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For a single large two-state paramagnet, the multiplicity function is very sharply peaked about N=N/2.

(a) Use Stirling's approximation to estimate the height of the peak in the multiplicity function.

(b) Use the methods of this section to derive a formula for the multiplicity function in the vicinity of the peak, in terms of xN(N/2). Check that your formula agrees with your answer to part (a) when x=0.

(c) How wide is the peak in the multiplicity function?

(d) Suppose you flip 1,000,000coins. Would you be surprised to obtain heads and 499,000 tails? Would you be surprised to obtain 510,000 heads and 490,000 tails? Explain.

Short Answer

Expert verified

a) The peak of the height within the multiplicity function max2N

b) The multiplicity function within the vicinity of the height, maxe2x2N

c) The height within the multiplicity function is w=2N

d) While a results of 501,000 individuals falls just ahead of the apex, this isn't very astonishing. A conclusion of 510,000 heads, from the opposite hand , is significantly outside the high and would are unusual.

Step by step solution

01

Microstates Quantity (a)

(a) Assume we get a paramagnet has N magnets, and shut to half them are as in spin-up state, giving in N=12N,, where Nby signifies the energy units. This method provides quantity of microstates:

max=N+N+1N=N2+N2+1N2

when N is solely an honest

maxNN2=N!N2!N2!

For such design variables, we'll employ Stirling's approximation:

n!2nnnen

max2NNNeN2N2N2N2eN22

max2NNNeN2N2N2NeN

max2NNNNN2N

max2N2NN

max2N+12N

max2N+12N

max2N

02

Vicinity of the height   (b) 

b) We derive its multitude solution within the location of the crest, let:

x=NN2N=N2+x

x=NNN2N=N2x

Therefore, while the subsequent is accurate:

=N+N+1N=N2+x+N2x+1N2xN2x

N2x=N!N2x!N2+x!

As a conclusion, the redundancy think about units of xis:

2NNNeN2N2xN2xN2xeN2x2N2+xN2+xN2+xeN2+x

eNwith eN2+xeN2x

2NNN2N2xN2xN2x2N2+xN2+xN2+x

2N2+x2N2x=2N22x2

03

Equation

2NNN2N22x2N2xN2xN2+xN2+x

2NNN2N22x2N2xN2N2xxN2+xN2N2+xx

N2+xN2N2xN2=N22x2N2

2NNN2N22x2N22x2N2N2xxN2+xx

NNN2N22x2N2+12N2xxN2+xx

We also may function of notation and handle massive Napplications without feeling worried concerning square root values. As a basis, here's a conservative calculation:

NNN22x2N2N2xxN2+xx

both on sides, have used the expectation andtake care of ln(ab)=ln(a)+ln(b)andlnab=ln(a)ln(b)

ln()lnNNlnN22x22lnN2+xxlnN2xx

ln()Nln(N)N2lnN22x2xlnN2+x+xlnN2x

N2lnN22x2=N2lnN2212xN2

N2lnN22x2=N22lnN2+ln12xN2

04

Remaining Equation

ln(1+x)=xfor|x|<<1

N2lnN22x2=N22lnN22xN2

N2lnN22x2=NlnN22x2N

N2lnN22x2=NlnNNln22x2N

xlnN2+x=xlnN2+xln1+2xN

xlnN2+x=xlnN2+2x2N

05

Fourth Term of Equation

xlnN2x=xlnN2+xln12xN

xlnN2x=xlnN22x2N

ln()Nln(N)NlnN+Nln2+2x2NxlnN22x2N+xlnN22x2N

ln()Nln2+2x2N2x2N2x2N

ln()ln2N2x2N

2Ne2x2N

maxe2x2N

max=2N

06

Peak value (c)

c) Oncethe top declines to 1eof its previous peak, the length of the crest is:

maxe=maxe-2x2N

e-1=e-2x2N

2x2N=1

As a response, the peak's girth is increased.

07

Coins  (d)

d) If 1000000 currencies were spun, the probability of getting 501000 heads is (let Nbe the head):

Substitution giving in:

x=NN2

=50100010000002=1000

P=max

P=e2x2N

x=1000and N=1000000are changed, giving in:

P=e2(1000)21000000=0.1353

It wouldn't be a very controversial outcome, given the big likelihood.

Obtaining a conclusion of 510000heads seems to own a likelihood of:

x=NN2

=51000010000002

=10000

P=e2(10000)21000000

=1.3841087

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Most popular questions from this chapter

A black hole is a region of space where gravity is so strong that nothing, not even light, can escape. Throwing something into a black hole is therefore an irreversible process, at least in the everyday sense of the word. In fact, it is irreversible in the thermodynamic sense as well: Adding mass to a black hole increases the black hole's entropy. It turns out that there's no way to tell (at least from outside) what kind of matter has gone into making a black hole. Therefore, the entropy of a black hole must be greater than the entropy of any conceivable type of matter that could have been used to create it. Knowing this, it's not hard to estimate the entropy of a black hole.
aUse dimensional analysis to show that a black hole of mass Mshould have a radius of order GM/c2, where Gis Newton's gravitational constant and cis the speed of light. Calculate the approximate radius of a one-solar-mass black holeM=21030kg .
bIn the spirit of Problem 2.36, explain why the entropy of a black hole, in fundamental units, should be of the order of the maximum number of particles that could have been used to make it.

cTo make a black hole out of the maximum possible number of particles, you should use particles with the lowest possible energy: long-wavelength photons (or other massless particles). But the wavelength can't be any longer than the size of the black hole. By setting the total energy of the photons equal toMc2 , estimate the maximum number of photons that could be used to make a black hole of mass M. Aside from a factor of 82, your result should agree with the exact formula for the entropy of a black hole, obtained* through a much more difficult calculation:

Sb.h.=82GM2hck

d Calculate the entropy of a one-solar-mass black hole, and comment on the result.

Show that during the quasistatic isothermal expansion of a monatomic ideal gas, the change in entropy is related to the heat input Qby the simple formula

s=QT

In the following chapter I'll prove that this formula is valid for any quasistatic process. Show, however, that it is not valid for the free expansion process described above.

Suppose you flip 20 fair coins.

(a) How many possible outcomes (microstates) are there?

(b) What is the probability of getting the sequence HTHHTTTHTHHHTHHHHTHT (in exactly that order)?

(c) What is the probability of getting 12 heads and 8 tails (in any order)?

Using the same method as in the text, calculate the entropy of mixing for a system of two monatomic ideal gases, Aand B, whose relative proportion is arbitrary. Let Nbe the total number of molecules and letx be the fraction of these that are of speciesB . You should find

Smixing=Nk[xlnx+(1x)ln(1x)]

Check that this expression reduces to the one given in the text whenx=1/2 .

Write e1023in the form 10x, for somex.

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