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The pressure \(P\), temperature \(T\), and volume \(V\) of an ideal gas are related by \(P V=n R T\), where \(n\) is the number of moles of the gas and \(R\) is the universal gas constant. For the purposes of this exercise, let \(n R=1 ;\) therefore, \(P=T / V\) a. Suppose the volume is held constant and the temperature increases by \(\Delta T=0.05 .\) What is the approximate change in the pressure? Does the pressure increase or decrease? b. Suppose the temperature is held constant and the volume increases by \(\Delta V=0.1 .\) What is the approximate change in the pressure? Does the pressure increase or decrease? c. Suppose the pressure is held constant and the volume increases by \(\Delta V=0.1 .\) What is the approximate change in the temperature? Does the temperature increase or decrease?

Short Answer

Expert verified
Answer: When the volume is constant and temperature increases by 0.05, the pressure increases (approximate change: \(\Delta P = \frac{1}{V} \cdot 0.05\)). When the temperature is constant and volume increases by 0.1, the pressure decreases (approximate change: \(\Delta P = -\frac{T}{V^2} \cdot 0.1\)).

Step by step solution

01

Differentiate with respect to temperature

For a constant volume, we can differentiate the ideal gas law equation, \(P=T/V\), with respect to temperature: \(\frac{dP}{dT} = \frac{1}{V}\)
02

Calculate change in pressure

Given \(\Delta T = 0.05\), we can approximate the change in pressure: \(\Delta P = \frac{dP}{dT} \cdot \Delta T = \frac{1}{V} \cdot 0.05\)
03

Determine if pressure increases or decreases

Since both \(\Delta T\) and \(\frac{1}{V}\) are positive, the change in pressure \(\Delta P\) is also positive, indicating that the pressure increases. b. Temperature constant, volume change
04

Differentiate with respect to volume

For a constant temperature, we can differentiate the ideal gas law equation, \(P=T/V\), with respect to volume: \(\frac{dP}{dV} = -\frac{T}{V^2}\)
05

Calculate change in pressure

Given \(\Delta V=0.1\), we can approximate the change in pressure: \(\Delta P = \frac{dP}{dV} \cdot \Delta V = -\frac{T}{V^2} \cdot 0.1\)
06

Determine if pressure increases or decreases

Since both \(T\) and \(V^2\) are positive and there's a negative in the equation, the change in pressure \(\Delta P\) is negative, indicating that the pressure decreases. c. Pressure constant, volume change
07

Differentiate with respect to volume

For constant pressure, we can rearrange the ideal gas law equation to solve for temperature: \(T = PV\). Differentiate it with respect to volume: \(\frac{dT}{dV} = P\)
08

Calculate change in temperature

Given \(\Delta V=0.1\), we can approximate the change in temperature: \(\Delta T = \frac{dT}{dV} \cdot \Delta V = P \cdot 0.1\)
09

Determine if temperature increases or decreases

Since both \(P\) and \(\Delta V\) are positive, the change in temperature \(\Delta T\) is also positive, indicating that the temperature increases.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Pressure-Temperature Relationship
When we observe the pressure-temperature relationship in the context of the Ideal Gas Law, we see that they are directly proportional. This means if the volume is held constant and the temperature increases, the pressure will increase as well.

To understand this, the Ideal Gas Law is given as \( P V = nRT \). If we simplify it to \( P = T/V \) (assuming \(nR = 1\) as in the exercise), it's clear that pressure \(P\) is proportional to temperature \(T\) when volume \(V\) is constant.

  • A higher temperature means the gas molecules move faster, which increases the force of their collisions with container walls, thus increasing pressure.
  • If the temperature were to decrease, we would see a decrease in pressure for the same reasons.
This relationship can easily be observed through differential calculus, where differentiating \(P = T/V\) with respect to \(T\) gives \(\frac{dP}{dT} = \frac{1}{V}\). The change in pressure \(\Delta P\) given a change in temperature \(\Delta T\) is then \(\Delta P = \frac{1}{V} \cdot \Delta T\), a positive result if the change in temperature is positive. Thus, we can conclude that pressure increases with increasing temperature when volume is constant.
Volume-Temperature Relationship
The volume-temperature relationship is straightforward under the assumption of constant pressure, as described by the Ideal Gas Law rearranged to \( T = PV \). Here we see that volume \(V\) is directly proportional to temperature \(T\) when pressure \(P\) is held constant.

  • This means increasing the volume of the gas requires an increase in temperature to keep the pressure from changing.
  • Conversely, if the volume decreases, the temperature must also reduce to maintain a constant pressure.
To compute how the temperature changes with a change in volume at constant pressure, we can use differential calculus. Differentiating \( T = PV \) with respect to \( V \) gives \( \frac{dT}{dV} = P \). Thus, when the volume changes by \( \Delta V \), the approximate change in temperature \( \Delta T \) is given by \( \Delta T = P \cdot \Delta V \). With both \(P\) and \(\Delta V\) positive, \(\Delta T\) is also positive, indicating that temperature increases as volume increases.
Differential Calculus in Physics
Differential calculus is a powerful tool in physics for analyzing how small changes in one quantity affect another. This is particularly useful in the study of ideal gases, where we often want to know how changes in temperature, pressure, or volume affect one another.

  • By applying differentiation, we can derive expressions predicting these changes without needing complex calculations.
  • This involved computing derivatives of the equation to find how one variable changes with respect to another.
For example, differentiating the pressure \(P = T/V\) with respect to temperature \(T\) gives \(\frac{dP}{dT} = \frac{1}{V}\), showing that pressure changes directly and linearly with temperature at constant volume.

On the other hand, differentiating the same equation with respect to volume gives \(\frac{dP}{dV} = -\frac{T}{V^2}\), which indicates that pressure decreases as volume increases when temperature is held constant.

Thus, differential calculus provides valuable insight and precise control over predictions about gas behavior in response to small changes in conditions, making it indispensable in physical sciences and engineering.

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