Chapter 3: Problem 6
The radioactive isotope of lead, \(\mathrm{Pb}-209\), decays at a rate proportional to the amount present at any time and has a half-life of \(3.3\) hours. If 1 gram of lead is present initially, how long will it take for \(90 \%\) of the lead to decay?
Short Answer
Expert verified
It takes approximately 10.96 hours for 90% to decay.
Step by step solution
01
Understand the Problem
We want to find the time it takes for 90% of the radioactive isotope \( \mathrm{Pb}-209 \) to decay. Given the half-life \( T_{1/2} = 3.3 \) hours and the initial amount \( A_0 = 1 \) gram, we need to determine when the remaining quantity is 10% of the original amount.
02
Set Up the Decay Equation
The decay of a radioactive isotope can be described by the equation \( A(t) = A_0 e^{-kt} \), where \( A(t) \) is the amount remaining at time \( t \), \( A_0 \) is the initial amount, and \( k \) is the decay constant.
03
Calculate the Decay Constant
Using the half-life formula \( T_{1/2} = \frac{\ln(2)}{k} \), we can solve for \( k \). Given \( T_{1/2} = 3.3 \), we have \( k = \frac{\ln(2)}{3.3} \).
04
Substitute Values
Substitute \( k \) into the decay equation. Also, since 90% decay means only 10% remains, set \( A(t) = 0.1A_0 \). Substitute \( A_0 = 1 \) gram, so \( A(t) = 0.1 \). The equation is now \( 0.1 = 1 e^{-k t} \).
05
Solve for Time \( t \)
Rearrange \( 0.1 = e^{-kt} \) to solve for \( t \): \( e^{-kt} = 0.1 \). Taking the natural log of both sides gives \( -kt = \ln(0.1) \). Solve for \( t \): \( t = -\frac{\ln(0.1)}{k} \).
06
Substitution and Calculation
Substitute \( k = \frac{\ln(2)}{3.3} \) into \( t = -\frac{\ln(0.1)}{k} \). Calculate \( t \) using a calculator: \( t \approx 10.96 \).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Half-Life
The concept of half-life is essential in understanding radioactive decay. Half-life is the time required for half of the radioactive isotope in a sample to decay.
For example, if you start with a certain amount of radioactive material, after one half-life, you will have half of it remaining.
After two half-lives, only a quarter of the original amount will be left. This means each half-life reduces the remaining quantity by half, no matter how much you start with.
For example, if you start with a certain amount of radioactive material, after one half-life, you will have half of it remaining.
After two half-lives, only a quarter of the original amount will be left. This means each half-life reduces the remaining quantity by half, no matter how much you start with.
- The half-life for lead-209 (\(\mathrm{Pb}-209 \)) is 3.3 hours.
- This half-life is specific to each isotope and does not change unless the isotope is altered.
- It allows us to predict how quickly a given isotope will decay over time.
Decay Constant
The decay constant, denoted by the symbol \( k \), is a crucial part of the radioactive decay equation. It relates to how quickly a substance undergoes decay.
A higher decay constant means the substance decays more rapidly.
A higher decay constant means the substance decays more rapidly.
- The decay constant \( k \) is calculated using the formula: \( k = \frac{\ln(2)}{T_{1/2}} \).
- \(\ln(2)\) is the natural logarithm of 2, approximately equal to 0.693.
- For lead-209, the half-life \( (T_{1/2}) \) is 3.3 hours, so \( k = \frac{0.693}{3.3} \).
- The decay constant is essential for setting up the exponential decay equation.
Exponential Decay Equation
The exponential decay equation is a powerful tool used to model radioactive decay. It can predict the remaining amount of a substance at any time \( t \). The equation: \[ A(t) = A_0 e^{-kt} \] is instrumental in scientific calculations.
For example, to determine when 90% of lead-209 has decayed, we set \( A(t) = 0.1 A_0 \) and solve for \( t \). This equation captures the unique property of exponential decay, where the rate of change is proportional to the current value. It helps in precise calculations for half-life and decay constant relationships.
- \(A(t)\) is the amount of the substance remaining at time \( t \).
- \(A_0\) is the initial amount of the substance.
- \(e\) is the base of the natural logarithm, approximately 2.718.
- \(k\) is the decay constant, determining the rate of decay.
For example, to determine when 90% of lead-209 has decayed, we set \( A(t) = 0.1 A_0 \) and solve for \( t \). This equation captures the unique property of exponential decay, where the rate of change is proportional to the current value. It helps in precise calculations for half-life and decay constant relationships.