/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 60 In an acid-base titration, a bas... [FREE SOLUTION] | 91Ó°ÊÓ

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In an acid-base titration, a base or acid is gradually added to the other until they have completely neutralized each other. Because acids and bases are usually colorless (as are the water and salt produced in the neutralization reaction), \(\mathrm{pH}\) is measured to monitor the reaction. Suppose that the equivalence point is reached after approximately \(100 \mathrm{~mL}\) of a \(\mathrm{NaOH}\) solution have been added (enough to react with all the acetic acid present) but that replicates are equally likely to indicate from 95 to \(104 \mathrm{~mL}\) to the nearest \(\mathrm{mL}\). Assume that volumes are measured to the nearest \(\mathrm{mL}\) and describe the sample space. (a) What is the probability that equivalence is indicated at \(100 \mathrm{~mL} ?\) (b) What is the probability that equivalence is indicated at less than \(100 \mathrm{~mL} ?\) (c) What is the probability that equivalence is indicated between 98 and \(102 \mathrm{~mL}\) (inclusive)?

Short Answer

Expert verified
(a) \(\frac{1}{10}\) (b) \(\frac{1}{2}\) (c) \(\frac{1}{2}\)

Step by step solution

01

Understand the Sample Space

In this problem, the sample space is the set of all possible outcomes for the volume at which equivalence is indicated. According to the problem, this can be any integer value from 95 mL to 104 mL, inclusive. Thus, the sample space is \[ S = \{95, 96, 97, 98, 99, 100, 101, 102, 103, 104\} \].
02

Calculate Probability for Equivalence at 100 mL

To find the probability that equivalence is exactly at 100 mL, consider that each possible outcome is equally likely. There are 10 possible outcomes (from 95 to 104 mL). The probability for equivalence at any specific mL is then \[ P(100\, \text{mL}) = \frac{1}{10} \].
03

Calculate Probability for Equivalence Under 100 mL

The outcomes less than 100 mL are 95, 96, 97, 98, and 99. Count these outcomes: there are 5. So, the probability for equivalence under 100 mL is \[ P(<100\, \text{mL}) = \frac{5}{10} = \frac{1}{2} \].
04

Calculate Probability for Equivalence Between 98 and 102 mL

The outcomes from 98 mL to 102 mL inclusive are 98, 99, 100, 101, and 102. There are 5 such outcomes. Thus, the probability is \[ P(98 \leq x \leq 102\, \text{mL}) = \frac{5}{10} = \frac{1}{2} \].

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Acid-Base Titration
In an acid-base titration, a chemical reaction occurs between an acid and a base. The main goal is to determine an unknown concentration of either the acid or the base. This is done by adding a titrant, which is a solution of known concentration, to a solution with the unknown concentration until the reaction reaches completion. The point at which the reaction is complete is known as the equivalence point. Titrations are fundamental in chemistry because they allow scientists to precisely measure concentrations and understand reactions.

During the titration process, the solution gradually changes as the titrant is added. This change can be monitored visually with indicators or more accurately with pH meters. Indicators might show a color change, but measuring pH provides a more precise determination of the equivalence point. Thus, it is important in acid-base titrations to closely monitor these changes to find when the neutralization occurs.

Keep in mind that acids donate protons (H+) and bases accept protons. When they react, they form water and a salt, making precise measurement key to understanding the complete reaction.
Equivalence Point
The equivalence point in a titration is reached when the amount of titrant added is just enough to completely neutralize the analyte solution. This means that moles of the acid equal the moles of the base in the solution. The equivalence point is not necessarily at a neutral pH (7), except for strong acid and strong base reactions.

For example, during an acid-base titration, if sodium hydroxide (NaOH) is added to acetic acid, the equivalence point is reached when the moles of acetic acid equal the moles of NaOH added. This is usually indicated by a sharp change in pH.
  • Each type of acid and base pair may have a unique equivalence point.
  • The use of a pH meter or indicator is crucial for accurate determination.
  • The equivalence point is crucial for determining the unknown concentration of a solution.
Thus, accurately identifying the equivalence point means accurately measuring the concentration of the solution being titrated.
Sample Space
In probability theory, the sample space is the set of all possible outcomes of a random experiment. When it comes to titration, the sample space refers to all possible values at which equivalence might be indicated during an experiment. In this context, each possible measurement is considered equally likely.

For instance, if the equivalence point for a titration is measured among a series of trials as any integer milliliter between 95 and 104 mL, then the sample space would be \( S = \{95, 96, 97, 98, 99, 100, 101, 102, 103, 104\} \).
  • Each value in the sample space represents a potential outcome.
  • Understanding the sample space allows us to calculate probabilities for different scenarios.
  • In this case, every milliliter is an equally probable event within the range.
By defining this sample space, the probability of the equivalence point being at any specific volume can be calculated and analyzed effectively.
pH Measurement
pH measurement is a critical aspect of acid-base titration because it provides a quantitative way to determine the acidity or alkalinity of a solution. The pH scale ranges from 0 to 14, with lower numbers being more acidic, higher numbers being more basic, and 7 being neutral.

Measuring the pH during a titration allows scientists to precisely track how the solution's acidity changes as the titrant is added. This is essential for determining the equivalence point:
  • A pH meter provides real-time feedback on changes in pH during the titration.
  • Sharp changes in pH usually indicate that the equivalence point has been reached.
  • Accurate pH measurement helps ensure the correct conclusion about the reaction is made, preventing errors in determining concentrations.
In summary, accurate pH measurement ensures that titration calculations are based on precise data, enhancing the reliability and accuracy of the experiments.

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