass fraction helps quantify component concentration within mixtures.
  • Useful in engineering for calculating energy balances.
Antoine Equation
The Antoine equation is an empirical equation that provides a reliable method to calculate the vapor pressure of a pure liquid at a specific temperature. Using this equation, one can find the saturation pressure needed for different temperatures, especially in temperatures that do not have corresponding tabulated data points.
The equation itself is expressed as follows:
\[\log_{10}(P_{\text{sat}}) = A - \frac{B}{C + T} \]
Where:
  • \(P_{\text{sat}}\) is the saturation vapor pressure.
  • \(T\) is the temperature in Celsius.
  • \(A, B,\) and \(C\) are empirical constants specific to each substance.
The Antoine equation is widely used due to its simplicity and accuracy for many substances within a limited temperature range, making it valuable in both academic studies and practical engineering tasks.

  • Provides a straightforward way to estimate vapor pressure.
  • Helps in determining saturation conditions across various temperatures.

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Most popular questions from this chapter

A closed cylindrical vessel containing stagnant air stands with its axis vertical. Each end is maintained at a uniform temperature with the base colder than the upper end; the cylindrical wall is insulated. Neglecting the variation in hydrostatic pressure, ascertain whether there are vertical gradients of (i) partial density of oxygen. (ii) partial pressure of oxygen. (iii) mass fraction of oxygen.

A common procedure for surface micromachining involves chemical etching of sacrificial layers. In one procedure, phosphosilicate glass is etched by hydrofluoric acid, with an overall reaction of $$ 6 \mathrm{HF}+\text { Si } \mathrm{O}_{2} \rightarrow \mathrm{H}_{2} \mathrm{Si} \mathrm{F}_{6}+2 \mathrm{H}_{2} \mathrm{O} $$ When the etching depth is small, the reaction rate is rate-controlled; but for deep etching, as required to machine channels, diffusion of acid through the solution also plays a role. Assuming quasi-steady diffusion and a one- dimensional model, obtain an expression for the etching depth as a function of time. The reaction is approximately first-order in HF molar concentration with rate constant \(k\) ". Hence determine the time required to etch a channel \(100 \mu \mathrm{m}\) deep if \(k^{\prime \prime}=2 \times 10^{-6} \mathrm{~m} / \mathrm{s}\), \(\mathscr{D}_{1 m}=2 \times 10^{-9} \mathrm{~m}^{2} / \mathrm{s}\), and the bulk concentration of HF in an aqueous solution is \(7.0 \mathrm{kmol} / \mathrm{m}^{3}\).

$$ \begin{aligned} &\text { A porous catalyst is used to burn fumes from a }\\\ &\begin{aligned} &\text { paint spray booth to environmentally safe } \mathrm{CO}_{2} \\ &\text { and } \mathrm{H}_{2} \mathrm{O} \text {. The reaction is first-order in mass } \\ &\text { fraction of fumes, with activation energy } 18 \\ &\mathrm{kcal} / \mathrm{mol} \text { and preexponential factor } 10 \mathrm{~m} / \mathrm{s} \text {. The } \\ &\text { catalyst has specific surface area } a_{p}=5 \times 10^{5} \\ &\mathrm{~cm}^{2} / \mathrm{cm}^{3} \text { and average pore radius } 0.5 \mu \mathrm{m} \text {, and } \\ &\text { is in the form of a matrix with } 2 \mathrm{~mm}-\mathrm{thick} \\ &\text { walls and square cross-section passages with } \\ &\text { sides of } 3 \mathrm{~mm} \text {. The cross-sectional area of the } \\\ &\text { reactor is large enough to ensure laminar flow } \\ &\text { through the passages. The catalyst operates at } 500 \mathrm{~K} \text { and } 1 \text { atm. At a location } \\ &\text { where the bulk mass fraction of fumes is } 0.005, \text { estimate the rate at which the } \\ &\text { fumes are oxidized per unit volume of reactor. For the fumes, take a molecular } \\ &\text { weight of } 110 \text { and an ordinary diffusion coefficient of } 20 \times 10^{-6} \mathrm{~m}^{2} / \mathrm{s} \text {. For the } \\ &\text { porous catalyst, take } \varepsilon_{v}=0.7, \tau=4.0 \text {. } \end{aligned} \end{aligned} $$

A \(4 \mathrm{~cm}\)-diameter composite membrane, consisting of a \(0.2 \mathrm{~mm}\)-thick film of vulcanized rubber and a \(1 \mathrm{~mm}\)-thick layer of polyethylene, separates pure hydrogen at \(1.085 \times 10^{5} \mathrm{~Pa}\) and \(25^{\circ} \mathrm{C}\) from atmospheric air. Calculate the rate at which hydrogen leaks through the membrane. Permeabilities of \(\mathrm{H}_{2}\) in the rubber and polyethylene, respectively, are \(3.42 \times 10^{-11}\) and \(6.53 \times 10^{-12} \mathrm{~m}^{3}(\mathrm{STP}) / \mathrm{m}^{2} \mathrm{~s}\) \((\mathrm{atm} / \mathrm{m})\).

(i) A mixture of noble gases contains equal mole fractions of helium, argon, and xenon. What is the composition in terms of mass fractions? (ii) If the mixture contains equal mass fractions of \(\mathrm{He}, \mathrm{Ar}\), and \(\mathrm{Xe}\), what are the corresponding mole fractions?

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