Problem 55 The equation of state for a ther... [FREE SOLUTION]

Chapter 9: Problem 55

The equation of state for a thermodynamic system is $F(P, V, 7)=0$, where $P, V$, and $T$ are pressure, volume, and temperature, respectively. If the equation defines $V$ as a function of $P$ and $T$, and also defines $T$ as a function of $V$ and $P$, show that $$ \frac{\partial V}{\partial T}=-\frac{\frac{\partial F}{\partial T}}{\frac{\partial F}{\partial V}}=-\frac{1}{\frac{\partial T}{\partial V}} . $$

Short Answer

Expert verified

$ \frac{\partial V}{\partial T} = -\frac{1}{\frac{\partial T}{\partial V}} $ is shown by simplifying implicit derivatives.

Step by step solution

Understand the Problem Statement

We are given an equation of state $ F(P, V, T) = 0 $ that defines relationships between pressure $ P $, volume $ V $, and temperature $ T $. The task is to show a specific relationship involving partial derivatives of these variables.

Express V as a Function of P and T

Since $ V $ can be expressed as a function of $ P $ and $ T $, use implicit differentiation to find $ \frac{\partial V}{\partial T} $. We do this by treating $ P $ as a constant when differentiating with respect to $ T $.

Implicit Differentiation

Differentiate the equation $ F(P, V, T) = 0 $ with respect to $ T $ while treating $ P $ as constant. This gives:\[ \frac{\partial F}{\partial V} \frac{\partial V}{\partial T} + \frac{\partial F}{\partial T} = 0 \]

Solve for $ \frac{\partial V}{\partial T} $

From the equation obtained in Step 3, solve for $ \frac{\partial V}{\partial T} $: \[ \frac{\partial V}{\partial T} = -\frac{\frac{\partial F}{\partial T}}{\frac{\partial F}{\partial V}} \]

Express T as a Function of V and P

Similarly, express $ T $ as a function of $ V $ and $ P $ using implicit differentiation, treating $ P $ as constant.

Implicit Differentiation for T

Differentiate $ F(P, V, T) = 0 $ with respect to $ V $ and solve for $ \frac{\partial T}{\partial V} $: \[ \frac{\partial F}{\partial V} + \frac{\partial F}{\partial T} \frac{\partial T}{\partial V} = 0 \] From this, solve for $ \frac{\partial T}{\partial V} $: \[ \frac{\partial T}{\partial V} = -\frac{\frac{\partial F}{\partial V}}{\frac{\partial F}{\partial T}} \]

Relate the Derivatives

Relate $ \frac{\partial V}{\partial T} $ and $ \frac{\partial T}{\partial V} $ using their derived expressions to show that:\[ \frac{\partial V}{\partial T} = -\frac{1}{\frac{\partial T}{\partial V}} \]This matches the expressions derived, confirming the relationship.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Equation of State

The equation of state is a fundamental concept in thermodynamics. It describes the relationship between different state variables such as pressure $ P $, volume $ V $, and temperature $ T $ in a thermodynamic system. The given equation of state is $ F(P, V, T) = 0 $. This relationship implies that these three variables are interdependent. Changing one of them will affect the others.Equations of state are crucial for understanding how systems behave under different conditions.

For gases, a common equation of state is the ideal gas law: $ PV = nRT $, where $ n $ is the amount of substance and $ R $ is the gas constant.
More complex equations might be needed for other states of matter or non-ideal gases.

These equations are essential for predicting the response of a system to external changes such as pressure changes or heat transfer.

Partial Derivatives

Partial derivatives are a valuable tool in thermodynamics for exploring how a function changes as its variables change. In our context, they show how a slight change in one variable, such as temperature $ T $, affects another variable, like volume $ V $, while keeping other variables constant. The partial derivative $ \frac{\partial V}{\partial T} $ identifies the change in volume with respect to temperature, assuming pressure is constant.

For a function $f(x, y)$, the partial derivative with respect to $x$ is found by differentiating $f$ with $x$ while keeping $y$ constant.
In the equation $ F(P, V, T) = 0 $, when exploring $ \frac{\partial V}{\partial T} $, we treat $ P $ as a constant factor.

Understanding partial derivatives allows us to predict how a small variation in one variable impacts others, crucial for examining thermodynamic systems.

Implicit Differentiation

When variables are related by an equation like $ F(P, V, T) = 0 $, differentiating explicitly isn't always possible. Implicit differentiation becomes valuable when solving for derivatives. It focuses on differentiating each term while acknowledging the interdependencies between the variables.Here's how you can apply implicit differentiation:

Differentiate the entire equation taking one variable as constant, like treating $ P $ as a constant when finding $\frac{\partial V}{\partial T}$.
Apply the chain rule appropriately to incorporate derivatives where needed. For instance, differentiating $ F $ concerning $ T $, you obtain $ \frac{\partial F}{\partial V} \frac{\partial V}{\partial T} + \frac{\partial F}{\partial T} = 0 $.

This method allows extraction of relationships between derivatives which aren't directly expressed through explicit functions.

Thermodynamic System Analysis

Analyzing thermodynamic systems often involves looking at relationships between variables, such as how temperature, pressure, and volume affect each other. The system described with the equation $ F(P, V, T) = 0 $ serves as a basis to delve into its dynamics.Key steps in analysis include:

Defining the scope: Identify the state variables and the specific relationships or dependencies between them.
Utilizing derivatives: Use partial and implicit derivatives to explore how small changes in one variable impact others.
Applying theoretical principles: Apply the law of conservation of energy and other thermodynamic laws to understand how the system behaves under different conditions.

Such analyses are fundamental in optimizing systems, predicting behavior under new conditions, and designing efficient energy solutions.

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Short Answer

Step by step solution

Understand the Problem Statement

Express V as a Function of P and T

Implicit Differentiation

Solve for \( \frac{\partial V}{\partial T} \)

Express T as a Function of V and P

Implicit Differentiation for T

Relate the Derivatives

Key Concepts

Equation of State

Partial Derivatives

Implicit Differentiation

Thermodynamic System Analysis

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