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In a study of isothermal autocatalytic reactions, Gray and Scott (1985) considered a hypothetical reaction whose kinetics are given in dimensionless form by $$ \dot{u}=a(1-u)-u v^{2}, \quad \dot{v}=u v^{2}-(a+k) v $$ where \(a, k>0\) are parameters. Show that saddle-node bifurcations occur at \(k=-a \pm \frac{1}{2} \sqrt{a}\).

Short Answer

Expert verified
In summary, to show that saddle-node bifurcations occur at \(k=-a \pm \frac{1}{2} \sqrt{a}\), we first found the fixed points of the given system of differential equations. We then linearized the system around these fixed points and analyzed the eigenvalues of the linearized system. By finding parameter values for which one eigenvalue is positive and one is negative, we derived the conditions for a saddle-node bifurcation and demonstrated that they occur at \(k=-a \pm \frac{1}{2} \sqrt{a}\).

Step by step solution

01

Find the fixed points

To find the fixed points of the system, set \(\dot{u} = 0\) and \(\dot{v} = 0\). This gives us the following system of equations: 1. \(a(1-u)-u v^2 = 0\) 2. \(u v^2 -(a+k) v = 0\) Now we need to solve these equations simultaneously for \(u\) and \(v\).
02

Solve for the fixed points

From equation (2), we have two cases: - Case 1: \(v = 0\) If \(v=0\), equation (1) becomes: \(a(1-u) = 0\) Solving for \(u\), we get: \(u = 1\) So one fixed point is \((u, v) = (1, 0)\). - Case 2: \(uv^2 = (a+k)v\) Divide both sides by \(v\): \(uv = a + k\) Now substitute this expression for \(uv\) in equation (1): \(a(1-u)-uv^2 = a(1-u)-(a+k)v = 0\) Rearrange and factor: \((1-u)(a-v) = 0\) This gives two possibilities: \(u = 1\) or \(v = a\). If \(u = 1\), we already found this fixed point in Case 1. So, we're left with \(v=a\). Substituting \(v=a\) in the expression for \(uv\), we get: \(ua = a + k \Rightarrow u = 1 + \frac{k}{a}\) Thus, the second fixed point is \(\left(1+\frac{k}{a}, a\right)\).
03

Linearize the system around the fixed points

We'll now linearize the given system of equations around the fixed points. The Jacobian matrix for the system is: \( J(u,v) = \begin{bmatrix} -\frac{\partial \dot{u}}{\partial u} & -\frac{\partial \dot{u}}{\partial v} \\ \frac{\partial \dot{v}}{\partial u} & \frac{\partial \dot{v}}{\partial v} \end{bmatrix}=\begin{bmatrix} -a-2uv^2 & -2uv \\ v^2 & 2uv-a-k \end{bmatrix} \) Now, compute the Jacobian at each fixed point: - Fixed Point 1: \((1,0)\) \( J(1,0) = \begin{bmatrix} -a & 0 \\ 0 & -a-k \end{bmatrix} \) - Fixed Point 2: \(\left(1+\frac{k}{a}, a\right)\) \( J\left(1+\frac{k}{a}, a\right) = \begin{bmatrix} -a+2k & -2(1+\frac{k}{a})a \\ a^2 & 0 \end{bmatrix} \)
04

Analyze the eigenvalues and find saddle-node bifurcations

Next, we analyze the eigenvalues for the Jacobian matrices calculated in Step 3 and find the parameter values at which saddle-node bifurcations occur. - For Fixed Point 1: The eigenvalues of \(J(1,0)\) are simply the diagonal elements, \(-a\) and \(-a-k\). As we are looking for a saddle-node bifurcation, one eigenvalue must be positive and one must be negative. In this case, both eigenvalues are negative, so there is no saddle-node bifurcation at \((1, 0)\). - For Fixed Point 2: The eigenvalues of \(J\left(1+\frac{k}{a}, a\right)\) are given by the characteristic equation: \( \det(J-\lambda I) = \begin{vmatrix} -a+2k-\lambda & -2(1+\frac{k}{a})a \\ a^2 & -\lambda \end{vmatrix} =(-\lambda)(-\lambda -2k+a)-2a^3(1+\frac{k}{a}) =0 \) Simplifying the characteristic equation, we have: \(\lambda^2 - (a-2k)\lambda - 2a^2 (a+k) = 0\) Now, apply the quadratic formula to find the eigenvalues: \(\lambda = \frac{-(a-2k) \pm \sqrt{((a-2k)^2 - 4(-2a^2 (a+k)))}}{2}\) For a saddle-node bifurcation, one eigenvalue must be positive, and one must be negative. This occurs when the discriminant of the characteristic equation is zero: \(((a-2k)^2 - 4(-2a^2 (a+k))) = 0\) Solving the equation for \(k\), we get: \(k=-a \pm \frac{1}{2} \sqrt{a}\) This shows that saddle-node bifurcations occur at \(k=-a \pm \frac{1}{2} \sqrt{a}\), as required.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Isothermal Autocatalytic Reactions
Isothermal autocatalytic reactions are a fascinating topic in the field of chemical kinetics. These are reactions where the reactant helps catalyze the reaction itself, which means they speed up when there's more of the reactant present. It's like the reaction encourages itself! In the case of isothermal processes, such reactions occur at a constant temperature. This simplicity can help us study the dynamics of the chemical system without thermal effects skewing the results.

In the equations presented from Gray and Scott (1985), the variables describe concentrations over time and illustrate how the concentration of substances in a reaction changes. This changes with respect to parameters and leads to stable or unstable behavior in the reaction. It's especially significant in demonstrating how certain conditions can lead to complex behavior such as bifurcations.
Fixed Points
Fixed points are solutions of a system of differential equations that do not change with time. Imagine you're sitting on a merry-go-round—fixed points would be the spots where you can sit without being spun around. In our chemical system, these points represent the steady-state conditions where the reaction doesn't change anymore.

To find these fixed points, we set the derivatives (denoted as \(\dot{u}\) and \(\dot{v}\)) to zero because this means there's no more change in these concentrations. In practice, you solve the resulting algebraic equations to find the values of \(u\) and \(v\) that make both derivatives zero. These solutions can then be analyzed to understand the system's behavior under various conditions.
Jacobian Matrix
The Jacobian matrix provides a snapshot of the system's dynamics near a fixed point, much like a weather forecast predicting the short-term climate around your home. It consists of first-order partial derivatives of the system's differential equations, showcasing how small changes in variables can lead to changes in the system's state.

In our study, the Jacobian matrix is built by taking the partial derivatives of \(\dot{u}\) and \(\dot{v}\) with respect to \(u\) and \(v\). The matrix helps identify the stability of fixed points by examining these derivatives' effects. At each fixed point, evaluating the Jacobian matrix allows us to see whether small disturbances grow or shrink, helping predict the system's response.
Eigenvalues
Eigenvalues are vital in understanding the stability of fixed points as they offer insight into the behavior of small disturbances. If eigenvalues were sounds, they'd tell us whether a system sings a steady tune or screeches to a halt.

Calculated from the Jacobian matrix, eigenvalues establish whether small changes in our variables grow or decay. If all eigenvalues are negative, the fixed point is like a stable chair—you sit down and it stays put. Positive eigenvalues, however, act like a marble at the top of a hill—the slightest push sends it rolling.

Saddle-node bifurcations occur when these eigenvalues change sign, signaling a shift from stability to instability. This transition is precisely what the solution outlines when solving for the characteristic equation's eigenvalues, showing under which conditions these bifurcations take place.

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Most popular questions from this chapter

Discuss the bifurcations of the system \(\dot{r}=r(\mu-\sin r), \dot{\theta}=1\) as \(\mu\) varies.

(A heuristic analysis) The system \(\dot{x}=-y+\mu x+x y^{2}, \hat{y}=x+\mu y-x^{2}\) can be analyzed in a rough, intuitive way as follows. a) Rewrite the system in polar coordinates. b) Show that if \(r<<1\), then \(\dot{\theta}=1\) and \(\dot{r}=\mu r+\frac{1}{8} r^{3}+\cdots\), where the terms omitted are oscillatory and have essentially zero time-average around one cycle. c) The formulas in part (b) suggest the presence of an unstable limit cycle of radius \(r=\sqrt{-8 \mu}\) for \(\mu<0 .\) Confirm that prediction numerically (Since we assumed that \(r<<1\), the prediction is expected to hold only if \(|\mu|<<1 .)\) The reasoning above is shaky. See Drazin (1992, pp. \(188-190)\) for a proper analysis via the Poincarc-Lindstedt method.

(Plotting Lissajous figures) Using a computer, plot the curve whose parametric equations are \(x(t)=\sin t, y(t)=\sin \omega t\), for the following rational and irrational values of the parameter \(\omega\) : (a) \(\omega=3\) (b) \(\omega=\\}\) (c) \(\omega=\frac{5}{3}\) (d) \(\omega=\sqrt{2}\) (e) \(\omega=\pi\) (f) \(\omega=\frac{1}{2}(1+\sqrt{5})\). The resulting curves are called Lissajous figures. In the old days they were displayed on oscilloscopes by using two ac signals of different frequencies as inputs.

Consider the biased van der Pol oscillator \(\ddot{x}+\mu\left(x^{2}-1\right) \dot{x}+x=a\). Find the curves in \((\mu, a)\) space at which Hopf bifurcations occur. The next three exercises deal with the system \(\dot{x}=-y+\mu x+x y^{2}\), \(\dot{y}=x+\mu y-x^{2}\).

Consider the system \(\dot{r}=r\left(1-r^{2}\right), \dot{\theta}=\mu-\sin \theta\) for \(\mu\) slightly greater than 1 . Let \(x=r \cos \theta\) and \(y=r \sin \theta\). Sketch the waveforms of \(x(t)\) and \(y(t)\). (These are typical of what one might see experimentally for a system on the verge of an infinite- period bifurcation.)

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