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If photons of energy \(12.75 \mathrm{eV}\) are passing through hydrogen gas in ground state then number of lines in emission spectrum will be (A) 6 (B) 4 (C) 3 (D) 2

Short Answer

Expert verified
The number of lines in the emission spectrum when photons of energy \(12.75 \mathrm{eV}\) pass through hydrogen gas in the ground state is 6 (Option A).

Step by step solution

01

Convert the energy to joules

To proceed with this exercise, we need to convert the energy of photons from electron volts (eV) to joules (J). We can do this using the conversion factor 1 eV = \(1.602 \times 10^{-19}\) J. Given energy, E = 12.75 eV To convert it to Joules, we multiply it with the conversion factor: E = \(12.75 \times 1.602 \times 10^{-19}\) J E ≈ \(2.043 \times 10^{-18}\) J
02

Identify the highest energy level

The energy for transitions in a hydrogen atom can be found using the formula: E = \(\frac{(2.18 \times 10^{-18} J)(1 - \frac{1}{n^{2}})}{1 - \frac{1}{(n+1)^{2}}}\) Where E is the energy required for the transition, and n is the energy level of the atom. Now, we need to find the maximum value of n for which the energy E is sufficient. Since the energy E should be equal or greater than the transition energy for hydrogen, we can write the inequality: \(2.043 \times 10^{-18} J\) ≥ \(\frac{(2.18 \times 10^{-18} J)(1 - \frac{1}{n^{2}})}{1 - \frac{1}{(n+1)^{2}}}\) After solving the inequality, we find that the maximum value of n is 4.
03

Calculate the number of lines in the emission spectrum

To find the number of lines in the emission spectrum when the hydrogen atom transitions from the highest energy level (n=4) to the ground state (n=1), we can use the formula: Number of lines = \(\frac{n(n-1)}{2}\) Where n is the highest energy level. Number of lines = \(\frac{4(4-1)}{2}\) Number of lines = \(\frac{4\times 3}{2}\) Number of lines = \(6\) So, the correct answer is: (A) 6

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