/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 57 1 mole of \(\mathrm{H}_{2}\) gas... [FREE SOLUTION] | 91影视

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1 mole of \(\mathrm{H}_{2}\) gas is contained in a box of volume \(V=1.00 \mathrm{~m}^{3}\) at \(T=300 \mathrm{~K} .\) The gas is heated to a temperature of \(T=3000 \mathrm{~K}\) and the gas gets converted to a gas of hydrogen atoms. The final pressure would be (considering all gases to be ideal) (A) same as the pressure initially. (B) two times the pressure initially. (C) ten times the pressure initially. (D) twenty times the pressure initially.

Short Answer

Expert verified
The final pressure would be twenty times the pressure initially. (D)

Step by step solution

01

Write down the initial conditions.

The initial conditions are given as: - Number of moles of gas (n) = 1 mole - Volume (V) = 1.00 m鲁 - Initial temperature (T鈧) = 300 K - Final temperature (T鈧) = 3000 K
02

Calculate the initial pressure using the Ideal Gas Law.

We can use the Ideal Gas Law to find the initial pressure (P鈧): \(P鈧乂 = nRT鈧乗) Since we need to find the relation between P鈧 and P鈧, we can leave P鈧 in terms of R: \(P鈧 = \frac{nRT鈧亇{V}\)
03

Calculate the final pressure using the Ideal Gas Law.

First, consider that the hydrogen molecules (H鈧) are now converted into hydrogen atoms (H). Since each molecule contains 2 atoms, we now have twice the number of moles - 2 moles of H. Using the Ideal Gas Law for the final pressure (P鈧), we have: \(P鈧俈 = nRT鈧俓), where n = 2 moles. Solve for P鈧: \(P鈧 = \frac{nRT鈧倉{V}\)
04

Find the relation between the initial and final pressure.

Divide the expression for P鈧 by the expression for P鈧: \(\frac{P鈧倉{P鈧亇 = \frac{\frac{nRT鈧倉{V}}{\frac{nRT鈧亇{V}}\) Notice that the volume (V) can be canceled out: \(\frac{P鈧倉{P鈧亇 = \frac{nRT鈧倉{nRT鈧亇\) Remember that the final number of moles is twice the initial number of moles, so substitute n = 2 in the equation: \(\frac{P鈧倉{P鈧亇 = \frac{2RT鈧倉{RT鈧亇\) Now, cancel the gas constant (R): \(\frac{P鈧倉{P鈧亇 = \frac{2(T鈧)}{(T鈧)}\) Finally, substitute the initial (T鈧) and final (T鈧) temperatures: \(\frac{P鈧倉{P鈧亇 = \frac{2(3000)}{(300)} = \frac{6000}{300}\) \(\frac{P鈧倉{P鈧亇 = 20\)
05

Choose the correct answer.

Since the final pressure (P鈧) is 20 times the initial pressure (P鈧), we choose answer (D).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Mole Concept
In chemistry, the mole concept is a fundamental idea that helps us understand the amount of substance. When we talk about a mole, we're essentially talking about Avogadro's number, which is approximately \(6.022 \times 10^{23}\) particles. This could be atoms, molecules, ions, or electrons. In the exercise, we start with 1 mole of hydrogen gas (\(\mathrm{H}_{2}\) molecules), meaning there are \(6.022 \times 10^{23}\) hydrogen molecules in our sample.
This understanding is crucial because it allows us to calculate how many individual entities we have in a given mass. In the problem, when the hydrogen gas gets converted from molecules to atoms, our 1 mole of hydrogen molecules turns into 2 moles of hydrogen atoms as each hydrogen molecule has 2 atoms.
Hence, the mole concept helps us track the number of particles before and after the chemical change, ensuring that we can apply the Ideal Gas Law accurately.
Hydrogen Gas
Hydrogen gas is the simplest and most abundant element in the universe. It exists naturally as diatomic molecules (\(\mathrm{H}_{2}\)), meaning each molecule is made of two hydrogen atoms bonded together. Because of this, hydrogen gas is quite different from single hydrogen atoms in terms of behavior and properties.
When we apply heat to hydrogen gas, it can cause the molecules to dissociate into individual hydrogen atoms. In the context of the Ideal Gas Law, this change in molecular structure affects the pressure of the gas because, now, we have twice the number of gaseous particles in the same volume.
Hydrogen's light mass and reactive nature make it important not only in chemical reactions but also in calculations like those involving the Ideal Gas Law. Understanding how hydrogen gas behaves under different states, such as temperature changes, is essential for accurate predictions and outcomes when using gas laws.
Temperature Change
Temperature is a measure of the average kinetic energy of particles. When the temperature of a gas increases, the kinetic energy of its molecules also increases, thereby causing the molecules to move more energetically. This is exactly what happens when the hydrogen gas in the problem is heated from 300 K to 3000 K.
A significant temperature increase not only makes the particles move faster but can also alter the physical state if enough energy is provided, as seen with hydrogen molecules dissociating into atoms. According to the Ideal Gas Law, \(PV = nRT\), if temperature (T) increases, pressure (P) will also increase if the volume (V) and number of moles (n) remain constant.
In our scenario, both the number of moles and the temperature dramatically increase, doubling the number of moles and increasing the temperature tenfold, which leads to a pressure increase proportional to these changes. Understanding this relationship is vital for predicting how a gas will react to energy changes, particularly in controlled environments.

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