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The specific heat capacity of Albertson's Rotini Tricolore is approximately 1.8 J/g oC . Suppose you toss 340 g of this pasta (at 25oC ) into 1.5 liters of boiling water. What effect does this have on the temperature of the water (before there is time for the stove to provide more heat)?

Short Answer

Expert verified

Final temperature is 366.48 K (93.48oC )

Step by step solution

01

Given information

Specific heat capacity of water, c = 1 cal/gK = 4.186J/gK
Specific heat capacity of pasta, cpasta=1.8 J/gK
Mass of water, mWater=1500 g
Mass of pasta, mPasta= 340 g
Initial temperature of water =100oC=373.15 K
Initial temperature of pasta =25oC = 298.15K


02

Step2:Explanation

We know heat capacity is given as

C = m c

where m= mass and c= specific heat capacity

Find the heat capacity of Pasta and Water

ForWaterCwater=mwater×cwater=(1500g)×(4.186J/gK)=6279JK-1................................(1)ForPasta,Cpasta=mpasta×cpasta=(340g)×(1.8J/gK)=612J-1K-1.......................................(2)

Now find the change in temperature using

C=QΔT

For water

Cwater=QwaterΔTwater6279J·g-1K-1=QwaterΔTwater......................(3)

Similarly for Pasta

Cpasta=QpassaΔTpasta612Jg-1K-1=QpastaΔTpasta...........................(4)

Assuming no heat is lost anywhere else.

Heat lost by water is equal to heat gain by Pasta.

Q=Qpasta=-Qwater

From the equation (3) and (4)

6279J·g-1K-1=-QT-373.15...........................(5)612J·g-1K-1=QT-298.15.............................(6)

Solve for T by dividing (5) by (6), we get,

6279J.g-1K-1612J.g-1K-1=-Q/(T-373.15K)Q/(T-298.15K)T-298.15K373.15K-T=10.26T-298.15=3828.51-10.26T11.26T=4126.66T=366.48K

Temp will be increased to 93.48oC

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Most popular questions from this chapter

A battery is connected in series to a resistor, which is immersed in water (to prepare a nice hot cup of tea). Would you classify the flow of energy from the battery to the resistor as "heat" or "work"? What about the flow of energy from the resistor to the water?

When the temperature of liquid mercury increases by one degree Celsius (or one kelvin), its volume increases by one part in 550,000 . The fractional increase in volume per unit change in temperature (when the pressure is held fixed) is called the thermal expansion coefficient, β :
β≡ΔV/VΔT
(where V is volume, T is temperature, and Δ signifies a change, which in this case should really be infinitesimal if β is to be well defined). So for mercury, β =1 / 550,000 K-1=1.81 x 10-4 K-1. (The exact value varies with temperature, but between 0oC and 200oC the variation is less than 1 %.)
(a) Get a mercury thermometer, estimate the size of the bulb at the bottom, and then estimate what the inside diameter of the tube has to be in order for the thermometer to work as required. Assume that the thermal expansion of the glass is negligible.
(b) The thermal expansion coefficient of water varies significantly with temperature: It is 7.5 x 10 -4 K-1 at 100oC, but decreases as the temperature is lowered until it becomes zero at 4oC. Below 4oC it is slightly negative, reaching a value of -0.68 x 10-4K-1 at 0oC. (This behavior is related to the fact that ice is less dense than water.) With this behavior in mind, imagine the process of a lake freezing over, and discuss in some detail how this process would be different if the thermal expansion coefficient of water were always positive.


Imagine some helium in a cylinder with an initial volume of 1litreand an initial pressure of 1atm.Somehow the helium is made to expand to a final volume of 3litres,in such a way that its pressure rises in direct proportion to its volume.

(a) Sketch a graph of pressure vs. volume for this process.

(b) Calculate the work done on the gas during this process, assuming that there are no "other" types of work being done.

(c) Calculate the change in the helium's energy content during this process.

(d) Calculate the amount of heat added to or removed from the helium during this process.

(e) Describe what you might do to cause the pressure to rise as the helium expands.

Even at low density, real gases don’t quite obey the ideal gas law. A systematic way to account for deviations from ideal behavior is the virial

expansion,

PV−nRT(1+B(T)(V/n)+C(T)(V/n)2+⋯)

where the functions B(T), C(T), and so on are called the virial coefficients. When the density of the gas is fairly low, so that the volume per mole is large, each term in the series is much smaller than the one before. In many situations, it’s sufficient to omit the third term and concentrate on the second, whose coefficient B(T)is called the second virial coefficient (the first coefficient is 1). Here are some measured values of the second virial coefficient for nitrogen (N2):

T(K)
B(cm3/mol)
100–160
200–35
300–4.2
4009.0
50016.9
60021.3
  1. For each temperature in the table, compute the second term in the virial equation, B(T)/(V/n), for nitrogen at atmospheric pressure. Discuss the validity of the ideal gas law under these conditions.
  2. Think about the forces between molecules, and explain why we might expect B(T)to be negative at low temperatures but positive at high temperatures.
  3. Any proposed relation between P, V, andT, like the ideal gas law or the virial equation, is called an equation of state. Another famous equation of state, which is qualitatively accurate even for dense fluids, is the van der Waals equation,
    (P+an2V2)(V−nb)=nRT
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  4. Plot a graph of the van der Waals prediction for B(T), choosing aand bso as to approximately match the data given above for nitrogen. Discuss the accuracy of the van der Waals equation over this range of conditions. (The van der Waals equation is discussed much further in Section 5.3.)

Given an example to illustrate why you cannot accurately judge the temperature of an object by how hot or cold it feels to the touch?

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